Molten-Volcanic-Ash-Phobic Thermal Barrier Coating based on Biomimetic Structure.

Volcanic ash is a major threat to aviation safety. The softening/melting temperatures of volcanic ash lie far below typical aero-engine operating temperatures. Thus, molten ash can accelerate the failure of thermal barrier coatings (TBCs). Here, inspired by natural superhydrophobic surfaces (e.g., the lotus leaf), a molten-volcanic-ash-phobic TBC, which provides a large possibility to eliminate molten ash issues of TBCs, is developed. A hierarchically structured surface is first prepared on a (Gd0.9 Yb0.1 )2 Zr2 O7 (GYbZ) pellet by ultrafast laser direct writing technology, aiming to confirm the feasibility of the biomimetic microstructure to repel molten volcanic ash wetting. Then biomimetic-structured GYbZ TBCs are successfully fabricated using plasma spray physical vapor deposition, which reveals "silicate" phobicity at high temperatures. The exciting molten-volcanic-ash-phobic attribute of the designed surfaces is attributed to the lotus-leaf-like dual-scale microstructure, emulating in particular the existence of nanoparticles. These findings may be an important step toward the development of next-generation aviation engines with greatly reduced vulnerability to environmental siliceous debris.

Silver nanoparticles decorated meta-aramid nanofibrous membrane with advantageous properties for high-performance flexible pressure sensor.

Flexible pressure sensors have received tremendous attention for various wearable applications. However, it remains a critical challenge to develop a flexible pressure sensor with excellent sensitivity performances and multiple advantageous properties. Herein, a high-performance flexible piezoresistive pressure sensor PMIA@PDA@Ag was developed, which sensitive component is consisted of Ag nanoparticles decorated polydopamine (PDA)-modified meta-aramid (poly(m-phenylene isophthalamide), PMIA) nanofibrous membrane. The PMIA@PDA@Ag pressure sensor shows excellent mechanical, thermal insulation, antibacterial and breathable properties, as well as remarkable sensing performances including high sensitivity, wide detectable pressure range, rapid response speed and good cyclic durability. In addition, it also shows great sensing performances in monitoring various human behaviors in real-time, including large-scale motions and subtle physiological signals.