Optical signatures of pentacene in soft rare-gas environments.

Acenes and pentacene (Pc), in particular, are promising candidates for organic dyes with interesting properties important for solar light to energy conversion. We present a combined experimental and computational study of Pc in an ultracold environment that allows for high resolution optical spectroscopy. The spectra and their vibrational substructure are interpreted with the help of density functional theory calculations. While there are only slight changes within superfluid helium as compared to vacuum, the neon surface shows more prominent effects. Additional vibrational coupling by neon modes leads to broadening as well as the emergence of new features, like the otherwise symmetry forbidden out-of-plane butterfly mode.

Singlet Fission in Weakly Interacting Acene Molecules.

The energy conversion in solar cells has conventionally been limited by the Shockley-Queisser limit. Singlet fission (SF), a decay mechanism where a single excited singlet state is converted into two triplet states, can drastically improve this efficiency. For the most part, observation of SF has been limited to crystalline structures in solids and films, where strong ordering was present. Here we report on singlet fission in a disordered system where organic chromophores are distributed on the surface of a rare gas cluster. In this case, the intermolecular distances and degree of excitation can be varied to obtain their effects on the rate of singlet fission. We introduce a kinematic model that takes into account the details of the geometrical arrangement of the system as well as the time-dependent populations of the relevant states of each molecule and evaluate the trends obtained by SF on the experimental observables.