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Phys Chem Chem Phys ; 2024 Aug 14.
Article in English | MEDLINE | ID: mdl-39140998

ABSTRACT

We have investigated the in-plane local structure of the Ba0.6K0.4Fe2As2 superconductor by polarized Fe K-edge extended X-ray absorption fine structure (EXAFS) measurements with temperature. The near neighbor bond distances and their stiffness, measured by polarized EXAFS in two orthogonal directions, are different suggesting in-plane anisotropy of the atomic displacements and local orthorhombicity in the title system. The X-ray absorption near edge structure (XANES) spectra reveal anisotropy of valence electronic structure that changes anomalously below ∼100 K. The local iron magnetic moment, measured by Fe Kß X-ray emission spectroscopy (XES), increases below the anomalous temperature and shows a decrease in the vicinity of the superconducting transition temperature (Tc ∼ 36 K). The results provide a clear evidence of coupled local lattice, electronic and magnetic degrees of freedom to induce possible nematic fluctuations in an optimally hole doped iron-based superconductor.

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