ABSTRACT
Spatial variations in tritium concentrations in groundwater were identified in the southern part of the coastal region in Fukushima Prefecture, Japan. Higher tritium concentrations were measured at wells near the Fukushima Daiichi Nuclear Power Station (F1NPS). Mean tritium concentrations in precipitation in the 5 weeks after the F1NPS accident were estimated to be 433 and 139 TU at a distance of 25 and 50 km, respectively, from the F1NPS. The elevations of tritium concentrations in groundwater were calculated using a simple mixing model of the precipitation and groundwater. By assuming that these precipitation was mixed into groundwater with a background tritium concentration in a hypothetical well, concentrations of 13 and 7 TU at distances of 25 and 50 km from the F1NPS, respectively, were obtained. The calculated concentrations are consistent with those measured at the studied wells. Therefore, the spatial variation in tritium concentrations in groundwater was probably caused by precipitation with high tritium concentrations as a result of the F1NPS accident. However, the highest estimated tritium concentrations in precipitation for the study site were much lower than the WHO limits for drinking water, and the concentrations decreased to almost background level at the wells by mixing with groundwater.
Subject(s)
Cesium Radioisotopes/isolation & purification , Radiation Monitoring , Tritium/isolation & purification , Water Pollutants, Radioactive/isolation & purification , Cesium Radioisotopes/chemistry , Cesium Radioisotopes/toxicity , Drinking Water/chemistry , Fukushima Nuclear Accident , Groundwater/chemistry , Humans , Tritium/chemistry , Tritium/toxicity , Water Pollutants, Radioactive/chemistry , Water Pollutants, Radioactive/toxicityABSTRACT
The influence of human activities on the flow system and contamination of groundwater were investigated in Seoul City, South Korea, one of the largest Asian cities, using a combination of isotopes (deltaD, T, delta15N, delta18O, delta34S, and 87Sr/86Sr). Eighteen representative groundwater and river water samples, which were collected over a wide area of the city, were compared with previously reported data. The distribution of stable isotopes (deltaD and delta18O) with groundwater potential data shows that recharged groundwater from either the surrounding mountainous area as well as the Han River and other surface streams discharged towards the northern-central part of the city, where a subway tunnel pumping station is located. It is suggested from T values (3.3 to 5.8 T.U.) that groundwater was recharged in the last 30 to 40 years. The delta34S and delta15N of SO4(2-) and NO3- data were efficiently used as indicators of contamination by human activities. These isotopes clarified that the contribution of anthropogenic contaminants i.e., industrial and household effluents, waste landfills, and fertilizers, are responsible for the enrichment by SO4(2-) (>30 ppm as SO4(2-)) and NO3- (>20 ppm as NO3-) of groundwater. The 87Sr/86Sr values of groundwater vary (0.71326 to 0.75058) in accordance with the host rocks of different origins. Mineral elements such as Ca are also suggested to be derived naturally from rocks. The groundwater under Seoul City is greatly affected by transportation of pollutants along the groundwater flow controlled by subway tunnel pumping, contributing to the degradation of water quality in urbanized areas.
