Surface Functional Groups Affect Iron (Hydr)oxide Heterogeneous Nucleation: Implications for Membrane Scaling.

Because of its favorable thermodynamics and fast kinetics, heterogeneous solid nucleation on membranes triggers early-stage mineral scaling. Iron (hydr)oxide, a typical membrane scale, initially forms as nanoparticles that interact with surface functional groups on membranes, but these nanoscale phenomena are difficult to observe in real time. In this study, we utilized in situ grazing incidence small angle X-ray scattering and ex situ atomic force microscopy to examine the heterogeneous nucleation of iron (hydr)oxide on surface functional groups commonly used in membranes, including hydroxyl (OH), carboxyl (COOH), and fluoro (F) groups. We found that, compared to nucleation on hydrophilic OH- and COOH-surfaces, the high hydrophobicity of an F-modified surface significantly reduced the extents of both heterogeneously and homogeneously formed iron (hydr)oxide nucleation. Moreover, on the OH-surface, the high functional group density of 0.76 nmol/cm2 caused faster heterogeneous nucleation than that on a COOH-surface, with a density of 0.28 ± 0.04 nmol/cm2. The F-surface also had the highest heterogeneous nucleation energy barrier (26 ± 0.6 kJ/mol), followed by COOH- (23 ± 0.8 kJ/mol) and OH- (20 ± 0.9 kJ/mol) surfaces. The kinetic and thermodynamic information provided here will help us better predict the rates and extents of early-stage scaling of iron (hydr)oxide nanoparticles in membrane processes.

Classical and Nonclassical Nucleation and Growth Mechanisms for Nanoparticle Formation.

All solid materials are created via nucleation. In this evolutionary process, nuclei form in solution or at interfaces, expand by monomeric growth and oriented attachment, and undergo phase transformation. Nucleation determines the location and size of nuclei, whereas growth controls the size, shape, and aggregation of newly formed nanoparticles. These physical properties of nanoparticles can affect their functionalities, reactivities, and porosities, as well as their fate and transport. Recent advances in nanoscale analytical technologies allow in situ real-time observations, enabling us to uncover the molecular nature of nuclei and the critical controlling factors for nucleation and growth. Although a single theory cannot yet fully explain such evolving processes, we have started to better understand how both classical andnonclassical theories can work together, and we have begun to recognize the importance of connecting these theories. This review discusses the recent convergence of knowledge about the nucleation and growth of nanoparticles.

Effects of MoS2 Layer Thickness on Its Photochemically Driven Oxidative Dissolution.

The distinctive optical and electronic properties of two-dimensional (2D) molybdenum disulfide (MoS2) make it a promising photocatalyst and photothermal agent in aqueous applications. In terms of environmental stability, MoS2 has been considered insoluble, but 2D MoS2 nanosheets can be susceptible to dissolution, owing to their large surface areas and highly accessible reactive sites, including defects at the basal plane and edge sites. Under light illumination, the dissolution of 2D MoS2 nanosheets can be further accelerated by their photochemical reactivity. To elucidate MoS2 reactivity in the environment, here we investigated the thickness-dependent dissolution of MoS2 under illumination. To synthesize nanoscale thicknesses of MoS2, we exfoliated bulk MoS2 by ultrasonication and controlled the layer thickness by iterative cascade centrifugation, producing MoS2 nanosheets averaging either ∼18 nm or ∼46 nm thick, depending on the centrifugation rate. Under simulated sunlight, MoS2 dissolution was accelerated, the Mo6+ composition increased, and the solution pH decreased compared to those in the dark. These results suggest that light exposure promotes the oxidation of MoS2, causing faster dissolution. Importantly, 18 nm thick MoS2 exhibited faster dissolution than either 46 nm or bulk MoS2, driven by the superoxide radical (O2•-) generation promoted by its relative thinness. These findings highlight the important role of the thickness-dependent photochemistry of MoS2 nanosheets in their dissolution, which is directly linked to their environmental behavior and stability.

Cellulose Nanomaterials in Interfacial Evaporators for Desalination: A "Natural" Choice.

Herein, the recent advances in realizing highly efficient cellulose-based solar evaporators for alleviating the global water crisis are summarized. Fresh water scarcity is one of the most threatening issues for sustainable development. Solar steam generation, which harnesses the abundant sunlight, has been recognized as a sustainable approach to harvest fresh water. In contrast to synthetic polymeric materials that can pose serious negative environmental impacts, cellulose-based materials, owing to their biocompatibility, renewability, and sustainability, are highly attractive for realizing solar steam generators. The molecular and macromolecular features of cellulose and the physicochemical properties of extracted cellulose nanoparticles (cellulose nanocrystals and cellulose nanofibrils (CNF)) and natural cellulose materials (wood and bacterial nanocellulose (BNC)) that make them attractive as supporting substrate materials in solar steam generators are briefly discussed. Recent progress in designing highly efficient cellulose-based solar evaporators, including utilizing extracted cellulose nanoparticles via bottom-up assembly CNF, natural cellulose materials with intrinsic hierarchical structure (wood and BNC), and commercial planar cellulose substrates (air-laid paper, cellulose paper, and cotton fabric) is reviewed. The outstanding challenges that need to be addressed for these materials and devices to be utilized in the real-world and in overcoming global water crisis are also briefly highlighted.

Photothermal Membrane Water Treatment for Two Worlds.

In meeting the increasing need for clean water in both developing and developed countries and in rural and urban communities, photothermal membrane water treatment technologies provide outstanding advantages: For developing countries and rural communities, by utilizing sunlight, photothermal membrane water treatment provides inexpensive, convenient, modular, decentralized, and accessible ways to clean water, which can reduce the consumption of conventional energy (e.g., electricity, natural gas) and the cost of clean water production. In developed countries and urban communities, photothermal membrane water treatment can improve the energy efficiency during water purification. In these water purification processes, the light absorption and light-to-heat conversion of photothermal materials are important factors in determining the membrane efficacy. Nanomaterials with well-controlled structure and optical properties can increase the light absorption and photothermal conversion of newly developed membranes. This Account introduces our recent work on developing scalable, cost-effective, and highly efficient photothermal membranes for four water purification applications: reverse osmosis (RO), ultrafiltration (UF), solar steam generation (SSG), and photothermal membrane distillation (PMD). By utilizing photothermal materials, first, we have demonstrated how sunlight can be used to improve the membrane's resistance to biofouling in RO and UF processes by photothermally induced inactivation of microorganisms. Second, we have developed novel SSG membranes (i.e., interfacial evaporators) that can harvest solar energy, convert it to localized heat, and generate clean water by evaporation. This desalination approach is particularly useful and promising for treatment of highly saline water. These new interfacial evaporators utilized graphene oxide (GO), reduced graphene oxide (RGO), molybdenum disulfide (MoS2), and polydopamine (PDA). The solar conversion efficiency and environmental sustainability of the interfacial evaporators were optimized via (i) novel and versatile bottom-up biofabrication (e.g., incorporation of photothermal materials during bacterial nanocellulose (BNC) growth) and (ii) easy and cost-effective top-down preparation (e.g., modification of natural wood with photothermal materials). Third, we have developed membranes for PMD that incorporate photothermal materials to generate heat under solar irradiation, thus providing a higher transmembrane temperature difference and higher driving force for effective vapor transport, making the membrane distillation process more energy-efficient. Lastly, this Account compares the photothermal membrane applications, summarizes current challenges for photothermal membrane applications, and offers future directions to facilitate the translation of photothermal membranes from the laboratory to large engineered systems by improving their scalability, stability, and sustainability.

Photothermally Active Reduced Graphene Oxide/Bacterial Nanocellulose Composites as Biofouling-Resistant Ultrafiltration Membranes.

Biofouling poses one of the most serious challenges to membrane technologies by severely decreasing water flux and driving up operational costs. Here, we introduce a novel anti-biofouling ultrafiltration membrane based on reduced graphene oxide (RGO) and bacterial nanocellulose (BNC), which incoporates GO flakes into BNC in situ during its growth. In contrast to previously reported GO-based membranes for water treatment, the RGO/BNC membrane exhibited excellent aqueous stability under environmentally relevant pH conditions, vigorous mechanical agitation/sonication, and even high pressure. Importantly, due to its excellent photothermal property, under light illumination, the membrane exhibited effective bactericidal activity, obviating the need for any treatment of the feedwater or external energy. The novel design and in situ incorporation of the membranes developed in this study present a proof-of-concept for realizing new, highly efficient, and environmental-friendly anti-biofouling membranes for water purification.

Catalytically Active Bacterial Nanocellulose-Based Ultrafiltration Membrane.

Large quantities of highly toxic organic dyes in industrial wastewater is a persistent challenge in wastewater treatment processes. Here, for highly efficient wastewater treatment, a novel membrane based on bacterial nanocellulose (BNC) loaded with graphene oxide (GO) and palladium (Pd) nanoparticles is demonstrated. This Pd/GO/BNC membrane is realized through the in situ incorporation of GO flakes into BNC matrix during its growth followed by the in situ formation of palladium nanoparticles. The Pd/GO/BNC membrane exhibits highly efficient methylene orange (MO) degradation during filtration (up to 99.3% over a wide range of MO concentrations, pH, and multiple cycles of reuse). Multiple contaminants (a cocktail of 4-nitrophenol, methylene blue, and rhodamine 6G) can also be effectively treated by Pd/GO/BNC membrane simultaneously during filtration. Furthermore, the Pd/GO/BNC membrane demonstrates stable flux (33.1 L m-2 h-1 ) under 58 psi over long duration. The novel and robust membrane demonstrated here is highly scalable and holds a great promise for wastewater treatment.