ABSTRACT
The development of a robust electrocatalyst for the electrochemical sensor for hazardous pesticides will reduce its effects on the ecosystem. Herein, we synthesized the robust manganese cobalt phosphide (MnCoP) - Core-shell as an electrochemical sensor for the determination of hazardous pesticide methyl parathion (MP). The MnCoP- Core-shell was prepared with the sustainable self-template route can help with the larger surface area. The Core-shell structure of MnCoP possesses a higher active surface area which increases the electrocatalytic performance and is utilized to improve the electrochemical MP reduction with the synergism of the core and shell structure. Remarkably, it realizes the higher sensitivity (0.014 µA µM-1 cm-2) of MnCoP- Core-shell/GCE achieves towards MP with lower limit of detection (LoD 50 nM) and exceptional recovery rate of MP in vegetable samples are achieved with the differential pulse voltammetry (DPV) technique. The MnCoP- Core-shell electrode reserved their superior electrochemical performances with high reproducibility and repeatability. This prominent activity of the MnCoP core-shell towards the MP in real sample analysis, makes it a promising electrochemical sensor for the detection of MP.
ABSTRACT
Boosting catalytic performance as a vital role for an electrochemical sensor for monitoring various hazardous nitro drugs. Herein, an inexpensive, facile, and eco-friendly construction of praseodymium tungstate decorated on three dimensional porous biocarbon (PrW/3D-PBC) for electrochemical determination of carcinogenic residue furazolidone (FZ). The nanostructured PrW nanoparticles were prepared by solvent evaporation from peroxo-tungstic acid and 3D-PBC was prepared from biomass precursor under the carbonization method. Furthermore, the composite of PrW decorated on 3D-PBC was prepared by an ultrasonic-assisted wet chemical approach. Besides, the composite characterization of crystalline, functional group, degree of carbonization, chemical states, and morphology were utilized by theXRD, FTIR, RAMAN, XPS, and FESEM analysis. These 3D porous carbon decorated PrW nanoparticles facilitate the electrochemical anchoring sites, surface area, and ease of diffusion layers towards the detection of hazardous nitro pollutant FZ by using CV analysis. The low LOD and high sensitivity were achieved by FZ determination through using LSV and DPV techniques. The practical capability of the PrW/3D-PBC/GCE sensor was determined by using aquatic samples to achieve a good recovery result. These results instigate that the PrW/3D-PBC will be an efficient electrocatalytic material for FZ sensor in environmental aquatic samples.
Subject(s)
Furazolidone , Praseodymium , Electrodes , Electrochemical Techniques/methods , PorosityABSTRACT
In this study, we designed a CrNiCo-P/GCN composite for use as a high-performance multifunctional catalyst for the oxygen evolution reaction (OER), electrochemical determination, and photodegradation of roxarsone (ROX). CrNiCo-P/GCN demonstrates favorable charge resistance and electrical conductance due to its intrinsic properties. It exhibits an admirable OER overpotential of 290 mV with a lower Tafel plot value of 125 mV dec-1 in alkaline media and compared with the control samples. Furthermore, this composite also demonstrates high performance in electrochemical sensing of ROX over a wide concentration range of 1-413 µM with a lower limit of detection (LOD) of 31 nM in phosphate buffer. Moreover, this composite is a promising electrocatalyst for ROX sensors in practical analysis and also possesses excellent photodegradation of ROX under visible light irradiation.
ABSTRACT
A WS2/GdCoO3 nanocomposite was successfully prepared using hydrothermal-assisted synthesis. Our prepared WS2/GdCoO3 nanocomposite was fabricated on a glassy carbon electrode (GCE) for the detection of quercetin (QCT). The WS2/GdCoO3 nanomaterial was characterized by powder XRD, micro-Raman, FT-IR, XPS, FE-SEM, and HR-TEM, which proved that WS2 nanoplates were finely dispersed on the surface of the GdCoO3 nanoflakes. The electrocatalytic performance of WS2/GdCoO3 was investigated by the EIS technique, and it exhibited a small semi-circle, which confirms that it has a large active surface area and high electrical conductivity. The electrochemical behavior of QCT at the WS2/GdCoO3 sensor was explored by using the CV and DPV methods. The proposed electrochemical sensor exhibited excellent electrochemical response toward QCT with a wide linear range of 0.001 to 329 µM, low limit of detection (LOD) of 0.003 µM, and limit of quantification (LOQ) of 0.0101 µM. The sensor also displayed excellent selectivity, sensitivity, reproducibility, and stability. Additionally, the WS2/GdCoO3 sensor was utilized for the detection of QCT in apple juice and grape juice samples, and it exhibited good recovery results.
ABSTRACT
In recent times, metal tungstates have received a lot of attention in various research fields. Accordingly, the CaWO4/RGO (CW/RGO) nanocomposite was prepared by a facile hydrothermal method. The electrocatalytic performance of the hydrothermally prepared CW/RGO nanocomposite was used for the electrochemical detection of the antibiotic medicine enrofloxacin (ENF). The electrocatalytic oxidation performance of ENF was examined by cyclic voltammetry (CV) and amperometry (AMP) techniques. The CV results showed the lowest anodic peak potential and the enhanced anodic peak current response compared to the other modified electrodes. Mainly, our newly proposed sensor exhibited excellent electrochemical performance with the lowest limit of detection (LOD) of 0.021 µM, and a significant linear range of 0.001-115 µM. Additionally, our proposed sensor exhibited good selectivity, great long-term stability, and excellent reproducibility. Then, our proposed sensor was successfully applied to detect the amount of ENF in a milk sample and river water, which exhibited good satisfactory results.
