Appropriate oxygen vacancies and Mo-N bond synergistically modulate charge transfer dynamics of MoO3-x/S-CN for superior photocatalytic disinfection: Unveiling synergistic effects and disinfection mechanism.

Highly efficient charge transfer is a critical factor to modulate the photocatalytic activity. However, the conscious modulation of charge transfer efficiency is still a great challenge. Herein, a novel interfacial Mo-N bond and appropriate oxygen vacancies (OVs) modulated S-scheme MoO3-x/S-CN heterojunction was rationally fabricated for efficient photocatalytic disinfection. The results of characterizations and density functional theory (DFT) calculations suggested that the enhanced charge transfer dynamics is ascribed to the optimizing oxygen vacancies density and forming interfacial Mo-N bond. It can improve charge transfer efficiency from 36.4% (MoO3-x) to 52.5% (MoO3-x/S-CN) and produce more reactive oxygen species (ROS), achieving entirely inactivate of 7.60-log E. coli and S. aureus within 50 min and 75 min. Besides, MoO3-x/S-CN can well resist the disturbance from the coexisting substances, and can be applied in a wide pH range, and even authentic water bodies. Monitoring of bacterial antioxidant systems and membrane integrity revealed that bacterial inactivation begins with the oxidation of cell membrane and dies from leakage of intracellular substances and destruction of cell structure. This work provides an inspiration on consciously modulating S-scheme charge transfer efficiency by optimizing oxygen vacancies density and atomic-level interface control for promoting the photocatalytic antibacterial activity.

Core-shell nanomaterials: Applications in energy storage and conversion.

Materials with core-shell structures have attracted increasing attention in recent years due to their unique properties and wide applications in energy storage and conversion systems. Through reasonable adjustments of their shells and cores, various types of core-shell structured materials can be fabricated with favorable properties that play significant roles in energy storage and conversion processes. The core-shell material can provide an effective solution to the current energy crisis. Various synthetic strategies used to fabricate core-shell materials, including the atomic layer deposition, chemical vapor deposition and solvothermal method, are briefly mentioned here. A state-of-the -art review of their applications in energy storage and conversion is summarized. The involved energy storage includes supercapacitors, li-ions batteries and hydrogen storage, and the corresponding energy conversion technologies contain quantum dot solar cells, dye-sensitized solar cells, silicon/organic solar cells and fuel cells. In addition, the correlation between the core-shell structures and their performance in energy storage and conversion is introduced, and this finding can provide guidance in designing original core-shell structures with advanced properties.