Harnessing instability for work hardening in multi-principal element alloys.

The strength-ductility trade-off has long been a Gordian knot in conventional metallic structural materials and it is no exception in multi-principal element alloys. In particular, at ultrahigh yield strengths, plastic instability, that is, necking, happens prematurely, because of which ductility almost entirely disappears. This is due to the growing difficulty in the production and accumulation of dislocations from the very beginning of tensile deformation that renders the conventional dislocation hardening insufficient. Here we propose that premature necking can be harnessed for work hardening in a VCoNi multi-principal element alloy. Lüders banding as an initial tensile response induces the ongoing localized necking at the band front to produce both triaxial stress and strain gradient, which enables the rapid multiplication of dislocations. This leads to forest dislocation hardening, plus extra work hardening due to the interaction of dislocations with the local-chemical-order regions. The dual work hardening combines to restrain and stabilize the premature necking in reverse as well as to facilitate uniform deformation. Consequently, a superior strength-and-ductility synergy is achieved with a ductility of ~20% and yield strength of 2 GPa during room-temperature and cryogenic deformation. These findings offer an instability-control paradigm for synergistic work hardening to conquer the strength-ductility paradox at ultrahigh yield strengths.

High Reversible Strain in Nanotwinned Metals.

Development of bulk metals exhibiting large reversible strain is of great interest, owing to their potential applications in flexible electronic devices. Bulk metals with nanometer-scale twins have demonstrated high strength, good ductility, and promising electrical conductivity. Here, ultrahigh reversible strain as high as ∼7.8% was observed in bent twin lamellae with 1-2 nm thickness in nanotwinned metals, where the maximum reversible strain increases with the reduction in twin lamella thickness. This high reversible strain is attributed to the suppression of dislocation nucleation, including both hard mode dislocations in the bent twin lamellae, while soft mode dislocations along twin boundaries have insignificant contribution. In situ transmission electron microscopy experiments show that higher recoverability was achieved in twinned Au nanorods compared with twin-free ones with similar aspect ratios and diameters during bending deformation, which demonstrates that the introduction of thin twin lamellae also significantly improves the shape recoverability of Au nanorods. This result introduces a novel pathway for developing bulk metals with the capability for large reversible strain.

Free-standing Monatomic Thick Two-dimensional Gold.

Monolayer metal membranes have attracted research attention owing to their fascinating physical properties. Unlike layered materials with weak interlayer van der Waals bonding, metallic monolayer membranes are difficult to exfoliate due to strong metallic bonding between layers. Here, we fabricate free-standing monatomic-thick Au membranes and nanoribbons framed in bulk crystals using in situ dealloying inside transmission electron microscope. The Au membranes are robust under high energy electron beam. Monatomic-thick nanoribbons with a minimal width of 0.6 nm are observed. First-principles calculations reveal that zigzag-edged nanoribbons are ferromagnetic with magnetic moments ranging 0.38-0.51 µB per unit-cell for a width less than 0.9 nm. In addition, a linear relationship between the bond length and the coordination number of atoms is directly investigated using atomic resolution images of monolayer and bilayer Au membranes. This work provides a pathway for direct fabrication of metal membranes and nanoribbons and to achieve novel physical properties.