Deep decarbonization potential and implementation path under provincial differences in China's fleet electrification.

Fleet electrification is considered to be an important measure for reducing carbon emissions in the road transport industry. Considering the heterogeneity of the NEV market penetration and the vehicle types in different provinces, how to design targeted and time-sequenced road transport decarbonisation reduction strategies has become a key issue that needs to be discussed urgently. In this study, the NEVs ownership in China's 31 provinces is used as an intermediate variable. Considering the process of energy transition and changes in vehicle structure, a two-layer scenario framework that combines Shared Socioeconomic Pathways scenarios and model structure was developed to predict carbon emissions. This study firstly analyzes the electrification process and carbon emission reduction potential of provincial road transport industry by region, vehicle type and stage. The potential for reducing carbon emissions was determined under benchmark, transition, and electrification scenarios. The results indicate that the Pearson Correlation Coefficient-Discrete Wavelet Transform-Bidirectional Long Short-term Memory prediction model has an mean absolute percentage error of 8.583 and an R-squared of 0.975. China's road transportation industry total carbon emissions will reach its peak as early as 2027, due to the rapid implementation of renewable energy and fleet electrification. Shanghai, Jiangsu, Shandong, Henan, and Guangdong have set carbon peak targets that can be achieved faster with the transition plan for new energy vehicles to replace fossil fuel vehicles. This paper proposes a timing-responsive deep decarbonization path and policy recommendations for China's road transport industry in sub provincial and time-series settings.

The past 10 years of molecular ferroelectrics: structures, design, and properties.

Ferroelectricity, which has diverse important applications such as memory elements, capacitors, and sensors, was first discovered in a molecular compound, Rochelle salt, in 1920 by Valasek. Owing to their superiorities of lightweight, biocompatibility, structural tunability, mechanical flexibility, etc., the past decade has witnessed the renaissance of molecular ferroelectrics as promising complementary materials to commercial inorganic ferroelectrics. Thus, on the 100th anniversary of ferroelectricity, it is an opportune time to look into the future, specifically into how to push the boundaries of material design in molecular ferroelectric systems and finally overcome the hurdles to their commercialization. Herein, we present a comprehensive and accessible review of the appealing development of molecular ferroelectrics over the past 10 years, with an emphasis on their structural diversity, chemical design, exceptional properties, and potential applications. We believe that it will inspire intense, combined research efforts to enrich the family of high-performance molecular ferroelectrics and attract widespread interest from physicists and chemists to better understand the structure-function relationships governing improved applied functional device engineering.

Organic-Inorganic Hybrid Perovskite Ferroelectric Nanosheets Synthesized by a Room-Temperature Antisolvent Method.

Over the past years, the application potential of ferroelectric nanomaterials with unique physical properties for modern electronics is highlighted to a large extent. However, it is relatively challenging to fabricate inorganic ferroelectric nanomaterials, which is a process depending on a vacuum atmosphere at high temperatures. As significant complements to inorganic ferroelectric nanomaterials, the nanomaterials of molecular ferroelectrics are rarely reported. Here a low-cost room-temperature antisolvent method is used to synthesize free-standing 2D organic-inorganic hybrid perovskite (OIHP) ferroelectric nanosheets (NSs), that is, (CHA)2PbBr4 NSs (CHA = cyclohexylammonium), with an average lateral size of 357.59 nm and a thickness ranging from 10 to 70 nm. This method shows high repeatability and produces NSs with excellent crystallinity. Moreover, ferroelectric domains in single NSs can be clearly visualized and manipulated using piezoresponse force microscopy (PFM). The domain switching and PFM-switching spectroscopy indicate the robust in-plane ferroelectricity of the NSs. This work not only introduces a feasible, low-cost, and scalable method for preparing molecular ferroelectric NSs but also promotes the research on molecular ferroelectric nanomaterials.

SHG Assisted Mixed-Phases Anatomizing in a Molecular Ferroelectric.

Anatomizing mixed-phases, referring to analyzing the mixing profiles and quantifying the phases' proportions in a material, which is of great significance in the genuine applications. Here, by using second-harmonic generation (SHG) polarimetry and piezoresponse force microscopy (PFM) techniques, this work elucidates the contributions and distributions of two different symmetric phases mixed in an archetype monoaxial molecular ferroelectric, diisopropylammonium chloride (DIPACl). The two competing phases are preferred in thermodynamics or kinetic process respectively, and this work evidences the switching behavior between the two competing phases facilitated by an external electrical field as opposed to a heating process. This research contributes novel insights into phase engineering in the field of molecular ferroelectrics and is poised to serve as a potent analytical tool for subsequent applications.