Capillary forces in a confined isotropic-nematic liquid crystal.

We have investigated nematic capillary condensation in the isotropic phase of nematic liquid crystals 5CB (4-cyano-4(')-n-pentylbiphenyl) and 8CB (4-cyano-4(')-n-octylbiphenyl) confined to nanometer thick layers between two orienting surfaces. The capillary condensation was induced by decreasing the liquid crystal layer thickness using an atomic force microscope, and the onset of condensation was detected by monitoring the structural force on a confining surface. Very strong and long-ranged capillary forces were observed at temperatures close to the isotropic-nematic transition. We have analyzed the temperature dependence of the thickness of the liquid crystal layer, at which the condensation occurs, with a thermodynamic Kelvin equation and determined the interfacial tension between the isotropic and nematic phases. The separation dependence of capillary forces was analyzed within the Landau-de Gennes approach, including electrostatic interaction due to surface charging. The quantitative agreement between the measured and calculated force profiles is very good, and a single set of parameters is needed to describe a set of measured force profiles at different temperatures. Surface charge density, surface potential, and Debye screening length were determined directly from the observed surface forces.

Structure and polarity of 8CB films evaporated onto solid substrates.

Brewster-angle reflection ellipsometry and surface optical second harmonic generation were used to study the growth of 4'-n-octyl-4-cyanobiphenyl (8CB) films evaporated in air onto polymeric and quartz glass substrates. The layer-by-layer growth of the films terminates after formation of two distinctive interfacial layers. Both of these two layers are polar and tilted. In the first layer the molecules lie nearly flat on the surface, while in the second layer they point on average about 50 degrees toward the surface normal. The dipole moment of the second layer has a lower magnitude and an opposite direction with respect to the dipole moment of the first layer.

Observation of an electrostatic force between charged surfaces in liquid crystals.

We report on the atomic force microscope observation of an electrostatic force between glass surfaces immersed in cyanobiphenil liquid crystals. The measured force is repulsive and decays exponentially with increasing surface separation. A mean field description of the electrostatic interaction in liquids has been used to determine the Debye screening length, the concentration of dissolved ions, and the surface electric potential. The effect of the observed interfacial electric field on the liquid crystal orientation at the surface has been discussed. It has been found that the coupling between the liquid crystal order and the surface electric field does not contribute considerably to the surface orienting action.

Surface-induced nematic and smectic order at a liquid-crystal-silanated-glass interface observed by atomic force spectroscopy and Brewster angle ellipsometry.

We have investigated nematic and smectic surface-induced ordering in the isotropic phase of the 4-cyano-4'-n-octylbiphenyl liquid crystal on silanated BK7 and LaSF glass using atomic force spectroscopy and Brewster angle ellipsometry. We have observed complete wetting of the silanated glass surfaces with the nematic phase when approaching the isotropic-nematic phase transition from above. Using the atomic force spectroscopy at the same interfaces, we have detected a significant presmectic ordering that is enhanced at the nematic-isotropic transition. We have observed the first, strongly adsorbed layer of liquid-crystalline molecules underneath this presmectic ordering. This first molecular layer is laterally inhomogeneous with typically 100 nm voids and covers approximately 70% of the surface. It is stable far above the clearing point and is responsible for the surface-memory effect. The results have been analyzed using Landau-de Gennes theory. The surface coupling energies of the nematic and smectic order have been determined, as well as the coupling energy between the nematic and smectic order.

Forces in the isotropic phase of a confined nematic liquid crystal 5CB.

Using a temperature controlled atomic force microscope, we have measured the temperature dependence of the force between a flat silanated glass surface and a silanated glass microsphere, immersed in the isotropic phase of the nematic liquid crystal 5CB (4'-n-pentyl 4-cyanobiphenyl). At separations of several nanometers, we observed a weak, short range attractive force of the order of 100 pN, which was increased by decreasing the temperature. The temperature dependence of the amplitude and the range of this attractive force can be described by a combination of van der Waals and a mean-field prenematic force due to the surface-induced nematic order. This is supported by ellipsometric study and allows for the determination of the surface coupling energy of 5CB on a silanated glass surface.

Capillary condensation of a nematic liquid crystal observed by force spectroscopy.

We have observed capillary condensation in nanometer-thin films of nematic liquid crystals using force spectroscopy. The liquid crystal was confined to a submicron gap between a flat substrate and a microsphere, attached to the cantilever of an atomic force microscope. A long-ranged and strongly attractive force due to capillary condensation of a nematic phase was observed at temperatures close to the bulk isotropic-nematic phase transition. The critical point, terminating the first-order confined isotropic-nematic transition line, was determined for the first time.

Investigation of the felodipine glassy state by atomic force microscopy.

The glassy state of felodipine was prepared by melting crystals of felodipine on a clean glass slide and cooling to room temperature. It has been confirmed that glassy felodipine is a metastable state, and undergoes transformation to the more stable crystalline form. Crystallization occurred slowly and spontaneously at room temperature, below the glassy state transition temperature (Tg). The contact mode of atomic force microscopy was used for topographical imaging of the glassy and crystalline states of felodipine. When the glassy felodipine region next to the recrystallized zone was exposed to controlled mechanical stress through the tip, rapid additional crystallization was observed. This crystallization process can be induced and imaged in real time by atomic force microscopy.

Atomic force microscope evidence for the existence of smecticlike surface layers in the isotropic phase of a nematic liquid crystal

Using a temperature controlled atomic force microscope we have observed presmectic layering in the isotropic phase of 4-cyano-4(')-n-octylbiphenyl (8CB) on silanated glass. The first molecular layer shows a smecticlike compressibility modulus of B approximately 10(7) N/m(2) and is stable more than 20 K beyond the bulk clearing point. It is followed by a presmectic modulation that increases when cooling towards the isotropic-nematic transition. In the bulk isotropic phase, the layers cover approximately 70% of the glass surface, indicating a clusterlike organization.