Potential source and health risks of black carbon based on MERRA-2 reanalysis data in a typical industrial city of North China Plain.

Black carbon (BC) significantly affects climate, environmental quality, and human health. This study utilised Modern-Era Retrospective Analysis for Research and Applications, version 2 (MERRA-2), which can compensate for the shortcomings of ground BC monitoring in spatial-temporal distribution to study the pollution characteristics of BC and potential pollution sources in a typical industrial city (Xinxiang) with serious air pollution in northern China. The results showed that average daily ground observation and MERRA-2 concentration of BC of 7.33 µg m-3 and 9.52 µg m-3. The mean BC concentration derived from MERRA-2 reanalysis data was higher than ground measurement due to resolution limitations and pollution from the northern regions. The reliability of the MERRA-2 data was confirmed through correlation analysis. Consideration of the spatial distribution of BC from MERRA-2 and incorporating the potential source contribution function (PSCF), concentration-weighted trajectory (CWT), and emission inventory, other possible source areas and primary sources of BC in Xinxiang were investigated. The results indicated that implementing transportation and residential emission control measures in Henan Province and its surrounding provinces, such as Hebei Province, will effectively decrease the BC level in Xinxiang City. A passively smoked cigarettes model was used to evaluate the risk of BC exposure. The percentage of lung function decrement (PLFD) was the highest in school-age children, while the impact on lung cancer (LC) health risk was comparatively lower. Notably, the BC health risk in Xinxiang was lower than in most cities across Asia.

Dimethylsiloxanes in dust from nine indoor microenvironments of Henan Province: Occurrence and human exposure assessment.

Dimethylsiloxanes (MSs) are widely used in daily life and industry, with indoors being the main release site. Detecting the levels of MSs in indoor dust is essential for assessing the risks of human exposure. In this study, the content of MSs (D3-D8 and L3-L16) was quantified in indoor dust samples from nine microenvironments of Henan Province. The detection frequency of the targets ranged from 5.00 % to 100 %. The sum concentration of dimethylsiloxanes (TSi) was in a range of 463-3.32 × 104 ng·g-1 (median: 1.92 × 103 ng·g-1). The sum concentration of linear dimethylsiloxanes (TLSi) from all microenvironments was higher than the sum concentration of cyclic dimethylsiloxanes (TCSi), which was consistent with previously reported results. D7 and D8 were the main cyclic dimethylsiloxane, which had similar sources based on Spearman correlation analysis (p < 0.001). Moreover, D8 was detected with high levels in indoor dust for the first time, which warrants further exploration. L8-L16 were the main linear dimethylsiloxanes, which may have been due to their widespread use in electronic equipment and office equipment. The Spearman analysis found that total organic carbon (TOC) in indoor dust had weak effect on MSs. Additionally, relatively high MS levels were recorded in high people-flow working microenvironments. Accordingly, the exposure doses of MSs via indoor dust intake were estimated for different age groups using the model of worst-case exposure and median concentration. Toddlers had the highest EDIs (95th percentile concentration, 90.7 ng·kg-1-bw·d-1) to MSs.

Magnetic Biochar Derived from Fenton Sludge/CMC for High-Efficiency Removal of Pb(II): Synthesis, Application, and Mechanism.

Magnetic biochar composites (MBC) were developed by a simple one-step pyrolysis method using Fenton sludge waste solid and carboxymethyl cellulose sodium. Detailed morphological, chemical, and magnetic characterizations corroborate the successful fabrication of MBC. Batch adsorption experiments show that the synthesized MBC owns high-efficiency removal of Pb(II), accompanied by ease-of-separation from aqueous solution using magnetic field. The experiment shows that the equilibrium adsorption capacity of MBC for Pb(II) can reach 199.9 mg g-1, corresponding to a removal rate of 99.9%, and the maximum adsorption capacity (qm) reaches 570.7 mg g-1, which is significantly better than that of the recently reported magnetic similar materials. The adsorption of Pb(II) by MBC complies with the pseudo second-order equation and Langmuir isotherm model, and the adsorption is a spontaneous, endothermic chemical process. Investigations on the adsorption mechanism show that the combination of Pb(II) with the oxygen-containing functional groups (carboxyl, hydroxyl, etc.) on biochar with a higher specific surface area are the decisive factors. The merits of reusing solid waste resource, namely excellent selectivity, easy separation, and simple preparation make the MBC a promising candidate of Pb(II) purifier.

Effectively removing gaseous polycyclic aromatic hydrocarbons (PAHs) by willow catkins: Do you still dislike the catkins floating?

The floating catkins generated by willow and poplar trees have been criticized for spreading germ and causing fire for decades. It has been found that catkins are with a hollow tubular structure, which made us wonder if the floating catkins can adsorb atmospheric pollutions. Thus, we conducted a project in Harbin, China to investigate whether and how willow catkins could adsorb atmospheric polycyclic aromatic hydrocarbons (PAHs). The results suggest that both the catkins floating in the air and on the ground preferred to adsorb gaseous PAHs rather than particulate PAHs. Moreover, 3- and 4-ring PAHs were the dominating compositions adsorbed by catkins, which significantly increased with exposure time. The gas/catkins partition (KCG) was defined, which explained why 3-ring PAHs are more easily adsorbed by catkins than by airborne particles when their subcooled liquid vapor pressure is high (log PL > -1.73). The removal loading of atmospheric PAHs by catkins were estimated as 1.03 kg/year in the center city of Harbin, which may well explain the phenomenon that levels of gaseous and total (particle + gas) PAHs are relatively low in the months with catkins floating reported in peer-reviewed papers.

Novel insights into impacts of the "7.20" extreme rainstorm event on water supply security of Henan Province, China: Levels and health risks of tap water disinfection by-products.

Spatial distributions, levels, and comprehensive assessments of post-flood tap water disinfection by-products (DBPs) were first studied in Henan Province after the "7.20" Extreme Rainstorm Event in 2021. DBPs levels and health risks in tap water were higher in areas flooded (waterlogged) by storm or upstream flood discharge (WA) and rainstorm-affected areas (RA) compared with other areas (OA), suggesting that extreme rainstorm and flooding events may somehow exacerbate DBPs contamination of tap water through disinfection. WA sites were characterized as contamination hotspots. The results revealed high haloacetic acids (HAAs) levels in WA (Avg: 57.79 µg·L-1) and RA (Avg: 32.63 µg·L-1) sites. Compared with normal period, DBPs-caused cancer risk increased by 3 times, exceeding the negligible risk level. Cancer risk came primarily from the ingestion of trihalomethanes (THMs) (>80%), children were the sensitive group. Those between 30 and 69 showed approximately 1.7 times higher disability-adjusted life yearsper person-yearthan other age groups. Apart from regulated DBPs, bromochloracetic acid (BCAA) and dibromoacetonitrile (DBAN) appear to be the main toxicity contributors in these samples. Our results provide a scientific basis for preventing and controlling health risks from tap water DBPs and for assessing the social benefits and burdens of emergency disinfection.

A Bifunctional BiOBr/ZIF-8/ZnO Photocatalyst with Rich Oxygen Vacancy for Enhanced Wastewater Treatment and H2O2 Generation.

Photocatalytic technology is considered an ideal approach for clean energy conversion and environmental pollution applications. In this work, a bifunctional BiOBr/ZIF-8/ZnO photocatalyst was proposed for removing phenols in wastewater and generating hydrogen peroxide. Insights from scanning electron microscopy measurements revealed the well-dispersion of ZIF-8/ZnO was on the BiOBr layer, which could effectively prevent agglomeration of ZIF-8 and facilitate the separation of carriers. In addition, the optimal H2O2 yield of the BiOBr/ZIF-8/ZnO sample could reach 116 mmol·L-1·g-1 within 2 h, much higher than that of pure BiOBr (with the value of 82 mmol·L-1·g-1). The optimal BiOBr/ZIF-8/ZnO sample could also remove 90% of the phenol or bisphenol A in 2 h, and its kinetic constants were 3.8 times and 2.3 times that of pure BiOBr, respectively. Based on the analysis of the various experimental characterizations, the photocatalytic mechanism of the S-scheme BiOBr/ZIF-8/ZnO composite for the degradation of phenolic pollutants and generation of H2O2 was proposed. The formation of the heterojunction and the oxygen vacancy work together to significantly improve its photocatalytic efficiency. In addition, the BiOBr/ZIF-8/ZnO catalyst has a certain impact on the degradation of phenol in actual wastewater, providing a way to effectively remove refractory pollutants and generate H2O2 in actual water.

Hydroxyl regulating effect on surface structure of BiOBr photocatalyst toward high-efficiency degradation performance.

Herein, photocatalytic degradation of levofloxacin hydrochloride (LVF) by a simple surface hydroxyl strategy on BiOBr photocatalyst was studied under simulated visible light irradiation. Interestingly, the BiOBr contained abundant hydroxyl groups following its modification with glucose, which enhanced the photocatalytic degradation of levofloxacin hydrochloride (LVF). The degradation efficiency of LVF over the optimized composite of BiOBr-5 could reach 91.67% in 20 min, which was much higher than that of pristine BiOBr (59.26%). Following, the biotoxicity of antibiotics to Escherichia coli DH5a could be eliminated after LVF photocatalytic degradation. This strategy proposed in this work can provide new ideas for tuning the surface structures of photocatalysts via specific functional groups for the highly efficient degradation and efficient removal of antibiotics in wastewater.

Dual-functional Z-scheme CdSe/Se/BiOBr photocatalyst: Generation of hydrogen peroxide and efficient degradation of ciprofloxacin.

The major challenges of clean energy and environmental pollution have resulted in the development of photocatalysis technologies for energy conversion and the degradation of refractory pollutants. Herein, a novel CdSe/Se/BiOBr hydrangea-like photocatalyst was used to produce hydrogen peroxide (H2O2) and degrade ciprofloxacin (CIP). The Z-scheme heterojunction structure of the photocatalyst and the doping of selenium (Se) led to the efficient separation of electron-hole pairs and charge transfer. The optimized sample of 2 wt% CdSe/Se/BiOBr produced 142.15 mg·L-1 rate of H2O2, which was much higher than that produced by pure BiOBr (89.4 mg·L-1) or CdSe/Se (10.9 mg·L-1). Additionally, almost 100 % of CIP was degraded within 30 min, with a first order rate constant of nearly 5.35 times that of pure BiOBr and 81.44 times that of pure CdSe/Se. The excellent removal efficiency of CIP from natural water matrices confirmed that the composites are promising for the removal of contaminants from natural waterways. Based on trapping experiments, electron spin resonance spectra (ESR) spectroscopy, and density functional theory (DFT) calculations, the photocatalytic mechanisms of H2O2 and CIP degradation by the Z-scheme CdSe/Se/BiOBr composites were proposed. Overall, the dual-functional CdSe/Se/BiOBr composite could potentially be applied for photocatalytic production of H2O2 and treatment of organic pollutants in water.

Spatiotemporal distribution and mass loading of organophosphate flame retardants (OPFRs) in the Yellow River of China (Henan segment).

During three sampling periods in 2014, systematic investigations were conducted into contamination profiles of ten organophosphate flame retardants (OPFRs) in both suspended particulate phase and water phase in the Yellow River (Henan Area). This research shows that OPFRs exist at lower concentrations in the suspended phase than in the water phase. The median concentration of 10 OPFRs (∑10OPFRs) in the suspended particulate phase was 62.5 ng/g (fluctuating from ND to 6.17 × 103 ng/g, dw), while their median concentration in the water phase was 109 ng/L (fluctuating from 35.6 to 469 ng/L). Among the selected 10 OPFRs, triethylphosphate (TEP), tris(1-chloro-2-propyl) phosphate (TCPP), and tris(2-chloroethyl) phosphate (TCEP) were the predominant compounds in the water phase (occupying 91.6% of the ∑10OPFRs), while TCPP, TCEP, and tri-o-tolyl phosphate (o-TCP) were the most common in the suspended particulate phase, accounting for 90.1% of the ∑10OPFRs. Across the three sampling periods, there was no significant seasonable variation for OPFRs either in the water phase or in the suspended particulate phase, except for TCEP and TCPP in the water phase. Compared with research findings relating to concentrations of OPFRs around China and abroad, the OPFRs of the Yellow River (Henan Area) in the water phase were at a moderate level. Suspended particles (SS) had a very important impact on the transportation of OPFRs in the studied area, with about 83.9% of ∑10OPFRs inflow attributed to SS inflow and about 81.7% of ∑10OPFRs outflow attributed to SS outflow. The total annual inflow and outflow of OPFRs were 7.72 × 104 kg and 6.62 × 104 kg in the studied area, respectively.

Sucrose-derived N-doped carbon xerogels as efficient peroxydisulfate activators for non-radical degradation of organic pollutants.

Metal-free activation of peroxydisulfate (PDS) for degrading organic pollutants in water has received increasing attention because it can prevent secondary pollution. However, most of the catalysts that are efficient are derived from non-renewable fossil resources, are very expensive and have complex preparation processes. Also, the emerging non-radical mechanism is still unclear. Herein, 3D sucrose-derived N-doped carbon xerogels (NCXs) were synthesized by a simple and sustainable hydrothermal process and then employed as novel metal-free PDS activators to degrade organic pollutants. The structure, composition and performance of NCXs were regulated by changing the carbonization temperature. The sample carbonized at 900 °C (NCX900) exhibited the best catalytic performance, completely removing bisphenol A in 60 min. Quenching experiments and linear sweep voltammograms demonstrated that PDS was activated mainly through an electron-transfer non-radical mechanism. It was found that graphitic N played a critical role in activating PDS. With this non-radical mechanism, the NCX900/PDS system could adapt well to the wide pH range (3-11) and high Cl- concentration; it selectively oxidized organic pollutants with low ionization potentials. This work provides a sustainable approach to the low-cost and efficient metal-free catalysts for wastewater treatment.

Effects of hydrodynamic shear stress on sludge properties, N2O generation, and microbial community structure during activated sludge process.

Sludge properties are critical to the treatment performance and potentially correlate with nitrous oxide (N2O) generation during activated sludge processes. The hydrodynamic shear stress induced by aeration has a significant influence on sludge properties and is inevitable for wastewater treatment plants (WWTPs). In this study, the effects of aerobic induced hydrodynamic shear stress on sludge properties, N2O generation, and microbial community structure were investigated using three parallel sequencing batch reactors (SBRs) with identical dissolved oxygen (DO) concentrations. Results showed that with a shear stress increase from 1.5 × 10-2 N/m2 to 5.0 × 10-2 N/m2, the COD and NH4+-N removal rates were enhanced from 89.4% to 94.0% and from 93.9% to 98.0%, respectively, while the TN removal rate decreased from 66.0% to 56.5%. Settleability of the activated sludge flocs (ASFs) also increased with the enhancement of shear stress, due to variation in sludge properties including particle size, regularity, compactibility, and EPS (extracellular polymeric substances) composition. The increase in shear stress promoted oxygen diffusion within the ASFs and mitigated NO2--N accumulation, leading to a decrease in the N2O-N conversion rate from (4.8 ± 0.3)% to (2.2 ± 0.6)% (based on TN removal). Microbial analysis results showed that the functional bacteria involved in the biological nitrogen removal was closely related with shear stress. The increase in shear stress favored the enrichment of nitrite oxidizing bacteria (NOB) while suppressed the accumulation of ammonia-oxidizing bacteria (AOB) and denitrifying bacteria (DNB).

Effects of exogenous N-acyl-homoserine lactones on nutrient removal, sludge properties and microbial community structures during activated sludge process.

This study investigated the effects of exogenous N-acyl-homoserine lactone (AHL) signal molecules, N-hexanoyl-l-homoserine lactone (C6-HSL) and N-octanoyl-l-homoserine lactone (C8-HSL), on treatment performance, sludge properties and microbial community structures in activated sludge systems. Results showed that the nitrification and denitrification efficiencies were enhanced with the addition of signal molecules. The particle size, irregularity, and internal mass transfer resistance of activated sludge flocs (ASFs) increased, primarily because dosing AHLs led to a content increase and chemical composition variation of extracellular polymeric substances (EPS) in sludge. Microbial analysis indicated an increase in both the bacterial richness and diversity of the systems. The relative abundances of the key functional groups, including bacteria related to C and N removal and EPS production, varied correspondingly. This study presents an insight into the comprehensive understanding of the effects of AHL-based quorum sensing on activated sludge treatment process.

Viability and distribution of bacteria immobilized on Sawdust@silica: The removal mechanism of phenanthrene in soil.

Immobilized cells (ICs) have been widely used to enhance the remediation of organic-contaminated soil (e.g., polycyclic aromatic hydrocarbons, PAHs). Once ICs are added to the heterogeneous soil, degradation hotspots are immediately formed near the carrier, leaving the remaining soil lack of degrading bacteria. Therefore, it remains unclear how ICs efficiently utilize PAHs in soil. In this study, the viability of Silica-IC (Cells@Sawdust@Silica) and the distribution of inoculated ICs and phenanthrene (Phe) in a slurry system (soil to water ratio 1:2) were investigated to explore the removal mechanism of PAHs by the ICs. Results showed that the Silica-IC maintained (i) good reproductive ability (displayed by the growth curve in soil and water phase), (ii) excellent stability, which was identified by the ratio of colony forming units in the soil phase to the water phase, the difference between the colony number and the DNA copies, and characteristics of the biomaterial observed by the FESEM, and (iii) high metabolic activity (the removal percentages of Phe in soil by the ICs were more than 95% after 48 h). Finally, the possible pathways for the ICs to efficiently utilize Phe in soil are proposed based on the distribution and correlation of Phe and ICs between the soil and water phase. The adsorption-degradation process was dominant, i.e., the enhanced degradation occurred between the ICs and carrier-adsorbed Phe. This study provided new insights on developing a bio-material for efficient bio-remediation of PAHs-contaminated soil.

A seriously air pollution area affected by anthropogenic in the central China: temporal-spatial distribution and potential sources.

This study used the officially released data by the Chinese air quality monitoring network to analyze the pollution characteristics of six air pollutants (PM2.5, PM10, SO2, NO2, CO, and O3) for 29 cities in the Central Plains Economic Zone (CPEZ; China) in 2015. During 2015, serious particulate matter (PM) pollution often occurred, and the concentrations of PM2.5 and PM10 were 77 µg m-3 and 128 µg m-3, respectively. Air pollutants were at higher concentrations in the northern cities than those in the southern region of the CPEZ, and the correlation among the cities indicated that there was regional pollution in CPEZ. Generally, PM, SO2, NO2, and CO showed similar seasonal characteristics and the highest and lowest concentrations appeared in winter and summer, respectively. In addition, we used the HYSPLIT model and trajStat model to identify the potential source contribution function and concentration-weighted trajectory of Zhengzhou, the central city of CPEZ. More serious air pollution occurred when air masses were transported from the west of the CPEZ. Shaanxi Province, Hubei Province, Anhui Province and the northwest of the CPEZ were found to be the main exogenous sources of total PM with contributions of > 100 µg m-3 PM2.5 and > 180 µg m-3 PM10. Therefore, the concentrations of PM in 2015 at Zhengzhou were probably influenced by both long-distance transmission and local emissions.

Occurrence and distribution of priority pharmaceuticals in the Yellow River and the Huai River in Henan, China.

The occurrence and spatial distribution of priority pharmaceuticals (PPs) in water samples from the Yellow River and the Huai River in the Henan region of China were investigated in this study. The concentration of the total PPs (ΣPPs; sum of the 10 observed PPs) ranged from not detected to 3474 ng L-1 in samples from the Yellow River and from 4.35 to 146 ng L-1 in samples from the Huai River. The level of the ΣPPs in the Huai River was much lower than that found in the Yellow River. The composition of the PPs differed between the two rivers. Norfloxacin, carbamazepine, and 5,5-diphenylhydantoin were detected at high concentrations in the Yellow River, whereas sulfamethazine, ampicillin trihydrate, carbamazepine, and 5,5-diphenylhydantoin were the dominant species in the Huai River, suggesting there were different pollution sources. In comparison to other studies around China, most of the PPs in water samples from the Yellow River and the Huai River were at low concentrations, except for norfloxacin and ofloxacin. There were significant seasonal variations among the PPs in water samples from the Huai River, whereas spatial distinctions were recorded among the PPs in the Yellow River. Dissolved organic carbon content did not correlate with the PPs in the studied area.

Magnetic supramolecular polymer: Ultrahigh and highly selective Pb(II) capture from aqueous solution and battery wastewater.

For the practical capture of heavy metal ions from wastewater, fabricating environmental friendly adsorbents with high stability and super adsorption capacity are pursuing issue. In this work, we develop magnetic supramolecular polymer composites (M-SMP) by using a simple two-step hydrothermal method. Systematical characterizations of morphological, chemical and magnetic properties were conducted to confirm the formation of M-SMP composites. The resulting M-SMP composites were applied to remove Pb(II) from aqueous solution and from real battery wastewater, and easy separation was achieved using a permanent magnet. By investigating the effects of various parameters, we optimized their operating condition for Pb(II) adsorption by the M-SMP. The uptake of Pb(II) onto M-SMP fitted well the pseudo-second-order and Langmuir isotherm models, and favourable thermodynamics showed a spontaneous endothermic process. The SMP endowed M-SMP with ultrahigh adsorption capacity for Pb(II) (946.9 mg g-1 at pH = 4.0, T = 298 K), remarkable selectivity, satisfactory stability and desirable recyclability. In Pb-contaminated lead-acid battery industrial wastewater, the concentration of Pb(II) declined from 18.070 mg L-1 to 0.091 mg L-1, which meets the current emission standard for the battery industry. These merits, combined with simple synthesis and convenient separation, make M-SMP an outstanding scavenger for the elimination of industrial Pb(II) wastewater.

Highly effective remediation of Pb(II) and Hg(II) contaminated wastewater and soil by flower-like magnetic MoS2 nanohybrid.

The efficient enrichment and remediation of heavy metals from realistic wastewater and contaminated soil containing large excess of competitive ions remains a daunting challenge by far. In the present study, flower-like molybdenum disulfide decorated with iron oxide nanoparticles (MoS2/Fe3O4) is designed via a two-step hydrothermal method and mainly applied in the removal of Hg(II) and Pb(II) ions in aqueous environment. Exhaustive morphological, chemical and magnetic characterizations verify the successful formation of magnetic MoS2/Fe3O4. Batch adsorption experiments show that the obtained MoS2/Fe3O4 nanohybrid enables efficient capture of Hg(II) and Pb(II) ions, accompanied by ease-of-separation from solution by simply applying a magnet. In this respect, high adsorption capacities (263.6 mg g-1 for Pb(II) and 428.9 mg g-1 for Hg(II)) can be gained under optimized conditions (pH = 5.0; 298 K; nanohybrid dosage: 0.8 g L-1 and the contact time: 180 min). In addition, the effects of different parameters such as initial Pb(II)/Hg(II) concentration (50-500 mg L-1), temperature (298, 308 and 318 K) and co-existing ions (Zn(II), Cu(II), Cd(II) and Mg(II)) were systematically probed. The favorable adsorption capacity, selectivity and recyclability mainly originates from the strong Hg2+/Pb2+···S2- bonding interactions. Practical application potential of magnetic MoS2/Fe3O4 nanohybrid in realistic lead-acid battery industry wastewater and Pb(II)-contaminated soil is further explored, achieving promising results with high Pb(II) removal efficiency of 99.63% for wastewater and 57.15% for soil. Simple preparation, easy separation and high adsorption capacity would foster thus-designed sulfide-based nanohybrid a promising adsorbent for heavy metal removal from wastewater and contaminated soil.

In situ polymerization of magnetic graphene oxide-diaminopyridine composite for the effective adsorption of Pb(II) and application in battery industry wastewater treatment.

The efficient removal of heavy metals from aqueous environment is imperative and challenging. A novel ternary composite constructed of diaminopyridine polymers, graphene oxide, and ferrite magnetic nanoparticles was designed by a facile in situ polymerization strategy for the removal of Pb(II) from aqueous solution. Detailed characterization of morphological, chemical, and magnetic properties was employed systematically to confirm the formation of the composite material. Batch adsorption experiment studies suggested that the composite was an excellent adsorbent for Pb(II) which was easily collected after use via exposure to an external magnetic field for 30 s. The effects of different parameters such as solution pH, adsorbent dosage, contact time, initial Pb(II) concentration, temperature, and co-existing ions were examined. The maximum adsorption capacity at pH = 5 was estimated to be 387.2 mg g-1 at 298 K by the Langmuir isotherm model, accompanied by favorable adsorption recyclability according to the investigation of regeneration experiments. Thermodynamic studies revealed that the Pb(II) adsorption via our ternary composite was endothermic and spontaneous. The corresponding removal performance for effluent containing Pb(II) from the battery industry was successfully examined. The present results indicated that our designed adsorbent is beneficial to the practical Pb(II) removal in wastewater purification.

Parabens and their metabolite in surface water and sediment from the Yellow River and the Huai River in Henan Province: Spatial distribution, seasonal variation and risk assessment.

In this study, six alkyl esters of p-hydroxybenzoic acids (parabens) and their metabolite, 4-hydroxybenzoic acid (p-HB) were simultaneously determined in surface water and sediment from the Yellow River and the Huai River in Henan Province, China. Concentrations of ∑parabens in surface water were 3.31-55.2 ng/L in the Yellow River and 15.0-164 ng/L in the Huai River, while in the sediment, concentrations of ∑parabens were 13.3-37.2 ng/g and 16.1-31.6 ng/g, respectively. Compared with other studies, levels of parabens in the studied area were relatively high in the sediments but middle in the surface water. MeP and PrP were the most abundant parabens, and were detected in all sampling sites. Contributions of EtP, BzP, BuP, and HeP to ∑parabens were each no more than 10%. 4-Hydroxybenzoic acid was found in all samples albeit at low concentrations. Significant positive correlations among parabens suggest similar sources of parabens in the Yellow River and the HuaiRiver. Dissolved organic carbon (DOC) had an important effect on parabens in the surface water of the Yellow and Huai Rivers. Due to low dilution of discharges, high concentrations of parabens were found during moderate precipitation season as well as minimal precipitation season in surface water. However, no apparent seasonal variation of parabens in surface sediment was observed. Hazard quotients showed that the ecological risks of parabens was low in the studied area.

An improved quantification method for 12 linear dimethylsiloxanes and 1 cyclic dimethylsiloxane in polydimethylsiloxane using gas chromatography-flame ionization detector：Development strategy and accuracy.

PDMS 200 fluid (the mixture) was used as standard for quantification of linear dimethylsiloxanes (L5-L16) in environmental matrices. However, the quantification of individual dimethylsiloxane in PDMS 200 fluid by GC-FID was not established or detailed described in many real studies. To solve this problem, we did this research and the principal results were as follows: fifteen compounds in PDMS 200 fluid, including D7, L5 to L16 (12 linear dimethylsiloxanes) and 2 unknown compounds, were identified using GC-MS. Retention indices (RI) of L8 to L16 were first given. Meanwhile, we found that the "effective carbon number (ECN) concept" was applicable for responses of dimethylsiloxanes in FID. Based on GC-FID, a new quantification method for compounds in PDMS 200 fluid was established, detailed described and used to calculate the content of individual dimethylsiloxane in PDMS 200 fluid. Compared with the results from external standard method, internal standard method and normalization method, the new quantification method was more accurate and stable, especially for D7 at low content.