A solid state highly emissive Cu(i) metallacycle: promotion of cuprophilic interactions at the excited states.

The straightforward synthesis of a new Cu(i) metal-rich small metallacycle is presented. This compound is luminescent in the solid state with an emission quantum yield of 72% at room temperature and displays a pronounced reversible red-shift of its emission spectra upon cooling. Quantum chemical calculations reveal that these properties are governed by important geometrical relaxations that imply the formation of cuprophilic interactions at the excited states.

Correction: Supramolecular metallacycles with a 'pseudo double-paracyclophane' structure based on flexible π-conjugated linkers.

Correction for 'Supramolecular metallacycles with a 'pseudo double-paracyclophane' structure based on flexible π-conjugated linkers' by W. Shen et al., Chem. Commun., 2015, 51, 11560-11563.

Supramolecular metallacycles with a 'pseudo double-paracyclophane' structure based on flexible π-conjugated linkers.

The straightforward synthesis of new supramolecular metallacycles having a 'pseudo double-paracyclophane' structure is presented. They are obtained from the reaction of a pre-assembled Cu(I) bimetallic precursor bearing short intermetallic distances with cyano-capped homoditopic π-conjugated linkers having flexible central cores.