ABSTRACT
We herein report a case of encapsulating peritoneal sclerosis (EPS) in a patient without chronic kidney disease after gastrectomy. A 69-year-old man underwent distal gastrectomy for early gastric cancer at 25 years old. After 43 years, he developed bowel obstruction and underwent enterolysis of the encapsulated small intestine. A pathological examination of the capsular membranes revealed inflammation, foam, and giant cells that destroyed foreign substances. The patient was discharged 1.5 months later. Foreign body reactions to surgical instruments used in gastrectomy are considered a cause of EPS. EPS due to foreign body reactions to surgical instruments should also be considered in such cases.
Subject(s)
Foreign Bodies , Peritoneal Fibrosis , Stomach Neoplasms , Aged , Humans , Male , Foreign Bodies/complications , Gastrectomy/adverse effects , Peritoneal Fibrosis/diagnostic imaging , Peritoneal Fibrosis/etiology , Peritoneal Fibrosis/surgery , Peritoneum , Sclerosis , Stomach Neoplasms/pathologyABSTRACT
An axial-substituted silicon phthalocyanine derivative, SiPc(OR)2 (R = C4H9), that is soluble in organic solvent is conveniently synthesized. This silicon phthalocyanine derivative reacts with a hydroxyl group on a substrate and then with another phthalocyanine derivative under mild conditions. The accumulation number of the phthalocyanine molecules on the substrates is easily controlled by the immersion time. On the basis of AFM (atomic force microscopy) images, the surface of the phthalocyanine-modified glass substrate has uneven structures on the nanometer scale. ITO electrodes modified with the composition of the phthalocyanine derivative and PCBM show stable cathodic photocurrent generation upon light irradiation.
Subject(s)
Indoles/chemistry , Organosilicon Compounds/chemistry , Photosensitizing Agents/chemistry , Electrodes , Microscopy, Atomic Force , Photochemistry/methods , Surface PropertiesABSTRACT
Nanopillars composed of a photoresponsive phthalocyanine derivative have been conveniently fabricated using a continuous silane coupling reaction on a substrate. The chemical potentials of phthalocyanine nanopillars (PNs) are precisely controlled by changing the number of phthalocyanine derivatives on the substrate. In addition, photocurrent generation efficiencies have been strongly influenced by the number of phthalocyanine derivatives. High photocurrent conversion cells in a solid state have been obtained by the combination of PNs and a fullerene derivative.