1.
Molecules
; 13(11): 2837-47, 2008 Nov 14.
Article
in English
| MEDLINE
| ID: mdl-19015623
ABSTRACT
A study of microwave-induced and standard thermal Overman rearrangement of selected allylic trichloroacetimidates 1a-1f, 6-8 to the corresponding acetamides 2a-2f, 9-11 is reported. The microwave-assisted rearrangement of trifluoroacetimidate 13 is also described. Using this methodology, an efficient access to versatile allylic trihaloacetamides building synthons was established.