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Chem Commun (Camb)
; 55(43): 6066-6069, 2019 May 28.
Article
in English
| MEDLINE
| ID: mdl-31066388
ABSTRACT
Shape-persistent macrocycles and 3D nanocages have been prepared in one-pot under MeCN-promoted dynamic covalent bond conditions starting from silane catecholates, whose structures were confirmed by X-ray crystallography. Cation-exchange reactions of macrocycles and nanocages were performed along with the encapsulation of ammonium ions within the cavity of an anionic macrocycle and a tetrahedral nanocage.