ABSTRACT
Anodization coloring of titanium tools or implants is one of the common methods for the differentiation of each application by its size or type. Commercial purity titanium grade 4 plates (50 × 20 × 0.1 mm) were tested to obtain their electrochemical and other technological properties. The coloring process was done using the potential of 15, 30, 45, 60, and 75 Volts for 5 s in 1 wt. % citric acid in demineralized water solution. Organic acids solutions generally produce better surface quality compared to inorganic acids. The contact angle of colored surfaces was measured by the sessile drop method. Electrochemical impedance spectroscopy and potentiodynamic polarization were used for the determination of selected electrochemical and corrosion parameters of the tested surfaces. It was found that the anodization process decreases corrosion potential significantly. It was also confirmed that a higher potential used for anodization results in higher polarization resistance but also a decrease in corrosion potential. The anodization process at 75 V produces surfaces with the lowest corrosion rate under 1 nm/year and the noblest corrosion potential. It was confirmed that the anodization process in citric acid does not affect titanium cytotoxicity.
ABSTRACT
This article represents a multidisciplinary approach to biomechanics (engineering + medicine) in the field of "collum femoris" fractures. One possible treatment method for femoral neck fractures, especially for young people, is the application of cancellous (i.e. lag or femoral) screws (with full or cannulated cross-section) made of Ti6Al4V or stainless steel. This paper therefore aims to offer our own numerical model of cancellous screws together with an assessment of them. The new, simple numerical model presented here is derived together with inputs and boundary conditions and is characterized by rapid solution. The model is based on the theory of beams on an elastic foundation and on 2nd order theory (set of three differential 4th order equations, combination of pressure and bending stress-deformation states). It presents the process for calculating displacements, slopes, bending moments, stresses etc. Two examples (i.e. combinations of cancellous screws with full or cannulated cross-section made of stainless steel or Ti6Al4V material) are presented and evaluated (i.e. their displacement, slopes, bending moments, normal forces, shearing forces and stresses). Future developments and other applications are also proposed and mentioned.
ABSTRACT
Paper focuses on biomechanics, specifically on locking cortical bone screws in angularly stable plates used for the treatment of bone fractures in the medical fields of traumatology and orthopaedics. During extraction of titanium-alloy implants, problems are encountered in an effort to loosen some locking bone screws from the locking holes of an angularly stable plate and the subsequent stripping of the internal hexagon of the screw head. The self-locking of the screw-plate threaded joint was verified by calculation and the effect of the angle of the thread on the head of the locking cortical bone screw on self-locking was evaluated. The magnitude of the torque, causing the stripping of the internal hexagon (the Inbus type head) of a locking cortical bone screw with a shank diameter of 3.5 mm from Ti6Al4 V titanium alloy to ISO 5832-3, was determined experimentally. Also, it was experimentally found that the rotation of the screwdriver end with a hexagonal tip inside the locking cortical bone screw head during stripping of the internal hexagon causes strain of the screw head perimeter and thereby an increase of thread friction. The effect of tightening torque on the possibility of loosening of the locking cortical bone screw from the locking hole of an angularly stable plate was assessed experimentally. From the evaluation of five alternative shapes of locking cortical bone screw heads in terms of the acting stress and generated strains, it follows that the best screw is the screw with the Torx type head, which demonstrates the lowest values of reduced stress and equivalent plastic strain. Based on experiments and simulations the authors recommend that all global producers of locking cortical bone screws for locking holes of angularly stable plates use the Torx type heads, and not heads of the Inbus type or the Square, PH, PZ types.
ABSTRACT
The paper addresses laboratory preparation and antibacterial activity testing of kaolinite/nanoTiO2 composite in respect of the daylight irradiation time. Kaolinite/nanoTiO2 composites with 20 and 40 wt% of TiO2 were laboratory prepared, dried at 105 °C and calcined at 600 °C. The calcination caused transformation of kaolinite to metakaolinite and origination of the metakaolinite/nanoTiO2 composite. X-ray powder diffraction, Raman and FTIR spectroscopic methods revealed titanium dioxide only in the form of anatase in all evaluated samples (non-calcined and calcined) and also transformation of kaolinite to metakaolinite after the calcination treatment. Scanning electron microscopy was used as a method for characterization of morphology and elemental composition of the studied samples. A standard microdilution test was used to determine the antibacterial activity using four human pathogenic bacterial strains (Staphylococcus aureus, Escherichia coli, Enterococcus faecalis, Pseudomonas aeruginosa). A lamp with a wide spectrum bulb simulating daylight was used for induction of photocatalysis. The antibacterial assays found all the KATI samples to have antibacterial potency with different onset of the activity when calcined samples exhibited antibacterial activity earlier than the non-calcined. Significant difference in antibacterial activity of KATI samples for different bacterial strains was not observed.
