Bentonite SDBS-loaded composite for methylene blue removal from wastewater: An experimental and theoretical investigation.

This study addresses the urgent need for practical solutions to industrial water contamination. Utilizing Algerian Bentonite as an adsorbent due to its regional prevalence, we focused on the efficiency of the Bentonite/Sodium dodecylbenzene sulfonate (SDBS) matrix in Methylene Blue (MB) removal. The zero-charge point and IR spectroscopy characterized the adsorbent. Acidic pH facilitated SDBS adsorption on Bentonite, achieving equilibrium in 30 min with a pseudo-second-order model. The UPAC and Freundlich model indicated a qmax of 25.97 mg/g. SDBS adsorption was exothermic at elevated temperatures. The loaded Bentonite exhibited excellent MB adsorption (pH 3-9) with PSOM kinetics. Maximum adsorption capacity using IUPAC and GILES-recommended isotherms was qmax = 23.54 mg/g. The loaded Bentonite's specific surface area was 70.01 m2/g, and the Sips model correlated well with experimental data (R2 = 0.98). This study highlights adsorption, mainly Bentonite/SDBS matrices, as a promising approach for remediating polluted areas by efficiently capturing and removing surfactants and dyes, contributing valuable insights to address industrial water contamination challenges.

Optimization and validation of a bioanalytical HPLC-UV technique for simultaneous determination of underivatized phenylalanine and tyrosine in the blood for phenylketonuria diagnosis and monitoring.

This study aimed to develop a fast, accurate, and precise high-performance liquid chromatography with UV detection method for simultaneous analysis of underivatized phenylalanine (Phe) and tyrosine (Tyr) in biological samples. Separation of the analytes was accomplished using a Discovery HS F5-3 column, which offered better retention and peak symmetry for the tested analytes. Chromatographic conditions were optimized using central composite experimental design, and three factors were investigated: the concentration of ammonium acetate (A), the acetonitrile proportion in the mobile phase (B) and the column oven temperature (C). The approach was verified using ß-expectation tolerance intervals for total error measurement that did not exceed 15%. Optimal settings were A = 50 mm, B = 24% and C = 28°C. The method applicability was determined using human plasma from 75 volunteers. The limits of detection and quantification of the technique were satisfactory at 9 and 29 µm for Phe and 4 and 13 µm for Tyr. The mean analytical bias in spiking levels was acceptable, ranging from -1.649 to +1.659% for both substances, with RSD <5% in all instances. The suggested approach was successfully used to analyze Phe and Tyr in human blood samples and calculate the Phe/Tyr ratio.

Study of the effect of current intensity on the structural performance of electrogenerated mesoporous aluminum phosphate: application for adsorption.

To keep up with the development of contaminants in the water supply, it is required to create new adsorbents or improve current ones. The adsorption capacity of AlPO4 electrocoagulated with varying current intensities was examined. AlPO4 was produced by electrolysis in a NaCl solution using aluminum electrodes and a 0.1 M phosphate buffer at varying current intensities. Current efficiency was enhanced. X-ray diffraction (XRD), scanning electron microscopy (SEM), and Fourier transform infrared spectroscopy were used to analyze the adsorbents (FTIR). The specific surface area was estimated by the quantity of methylene blue adsorbed by particles in an aqueous solution. Numerous operating factors must be addressed, including pH, starting concentration, adsorbent dose, and contact duration. The electrostatic interaction between positively charged MB molecules and negatively charged adsorbents drives adsorption at alkaline pH. When describing equilibrium adsorption, the Langmuir model is more accurate. Modeling using an adsorption isotherm may further improve the predicted specific surface area. At 0.2 amperes, the observed specific surface area was 2.86 m2/g.