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Chem Commun (Camb) ; 59(74): 11089-11092, 2023 Sep 14.
Article in English | MEDLINE | ID: mdl-37642316

ABSTRACT

We herein report a direct and efficient protocol for phosphorylation of quinoxalines, which employs aerobic oxygen as the green oxidant under catalyst-free conditions. This methodology represents one of the most environmentally friendly and easily handled protocols, providing a series of phosphorylated quinoxalines in good to excellent yields. Control experiments clearly indicated that the reaction followed a dearomatization-rearomatization strategy.

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