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1.
ACS Omega ; 9(13): 15573-15589, 2024 Apr 02.
Article in English | MEDLINE | ID: mdl-38585086

ABSTRACT

Unconventional hydrocarbon exploration is needed in the current oil and gas crisis scenario. Therefore, the development of conditions for unconventional hydrocarbon exploration is needed. In the Upper Indus Basin (UIB), Pakistan, the Patala Formation is one of the potential candidates for this unconventional exploration. It is a proven source rock at the regional level in the Kohat-Potwar sub-basin of UIB. This study aims to evaluate the shale gas potential of the rock in the Minwal-Joyamair area of the sub-basin. Developing a shale rock physics model is important for exploring and developing shale reservoirs due to the difference between unconventional shale and conventional sand reservoirs. These differences include mineral types, mineral characteristics, matrix pores, and fluid properties. To achieve the study's objectives, an integrated strategy provides for evaluating rock physics parameters, petrophysics, and geochemical analyses. This integrated approach indicates that the Patala Formation is a good potential reservoir for shale gas exploration. The Formation has a significant thickness (around 40-50 m), higher total organic carbon content (02-10%), higher brittleness index (0.44-0.56), and relatively shallow depth (2136-3223 m). These research findings suggested that the presence of organic and quartz-rich lithofacies can be considered as highly favorable "sweet spots" for shale-gas exploration in the UIB, Pakistan. Through proper understanding of the spatial and temporal distribution of these "sweet spots", shale-gas exploration can be developed as an effective strategy to exploit shale gas.

2.
ACS Omega ; 9(12): 14123-14141, 2024 Mar 26.
Article in English | MEDLINE | ID: mdl-38559993

ABSTRACT

The Kohat sub-basin is one of the main hydrocarbon-producing sedimentary basins located in the northwest extension of the Indus Basin in Pakistan. It contains numerous proven and potential petroleum from the Cambrian to the Miocene. Conventional petroleum resources have been depleting rapidly over the last couple of years. Therefore, unconventional resources should be explored using a variety of geochemical and geophysical techniques to address the energy demands. Geochemical techniques, including total organic carbon (TOC) assessment, Rock-Eval pyrolysis, organic petrography, and biomarker studies, are essential for evaluating the potential of shale gas reservoirs to delineate future prospects in a basin. The source rock potential of the Paleocene rocks, including the Patala, Lockhart, and Hangu formations of the sub-basin, is evaluated using geochemical analyses on well cuttings from the Tolanj-01 well. The analyses include estimation of total organic carbon (TOC), Rock-Eval pyrolysis, and organic petrography (vitrinite reflectance) to evaluate the organic richness, thermal maturity, kerogen type, hydrocarbon type, and environment of deposition. Other techniques for extractable organic matter (EOM) include solid-liquid chromatographic separation of fractions, gas chromatography (GC-FID)/whole oil chromatography, and gas chromatography-mass spectrometry (GC-MS). The organic matter (TOC, wt %) analysis reveals that 18 (18) samples of the Hangu formation (0.08-1.8 wt %) show poor values, 12 (12) samples of the Lockhart formation (0.05-0.5 wt %) have poor to fair content, and 26 (26) samples of the Patala formation have poor to fair (0.08-0.19 wt %) TOC content. Rock-Eval pyrolysis studies including hydrogen index, oxygen index, Tmax, quantities of free hydrocarbons (S1, mg/g), and hydrocarbons produced from pyrolysis (S2, mg/g) are determined for the well-cut samples (56) of the Paleocene rocks. The hydrogen index values for the Hangu formation are lower than 200, and those for the Lockhart and Patala formations range between 100 and 250. A maceral analysis is also conducted on these samples, which reveal that the majority of the samples of the Paleocene units present in the basin belong to kerogen types II/III. The thermal maturity of the Hangu and Lockhart formations falls in the late-stage oil window, while that of the Patala formation falls in the peak to late oil window. The genetic potential (GP) for these rock units is also determined based on S1 and S2 values, which reveals that it is generally poor except for a few samples of the Hangu and Lockhart formations, which show fair GP values. For the organic petrography (vitrinite reflectance, R0), one sample from each unit is selected, which shows that the Hangu, Lockhart, and Patala formations fall in the category of the mature oil window with their R0 (%) values being 0.95, 0.89, and 0.82, respectively. The extracts (EOM) from these rock units are also analyzed to assess the depositional settings, biological source input, biodegradation, thermal maturity, etc. The greater values of pristine to phytane (Pr/Ph > 1) ratios for Hangu (1.33), Lockhart (1.23), and Patala (1.8) indicate an intermediate condition (suboxic), while a cross-plot of Pr/n-C17-Ph/n-C18 shows that the organic matter is deposited in a transitional setting. The ratios between C19TCT/C19 TCT + C23 TCT and C24 TeCT/C24TeCT + C23TCT biological source inputs are mainly of marine origin. Similarly, the ternary diagram of regular steranes (C27-C28-C29) shows a greater marine input. Lower values of the carbon preference index (CPI1) for Hangu (0.95), Lockhart (0.91), and Patala (1.04) indicate higher thermal maturity of the Paleocene rocks. Similarly, the methylphenanthrene index (MPI-1) values, Moretane index, and Pr/n-C17 vs Ph/n-C18 plots also show higher thermal maturity for these rock extracts.

3.
Heliyon ; 9(6): e16517, 2023 Jun.
Article in English | MEDLINE | ID: mdl-37313144

ABSTRACT

Upper Indus Basin has been a valuable asset as the complexity of structure and hydrocarbon production is the leading producer of oil and gas in history and still to date. Potwar sub-basin has significance in the light of oil production from carbonate reservoirs or Permian to Eocene age reservoirs. Minwal-Joyamair field is very significant and has unique hydrocarbon production history with complexity in structure style and stratigraphy. The complexity is present for carbonate reservoirs of the study area due to heterogeneity of lithological and facies variation. In this research, the emphasis is on integrated advanced seismic and well data for Eocene (Chorgali, Sakesar), Paleocene (Lockhart), and Permian age (Tobra) formations reservoirs. This research's primary focus is to analyze field potential and reservoir characterization by conventional seismic interpretation and petrophysical analysis. Minwal-Joyamair field is a combination of thrust and back thrust, forming a triangle zone in the subsurface. The petrophysical analysis results suggested favorable hydrocarbon saturation in Tobra (74%) and Lockhart (25%) reservoirs in addition to the lower volume of shale (28% and 10%, receptively) and higher effective values (6% and 3%, respectively). The main objective of the study is the re-assessment of a hydrocarbon producing field and describe the future prospectively of the field. The analysis also includes the difference in hydrocarbon production from two different type of reservoir (carbonate & clastic). The findings of this research will be useful for any other similar basins around the world.

4.
Heliyon ; 9(5): e15621, 2023 May.
Article in English | MEDLINE | ID: mdl-37131446

ABSTRACT

The information about the subsurface structure, type of fluids present in the reservoir, and physical properties of the rocks is essential for identifying potential leads. The integrated approach of petrophysical analysis, seismic data interpretation, seismic attributes analysis, lithology, mineralogy identification, and Gassmann fluid substitution were used for this purpose. The structural interpretation with the help of seismic data indicated the extensional regime with horst and graben structures in the study area. The two negative flower structures are cutting the entire Cretaceous deposits. The depth contour map also indicate favorable structures for hydrocarbon accumulation. The four possible reservoir zones in the Sawan-01 well and two zones in the Judge-01 well at B sand and C sand levels are identified based on well data interpretation. The main lithology of the Lower Goru Formation is sandstone with thin beds of shale. The clay types confirm the marine depositional environment for Lower Goru Formation. The water substitution in the reservoir at B sand and C sand levels indicated increased P-wave velocity and density. The water substitution affected the shear wave velocity varies slightly due to density changes. The cross plots of P-impedance versus Vp/Vs ratio differentiate the sandstone with low P-impedance and low Vp/Vs ratio from shaly sandstone with high values in the reservoir area. The P-impedance and S-impedance cross plot indicate increasing gas saturation with a decrease in impedance values. The low values of Lambda-Rho and Mu-Rho indicated the gas sandstone in the cross plot.

5.
ACS Omega ; 8(4): 4127-4145, 2023 Jan 31.
Article in English | MEDLINE | ID: mdl-36743037

ABSTRACT

The carbonate reservoir quality is strongly reliant on the compaction process during sediment burial and other processes such as cementation and dissolution. Porosity and pore pressure are the two main factors directly affected by mechanical and chemical compactions. Porosity reduction in these carbonates is critically dependent on the overburden stress and subsidence rate. A variable sediment influx in younger basins may lead to changes in the reservoir quality in response to increasing lithostatic pressure. Deposition of molasse sediments as a result of the Himalayan orogeny caused variations in the sedimentation influx in the Potwar Basin of Pakistan throughout the Neogene times. The basic idea of this study is to analyze the carbonate reservoir quality variations induced by the compaction and variable sediment influx. The Sakesar Limestone of the Eocene age, one of the proven carbonate reservoirs in the Potwar Basin, shows significant changes in the reservoir quality, specifically in terms of porosity and pressure. A 3D seismic cube (10 km2) and three wells of the Balkassar field are used for this analysis. To determine the vertical and lateral changes of porosity in the Balkassar area, porosity is computed from both the log and seismic data. The results of both the data sets indicate 2-4% porosities in the Sakesar Limestone. The porosity reduction rate with respect to the lithostatic pressure computed with the help of geohistory analysis represents a sharp decrease in porosity values during the Miocene times. Pore pressure predictions in the Balkassar OXY 01 well indicate underpressure conditions in the Sakesar Limestone. The Eocene limestones deposited before the collision of the Indian plate had enough time for fluid expulsion and show underpressure conditions with high porosities.

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