ABSTRACT
In this study, an electrostatically induced quantum confinement structure, so-called quantum point contact, has been realized in a p-type trilayer tungsten diselenide-based van der Waals heterostructure with modified van der Waals contact method with degenerately doped transition metal dichalcogenide crystals. Clear quantized conductance and pinch-off state through the one-dimensional confinement were observed by dual-gating of split gate electrodes and top gate. Conductance plateaus were observed at a step of e2/h in addition to quarter plateaus such as 0.25 × 2e2/h at a finite bias voltage condition indicating the signature of intrinsic spin-polarized quantum point contact.
ABSTRACT
The continued reduction of semiconductor device feature sizes towards the single-digit nanometer regime involves a variety of quantum effects. Modeling quantum effects in phase space in terms of the Wigner transport equation has evolved to be a very effective approach to describe such scaled down complex systems, accounting from full quantum processes to dissipation dominated transport regimes including transients. Here, we discuss the challanges, myths, and opportunities that arise in the study of these complex systems, and particularly the advantages of using phase space notions. The development of particle-based techniques for solving the transport equation and obtaining the Wigner function has led to efficient simulation approaches that couple well to the corresponding classical dynamics. One particular advantage is the ability to clearly illuminate the entanglement that can arise in the quantum system, thus allowing the direct observation of many quantum phenomena.
ABSTRACT
We use dispersion-corrected density functional theory to explore the bridge-site asymmetry for methanethiol adsorbed on Au(111) with two different S-C bond orientations. We attribute the asymmetry to the intrinsic character of the Au(111) surface rather than the adsorbate. The preference for bridge-fcc versus bridge-hcp SCH3 adsorption sites is controlled by the S-C bond orientation. The system energy difference favors the bridge-fcc site by 8.1 meV on the unrelaxed Au(111) surface. Relaxing the Au substrate increased this energy difference to 26.1 meV. This asymmetry is also reflected in the atomic displacement of the relaxed Au surface. Although in both cases, the bridge-site Au atoms shift away from the fcc 3-fold hollow site, the motion is greater for the bridge-fcc allowing a more favorable geometry for the sulfur atom to bond to the bridging atoms. We confirm that the adsorption energy is strongly dependent on the S-C bond orientation and position, which can be understood in terms of a simple coordination geometry model. This work has important implications for alkanethiol surface diffusion and the structure of their self-assembled monolayers.
ABSTRACT
We exploit scanning-probe-controlled domain patterning in a ferroelectric top layer to induce nonvolatile modulation of the conduction characteristic of monolayer MoS_{2} between a transistor and a junction state. In the presence of a domain wall, MoS_{2} exhibits rectified I-V characteristics that are well described by the thermionic emission model. The induced Schottky barrier height Φ_{B}^{eff} varies from 0.38 to 0.57 eV and is tunable by a SiO_{2} global back gate, while the tuning range of Φ_{B}^{eff} depends sensitively on the conduction-band-tail trapping states. Our work points to a new route to achieving programmable functionalities in van der Waals materials and sheds light on the critical performance limiting factors in these hybrid systems.
ABSTRACT
A flake of monolayer graphene was sandwiched between boron nitride sheets. Temperature dependent Shubnikov-de Haas measurements were performed to access how this technique influences the electronic properties of the graphene sample. The maximum mobility found in this configuration was approximately 105 cm2 Vs -1. From the phase of the oscillations a Berry phase ß of 1/2 was obtained indicating the presence of Dirac fermions. We obtained Fermi velocities around [Formula: see text] m s-1 which imply hopping energies close to 2.5 eV. Furthermore, the carrier lifetime is typically higher than that found in graphene supported by SiO2, reaching values higher than 700 fs.
ABSTRACT
The fluctuations in the conductance of graphene that arise from a long-range disorder potential induced by random impurities are investigated with an atomic tight-binding lattice. The screened impurities lead to a slow variation of the background potential and this varies the overall potential landscape as the Fermi energy or an applied magnetic field is varied. As a result, the phase interference varies randomly and leads to fluctuations in the conductance. Recently, experiments have shown that an applied magnetic field produces a remarkable reduction in the amplitude of these conductance fluctuations. We find qualitative agreement with these experiments, and it appears that the reduction in magnetic field of the fluctuations arises from a field induced smoothing of the conductance landscape.
ABSTRACT
The theoretical understanding of electron transport in graphene and graphene nanoribbons is reviewed, emphasizing the help provided by atomic pseudopotentials (self-consistent and empirical) in determining not only the band structure but also other fundamental transport parameters such as electron-phonon matrix elements and line-edge roughness scattering. Electron-phonon scattering in suspended graphene sheets, impurity and remote-phonon scattering in supported and gated graphene, electron-phonon and line-edge roughness scattering in armchair-edge nanoribbons are reviewed, keeping in mind the potential use of graphene in devices of the future very large scale integration technology.
ABSTRACT
A small forbidden gap matched to low-energy photons (meV) and a quasi-Dirac electron system are both definitive characteristics of bilayer graphene (GR) that has gained it considerable interest in realizing a broadly tunable sensor for application in the microwave region around gigahertz (GHz) and terahertz (THz) regimes. In this work, a systematic study is presented which explores the GHz/THz detection limit of both bilayer and single-layer graphene field-effect transistor (GR-FET) devices. Several major improvements to the wiring setup, insulation architecture, graphite source, and bolometric heating of the GR-FET sensor were made in order to extend microwave photoresponse past previous reports of 40 GHz and to further improve THz detection.
ABSTRACT
Quantum interference causes a wavefunction to have sensitive spatial dependence, and this has a significant effect on quantum transport. For example, in a quantum-dot system, the conductance can depend on the lead positions. We investigate, for graphene quantum dots, the conductance variations with the lead positions. Since for graphene the types of boundaries, e.g., zigzag and armchair, can fundamentally affect the quantum transport characteristics, we focus on rectangular graphene quantum dots, for which the effects of boundaries can be systematically studied. For both zigzag and armchair horizontal boundaries, we find that changing the positions of the leads can induce significant conductance variations. Depending on the Fermi energy, the variations can be either regular oscillations or random conductance fluctuations. We develop a physical theory to elucidate the origin of the conductance oscillation/fluctuation patterns. In particular, quantum interference leads to standing-wave-like-patterns in the quantum dot which, in the absence of leads, are regulated by the energy-band structure of the corresponding vertical graphene ribbon. The observed 'coexistence' of regular oscillations and random fluctuations in the conductance can be exploited for the development of graphene-based nanodevices.
Subject(s)
Electric Conductivity , Electrochemistry , Graphite/chemistry , Quantum Dots , Quantum Theory , Models, ChemicalABSTRACT
The concentrations of wave functions about classical periodic orbits, or quantum scars, are a fundamental phenomenon in physics. An open question is whether scarring can occur in relativistic quantum systems. To address this question, we investigate confinements made of graphene whose classical dynamics are chaotic and find unequivocal evidence of relativistic quantum scars. The scarred states can lead to strong conductance fluctuations in the corresponding open quantum dots via the mechanism of resonant transmission.
ABSTRACT
We have studied the transport properties of graphene transistors in different solvents with dielectric constant varying over 2 orders of magnitude. Upon increasing the dielectric constant, the carrier mobility increases up to 3 orders of magnitude and reaches approximately 7 x 10(4) cm(2)/v.s at the dielectric constant of approximately 47. This mobility value changes little in higher dielectric constant solvents, which indicates that we are approaching the intrinsic limit of room temperature mobility in graphene supported on SiO(2) substrates. The results are discussed in terms of long-range Coulomb scattering originated from the charged impurities underneath graphene.
Subject(s)
Electronics , Graphite/chemistry , Silicon Dioxide/chemistry , Solvents/chemistry , Transistors, ElectronicABSTRACT
We study electronic transport in quantum-dot structures made of graphene. Focusing on the rectangular dot geometry and utilizing the non-equilibrium Green's function to calculate the transmission in the tight-binding framework, we find significant fluctuations in the transmission as a function of the electron energy. The fluctuations are correlated with the formation of quantum scarring states, or pointer states in the dot. Both enhancement and suppression of transmission have been observed. As the size of the quantum dot is increased, more scarring states can be formed, leading to stronger transmission or conductance fluctuations.
ABSTRACT
Over the past two decades, quantum computing has become a popular and promising approach to trying to solve computationally difficult problems. Missing in many descriptions of quantum computing is just how probability enters into the process. Here, we discuss some simple examples of how uncertainty and probability enter, and how this and the ideas of quantum computing challenge our interpretations of quantum mechanics. It is found that this uncertainty can lead to intrinsic decoherence, and this raises challenges for error correction.
ABSTRACT
Full understanding of the relaxation mechanisms and far-from-equilibrium transport in modern mesoscopic structures requires that such systems be treated as open. We therefore generalize some of the core elements of the Kadanoff-Baym-Keldysh nonequilibrium Green's function formalism, inherently formulated for closed systems, to treatment of an open system, coupled with its environment. We define the two-time correlation functions and analyze the influence of the memory effects on the open-system transport. In the transient regime, the two-time correlation functions clearly show four distinct terms: a closed-system-like term, an entanglement term, and two memory terms that depend explicitly on the initial state of the environment. We show that it is not possible to completely eliminate the influence of the environment by a fortunate choice of the initial state, and approximating the system as closed is valid only in the limit of negligible system-environment coupling, which is never the case in the transient regime. We derive the transport equations for transients that properly account for the system-environment coupling. On the other hand, we address the important issue of transport in a far-from-equilibrium steady state. We show that, once a steady state is reached, the balance between the driving and relaxation forces implies that the two-time correlation functions regain a closed-system-like form, but with an effective, modified system Hamiltonian, and with the system statistical operator unrelated to that of the initial state. We emphasize that the difference between the transient and the far-from-equilibrium steady-state regimes, crucial for theoretical investigation of nonequilibrium quasiparticle transport, effectively lies within the different relative magnitude of the combined entanglement and memory terms with respect to the closed-system-like term in two-time correlation functions.
ABSTRACT
Evolution of a system, coupled to its environment and influenced by external driving fields, is an old problem that remains of interest. In this paper, we derive an equation of motion for the reduced system density matrix, which is time convolutionless and free of the partial trace with respect to the environment states. This new approach uses an extension of the projection-operator technique, which incorporates an isomorphism between the system's Liouville space and the unit eigenspace of the projection operator induced by the uniform environment density matrix. Numerical application of the present approach is particularly useful in large externally driven systems, as the partial-trace-free equation is given in terms of submatrices significantly smaller than the matrices in the conventional time-convolutionless approaches, which alleviates the computational burden. We also show that all time-convolutionless approaches, conventional or partial-trace-free, are based upon a hidden underlying assumption of time reversibility of the system's evolution. This feature puts significant constraints on applicability of time-convolutionless approaches when employing approximations that yield time irreversibility. Also, we investigate the application of the approach in the description of far-from-equilibrium systems.
ABSTRACT
We argue that many major features in electronic transport in realistic quantum dots are not explainable by the usual semiclassical approach, due to the contributions of the quantum-mechanical tunneling of the electrons through the Kolmogorov-Arnol'd-Moser islands. We show that dynamical tunneling gives rise to a set of resonances characterized by two quantum numbers, which leads to conductance oscillations and concentration of wave functions near stable and unstable periodic orbits. Experimental results agree very well with our theoretical predictions, indicating that tunneling has to be taken into account to understand the physics of transport in generic nanostructures.