ABSTRACT
Contaminant vulnerability in the critical zones like groundwater (GW)-seawater (SW) continuum along the entire Gujarat coast was investigated for the first time through an extensive water monitoring survey. The prime focus of the study was to evaluate whether or not: i) seawater intrusion induced metal load translates to toxicity; ii) in the coastal groundwater, metal distribution follows the pattern of other geogenic and anthropogenic contaminants like NO3- and F-; and iii) what future lies ahead pertaining to metal fate in association with saturation conditions of the coastal aquifers. The spatial distribution of contaminants depicts that the Gulf of Khambhat area is highly contaminated. Ecological risk assessment (ERA) indicates that the Gujarat coast is experiencing a high ecological risk compared to the southeast coast of India. Investigation results revealed that metals, pH, NO3, and CO3 are more vulnerable at the SW-GW mixing interface. An increase in pH is reflected in fewer ionic species of metals in the GW. Salinity ingress due to seawater intrusion (SWI) reduces the toxicities of all trace metals except Cu, attributed to the increase of Ca in GW, leading to dissociation of CuCO3. Reactive species are dominant for Zn and Cd; and M-CO3 ligands are dominant for Cu and Pb owing to the undersaturation of dolomite and calcite in the aquifer system. SWI tends to increase the metal load but the toxicity of metals varies with the density of industries, anthropogenic activities, changes in the mixing-induced saturation conditions, and intensive salt production across the coast. Multivariate analysis confirmed that the hydrogeochemical processes change due to GW-SW mixing and dictates over natural weathering. The ecological risk index (ERI) for the Arabian sea is experiencing moderate (300 ≥ ERI>150) to high ecological risk (ERI >600). Children population is likely to encounter a high health risk through ingestion and dermal exposure than adults. Overall, the study emphasizes the complexity of toxicity-related health impacts on coastal communities and suggests the dire need for frequent water monitoring along the coastal areas for quick realization of sustainable development goals.
Subject(s)
Groundwater , Water Pollutants, Chemical , Child , Environmental Monitoring , Humans , Metals , Salinity , Seawater , WaterABSTRACT
The Brahmaputra river system (BRS) produces the largest discharge in India, supplying water to more than 62 million inhabitants. The present study aims to quantify the environmental elements that affect the spatio-temporal variation of nutrients in the Brahmaputra river system (BRS). The association of physico-chemical characteristics of floodplain sediments with the distribution pattern of P during wet and dry periods in different depths were also studied. The seasonal variation suggest that the average dissolved inorganic nitrogen and dissolve inorganic phosphorus are found higher in monsoon while the average dissolve silica were higher in post-monsoon. The spatial variation of dissolve inorganic phosphate and nitrate concentration suggests both the nutrient are higher in upstream sites. The DiS concentrations tended to be higher in downstream. In 70% of the sampled tributaries, the average molar ratio for dissolved inorganic nitrogen/dissolved inorganic phosphorous (DIN/DIP) was greater than 16:1, which indicates phosphate limited biological productivity. In contrast, an average molar ratio of dissolved inorganic silica/DIN (DSi/DIN) of 3.8 ± 3.0 favoured diatom growth in those tributaries where DSi/DIN molar ratio was lower than 1, indicating eutrophication. The BRS transported 24.7, 5.93, and 312 × 104 tons/year-1 of DIN, PO4-P and SiO2-Si, respectively. The depth-wise variation of P-fraction during monsoon suggests that the authigenic phosphorus was most abundant followed by Fe-bound, exchangeable, detrital and organic. In the post-monsoon, Fe-bound P was found at a higher concentration followed by authigenic phosphorus. High nutrient concentrations with more δ18O depleted water implied precipitation being the major source of nutrients in the BRS.
Subject(s)
Environmental Monitoring , Water Pollutants, Chemical , Nitrates , Nitrogen/analysis , Nutrients , Phosphates , Phosphorus/analysis , Silicon Dioxide , Water , Water Pollutants, Chemical/analysisABSTRACT
The upper Brahmaputra floodplain (UBF) is highly enriched with geogenic contaminants, mostly the Arsenic (As), owing to its sensitive geomorphology, aquifer groundwater (GW) dynamics, huge sediment deposition along with natural and anthropogenic disturbance significantly accelerate the As leaching rate into the groundwater, leading to an increase the health risk. Concerning the above active processes in the Lakhimpur district of UBF, current work aims to investigate seasonal dynamics of As contamination and associated health hazard for local community. To carry out this study, 51 GW samples analyzed which reveal the seasonal variation in As concentrations with the minimum average concentration in the monsoon season (4.7 µg.L-1) and the maximum in the post-monsoon season (18.5 µg.L-1) with 50% of the samples exceeding permissible limits. The differences in the local geological conditions and the GW flow may contribute to the spatial variations in mean As concentration in the study area. Also, the active GW recharge process identified in post-monsoon season accelerates the As leaching in the area's aquifers. Further, results indicate higher As levels associated with a pH range of 6-7 favours As desorption from minerals under reducing conditions. The hazard index indicates that the children population has high carcinogenic risk compared to adult populations. Furthermore, the study highlights the social risk potential arising from public health crises due to As exposure. Overall, results indicate high As concentrations in region with moderate seasonal variability and demand a dire attention for long-term monitoring to provide sustainable water resources to safeguard the people at risk.