ABSTRACT
The indirect emission had a negative influence on the ecosystem of enormous amounts of harmful dyes into water. Fe3O4@Ag-MOF was successfully fabricated to capture Gentine violet (GV)) as a model example of cationic dye from their aqueous solutions was evaluated in this search as a method to eliminate dyes from water contaminants. FTIR, XPS, BET, TGA, SEM, TEM, and XRD have all been used to study this adsorbent in order to determine its structural and chemical characteristics as well as to interpret its binding mechanisms. According to the results of the characterization, the synthesized composite had a size about 45 nm, a surface area of 856.06 m2/g, and considerable magnetic characteristics (66.2 emug-1). Consequently, we created mesoporous surfaces that had a strong ability to interface and absorb GV dye. It is possible to use the pseudo-second order rate equation to characterize the kinetic profile., while the Langmuir equation fits isotherm models. At pH 9, maximum sorption capacities can reach 1.68 mmol.g-1. Additionally, the investigations of temperature profiles indicated the endothermic process and Thermodynamic parameters were discovered as, ΔG°, ΔH° and ΔS° The synthesized adsorbent had an interestingly high reusability of > 92 percent up to the sixth cycle. These findings revealed that a mixture of electrostatic interactions, π-π stacking, hydrogen bonds, and pore filling were involved in the GV adsorption mechanism. Fe3O4@Ag-MOF was successful in demonstrating its effectiveness as a point-of-use colour collection candidate from actual dyeing effluents.
ABSTRACT
The purpose of this research was to investigate the doxorubicin (DOX) adsorption behavior on Fe3O4@Ag-Metal Organic Framework (Fe3O4@Ag-MOF). This adsorbent was effectively prepared using a simple synthetic process. Many instruments, including FTIR, XRD, SEM, TEM, and XPS, were used to characterized the new Fe3O4@Ag-MOF. Additionally, the presented Fe3O4@Ag-surface MOF's area was shown to be 586.06 m2/g with a size of around 43 nm. The composite that was made has magnetic properties that were quite strong (63.3 emu/g). The produced Fe3O4@Ag-MOF was discovered to have a fantastic ability to adsorb the anti-cancer drug DOX, with a 1.72 mmol/g (934.85 mg/g) adsorption capacity. On the basis of changes in temperature, pH, and DOX concentration, the DOX adsorption behavior mechanism was investigated. The adsorption capacity of Fe3O4@Ag-MOF for DOX was greater at pH 7.0, according to experimental data. The adsorption equilibrium also demonstrated that the Langmuir adsorption was regulated the best fit to the extracted data compared with the other models. Additionally, the activation energy of adsorption for DOX onto Fe3O4@Ag-MOF was determined, indicating the chemisorption process. The adsorption kinetics was shown in the well-known kinetic model of the pseudo-second-order. The adsorption thermodynamic measurements were documented according to according to the enthalpy (ΔH°), entropy(ΔS°), and Gibbs free energy (ΔG°) parameters demonstrated that the reaction was endothermic and spontaneous thermodynamic. The adsorption of DOX onto Fe3O4@Ag-MOF from real water samples (tap water, effluent wastewater, and influence wastewater) were investigated. It's interesting that the synthetic adsorbent had great recyclability 72.6 percent in the fifth cycle indicating that it was highly recyclable. After adsorption, the typical Fe3O4@Ag-MOF XRD peak intensities and locations were mostly unchanged throughout adsorption indicates the crystalline phase remained steady. The results indicated that Fe3O4@Ag-MOF were a good candidate for adsorbing the DOX and treating wastewater.
Subject(s)
Nanocomposites , Water Pollutants, Chemical , Adsorption , Wastewater , Doxorubicin , Water/chemistry , Water Pollutants, Chemical/chemistry , KineticsABSTRACT
Mesopores silica nanotubes (MSNTs)-based chemical sensors for the rapid detection and of highly selective Fe2+ ions have been prepared. The novel nanosensors were prepared via immobilization of 1,10-phenanthroline-5-amine (PA) and bathophenanthroline (BP) onto the MSNTs. The resultant PA and BP sensors display high sensitivity for detection the Fe2+ ions in tap water, river water, sea water, two units in simple cycle power station, and biological samples. More interestingly, upon meeting ultra-trace amount of Fe2+ ions, a red complex appears at once. Color changes can be seen from the naked eye and tracked with a smartphone or spectrophotometric techniques. The response time that is necessary to achieve a stable signal was less than 15 s. The Univariate (Univar) calibration technique had been utilized for the determination of figures of merits. The detection limit obtained from the digital image analysis was 19 ppb (7.04 × 10-7 M) for Fe2+ ions, while the obtained from the spectrophotometric method was 6.7 ppb (2.48 × 10-7 M). Therefore, the two sensors had been successfully used in the determination of Fe2+ in several real samples with high sensitivity and selectivity. In addition, they can be used as a simple, rapid, and portable method to detect and quantify the pre rust in any cooler system.
