ABSTRACT
Herein, we reported the dual functions of molybdenum disulfide/sulfur-doped graphitic carbon nitride (MoS2/SGCN) composite as a sensing material for electrochemical detection of 4-NP and a catalyst for 4-NP degradation. The MoS2 nanosheet, sulfur-doped graphitic carbon nitride (SGCN) and MoS2/SGCN were characterized using field emission scanning electron microscopy (FESEM), X-ray diffraction (XRD) spectroscopy and X-ray photoelectron spectroscopy (XPS). Electrochemical characterization of these materials with electrochemical impedance spectroscopy (EIS) and cyclic voltammetry (CV) in 1â¯mM K4[Fe(CN)6]3-/4- show that the composite has the lowest charge transfer resistance and the best electrocatalytic activity. The limit of detection (LOD) and the linear range of 4-nitrophenol at MoS2/SGCN modified glassy carbon electrode (MoS2/SGCN/GCE) were computed as 12.8â¯nM and 0.1 - 2.6 µM, respectively. Also, the percentage recoveries of 4-NP in spiked tap water samples ranged from 97.8 - 99.1â¯%. The electroanalysis of 4-NP in the presence of notable interferons shows that the proposed electrochemical sensor features outstanding selectivity toward 4-NP. Additionally, the results of the catalytic degradation of 4-NP at MoS2/SGCN show that the nanocatalyst catalyzed the transformation of 4-NP to 4-aminophenol (4-AP) with a first-order rate constant (k) estimated to be 4.2 ×10-2 s-1. The results of this study confirm that the MoS2/SGCN nanocatalyst is a useful implement for electroanalytical monitoring and catalytic degradation of the hazardous 4-NP in water samples.
ABSTRACT
Transparent and flexible vibrotactile actuators play an essential role in human-machine interaction applications by providing mechanical stimulations that can effectively convey haptic sensations. In the present study, we fabricated an electroactive, flexible, and transparent vibrotactile actuator with a dielectric layer including a dielectric elastomer and dielectric fluid mixture. The dielectric fluid mixture of propylene carbonate (PC) and acetyl tributyl citrate (ATBC) was injected to obtain a transparent dielectric layer. To further improve the haptic performance, different weight ratios of dielectric fluid (PC: ATBC) were injected. The fabricated vibrotactile actuators based on a transparent dielectric layer were investigated for their electrical and electromechanical behavior. The proposed actuators generate a large vibrational intensity (~2.5 g) in the range of 200-250 Hz. Hence, the proposed actuators open up a new class of vibrotactile actuators for possible use in various domains, including robotics, smart textiles, teleoperation, and the metaverse.
ABSTRACT
Till to date, the application of sulfur-doped graphitic carbon nitride supported transition metal carbide interface for electrochemical sensor fabrication was less explored. In this work, we designed a simple synthesis of molybdenum carbide sphere embedded sulfur doped graphitic carbon nitride (Mo2C/SCN) catalyst for the nanomolar electrochemical sensor application. The synthesized Mo2C/SCN nanocatalyst was systematically characterized using X-ray diffraction (XRD) and scanning electron microscopy (SEM) with elemental mapping. The SEM images show that the porous SCN network adhered uniformly on Mo2C, causing a loss of crystallinity in the diffractogram. The corresponding elemental mapping of Mo2C/SCN shows distinct peaks for carbon (41.47%), nitrogen (32.54%), sulfur (1.37%), and molybdenum (24.62%) with no additional impurity peaks, reflecting the successful synthesis. Later, the glassy carbon electrode (GCE) was modified by Mo2C/SCN nanocatalyst for simultaneous sensing of uric acid (UA) and folic acid (FA). The fabricated Mo2C/SCN/GCE is capable of simultaneous and interference free electrochemical detection of UA and FA in a binary mixture. The limit of detection (LOD) calculated at Mo2C/SCN/GCE for UA and FA was 21.5 nM (0.09 - 47.0 µM) and 14.7 nM (0.09 - 167.25 µM) respectively by differential pulse voltammetric (DPV) technique. The presence of interferons has no significant effect on the sensor's performance, making it suitable for real sample analysis. The present method can be extended to fabricate an electrochemical sensor for various molecules.
Subject(s)
Folic Acid , Uric Acid , Uric Acid/analysis , Electrochemical Techniques/methods , Carbon/chemistry , Electrodes , Limit of Detection , SulfurABSTRACT
A tunable optical lens can tune or reconfigure the lens material itself such that it can eliminate the moving part of the lens, which brings broad technological impacts. Many tunable optical lenses have been implemented using electroactive polymers that can change the shape of the lens. However, the refractive index (RI) change of electroactive polymers has not been well investigated. This paper investigated the RI change of CNC-based transparent and electroactive polyurethane (CPPU) in the presence of an actuating electric field. The prepared CPPU was electrically poled to enhance its electro-optical performance, and the poling conditions in terms of frequency and electric field were optimized. The poled CPPU was characterized using a Fourier transform infrared spectroscopy and a refractometer. To investigate the RI change in the presence of an actuating electric field, the poled CPPU was constrained between two electrodes with a fixed distance. The RI linearly increased as the actuating electric field increased. The RI change mechanism and the optimized poling conditions are illustrated. The tunable RI is a promising property for implementing a tunable optical lens.
ABSTRACT
This paper reports swelling behavior of cellulose nanocrystal (CNC)-based polyacrylamide hydrogels prepared by a radical polymerization. The CNC acts as a nanofiller through the formation of complexation and intermolecular interaction. FTIR spectroscopy and XRD studies confirmed the formation of intermolecular bonds between the acrylamide and hydroxyl groups of CNC. The swelling ratio and water retention were studied in de-ionized (DI) water at room temperature, and the temperature effect on the swelling ratio was investigated. Further, the pH effect on the swelling ratio was studied with different temperature levels. Increasing the pH with temperature, the prepared hydrogel shows 6 times higher swelling ratio than the initial condition. The swelling kinetics of the developed hydrogels explains that the diffusion mechanism is Fickian diffusion mechanism. Since the developed hydrogels have good swelling behaviors with respect to pH and temperature, they can be used as smart materials in the field of controlled drug delivery applications.
ABSTRACT
This paper reports a nontoxic, soft and electroactive hydrogel made with polyvinyl alcohol (PVA) and cellulose nanocrystal (CNC). The CNC incorporating PVA-CNC hydrogels were prepared using a freezeâ»thaw technique with different CNC concentrations. Fourier transform infrared spectroscopy, thermogravimetric analysis, X-ray diffraction and scanning electron microscopy results proved the good miscibility of CNCs with PVA. The optical transparency, water uptake capacity and mechanical properties of the prepared hydrogels were investigated in this study. The CNC incorporating PVA-CNC hydrogels showed improved displacement output in the presence of an electric field and the displacement increased with an increase in the CNC concentration. The possible actuation mechanism was an electrostatic effect and the displacement improvement of the hydrogel associated with its enhanced dielectric properties and softness. Since the prepared PVA-CNC hydrogel is nontoxic and electroactive, it can be used for biomimetic soft robots, actively reconfigurable lenses and active drug-release applications.
ABSTRACT
Recently, a cellulose-based composite material with a thin ZnO nanolayer-namely, ZnO nanocoated cellulose film (ZONCE)-was fabricated to increase its piezoelectric charge constant. However, the fabrication method has limitations to its application in mass production. In this paper, a hydrothermal synthesis method suitable for the mass production of ZONCE (HZONCE) is proposed. A simple hydrothermal synthesis which includes a hydrothermal reaction is used for the production, and the reaction time is controlled. To improve the piezoelectric charge constant, the hydrothermal reaction is conducted twice. HZONCE fabricated by twice-hydrothermal reaction shows approximately 1.6-times improved piezoelectric charge constant compared to HZONCE fabricated by single hydrothermal reaction. Since the fabricated HZONCE has high transparency, dielectric constant, and piezoelectric constant, the proposed method can be applied for continuous mass production.
ABSTRACT
This paper reports the synthesis and UV sensing characteristics of a cellulose and ZnO hybrid nanocomposite (CEZOHN) prepared by exploiting the synergetic effects of ZnO functionality and the renewability of cellulose. Vertically aligned ZnO nanorods were grown well on a flexible cellulose film by direct ZnO seeding and hydrothermal growing processes. The ZnO nanorods have the wurtzite structure and an aspect ratio of 9 ~ 11. Photoresponse of the prepared CEZOHN was evaluated by measuring photocurrent under UV illumination. CEZOHN shows bi-directional, linear and fast photoresponse as a function of UV intensity. Electrode materials, light sources, repeatability, durability and flexibility of the prepared CEZOHN were tested and the photocurrent generation mechanism is discussed. The silver nanowire coating used for electrodes on CEZOHN is compatible with a transparent UV sensor. The prepared CEZOHN is flexible, transparent and biocompatible, and hence can be used for flexible and wearable UV sensors.
ABSTRACT
The increasing requirements of hyperspectral imaging optics, electro/photo-chromic materials, negative refractive index metamaterial optics, and miniaturized optical components from micro-scale to quantum-scale optics have all contributed to new features and advancements in optics technology. Development of multifunctional capable optics has pushed the boundaries of optics into new fields that require new disciplines and materials to maximize the potential benefits. The purpose of this study is to understand and show the fundamental materials and fabrication technology for field-controlled spectrally active optics (referred to as smart optics) that are essential for future industrial, scientific, military, and space applications, such as membrane optics, light detection and ranging (LIDAR) filters, windows for sensors and probes, telescopes, spectroscopes, cameras, light valves, light switches, and flat-panel displays. The proposed smart optics are based on the Stark and Zeeman effects in materials tailored with quantum dot arrays and thin films made from readily polarizable materials via ferroelectricity or ferromagnetism. Bound excitonic states of organic crystals are also capable of optical adaptability, tunability, and reconfigurability. To show the benefits of smart optics, this paper reviews spectral characteristics of smart optical materials and device technology. Experiments testing the quantum-confined Stark effect, arising from rare earth element doping effects in semiconductors, and applied electric field effects on spectral and refractive index are discussed. Other bulk and dopant materials were also discovered to have the same aspect of shifts in spectrum and refractive index. Other efforts focus on materials for creating field-controlled spectrally smart active optics (FCSAO) on a selected spectral range. Surface plasmon polariton transmission of light through apertures is also discussed, along with potential applications. New breakthroughs in micro scale multiple zone plate optics as a micro convex lens are reviewed, along with the newly discovered pseudo-focal point not predicted with conventional optics modeling. Micron-sized solid state beam scanner chips for laser waveguides are reviewed as well.
ABSTRACT
This paper introduces an electroactive bionanocomposite based on poly(diethylene glycol adipate) (PDEGA) and cellulose nanocrystals (CNCs). The bionanocomposites were made using CNCs extracted from cotton and by optimizing its concentration in terms of the optical transmittance and viscosity. The characteristic properties of the materials were analyzed using contact angle measurements and Fourier transformation infrared spectra. Using the PDEGA/CNC bionanocomposite at a very low concentration of CNCs, a configurable lens having a robust, self-contained tunable optical structure was developed. The shape and curvature of the soft PDEGA/CNC device were controlled by applying voltage, and the focal length was measured. The simple structure, high optical transparency, biodegradability, thermal stability, high durability, and low power consumption make the new material particularly useful in fabricating a reconfigurable lens for future electronic and optical devices.
Subject(s)
Nanocomposites/chemistry , Cellulose/chemistry , Microscopy, Atomic Force , Microscopy, Electron, Transmission , Nanoparticles/chemistry , ViscosityABSTRACT
The rapid development of touch screens as well as photoelectric sensors has stimulated the fabrication of reliable, convenient, and human-friendly devices. Other than sensors that detect physical touch or are based on pressure sensing, proximity sensors offer controlled sensibility without physical contact. In this work we present a transparent and eco-friendly sensor made through layer-by-layer spraying of modified graphene oxide filled cellulose nanocrystals on lithographic patterns of interdigitated electrodes on polymer substrates, which help to realize the precise location of approaching objects. Stable and reproducible signals generated by keeping the finger in close proximity to the sensor can be controlled by humidity, temperature, and the distance and number of sprayed layers. The chemical modification and reduction of the graphene oxide/cellulose crystal composite and its excellent nanostructure enable the development of proximity sensors with faster response and higher sensitivity, the integration of which resolves nearly all of the technological issues imposed on optoelectronic sensing devices.
Subject(s)
Cellulose/chemistry , Graphite/chemistry , Nanoparticles/chemistry , Oxides/chemistry , Crystallization , Electrochemistry , Electrodes , Electronics , Equipment Design , Gossypium , Humans , Hydrogen Bonding , Isocyanates/chemistry , Microscopy, Atomic Force , Microscopy, Electron, Transmission , Nanotechnology/instrumentation , Optics and Photonics , Temperature , X-Ray DiffractionABSTRACT
Most sensors are based on ceramic or semiconducting substrates, which have no flexibility or biocompatibility. Polymer-based sensors have been the subject of much attention due to their ability to collect molecules on their sensing surface with flexibility. Beyond polymer-based sensors, the recent discovery of cellulose as a smart material paved the way to the use of cellulose paper as a potential candidate for mechanical as well as electronic applications such as actuators and sensors. Several different paper-based sensors have been investigated and suggested. In this paper, we review the potential of cellulose materials for paper-based application devices, and suggest their feasibility for chemical and biosensor applications.
ABSTRACT
This paper reports a hybrid nanocomposite of well-aligned zinc oxide (ZnO) nanorods on cellulose and its strain sensing behavior. ZnO nanorods are chemically grown on a cellulose film by using a hydrothermal process, termed as cellulose ZnO hybrid nanocomposite (CEZOHN). CEZOHN is made by seeding and growing of ZnO on the cellulose and its structural properties are investigated. The well-aligned ZnO nanorods in conjunction with the cellulose film shows enhancement of its electromechanical property. Strain sensing behaviors of the nanocomposite are tested in bending and longitudinal stretching modes and the CEZOHN strain sensors exhibit linear responses.