ABSTRACT
SiOx (x ≈ 1) is one of the most promising anode materials for application in secondary lithium-ion batteries because of its high theoretical capacity. Despite this merit, SiOx has a poor initial Coulombic efficiency, which impedes its widespread use. To overcome this limitation, in this work, we successfully demonstrate a novel synthesis of Mg-doped SiOx via a mass-producible physical vapor deposition method. The solid-state reaction between Mg and SiOx produces Si and electrochemically inert magnesium silicate, thus increasing the initial Coulombic efficiency. The Mg doping concentration determines the phase of the magnesium silicate domains, the size of the Si domains, and the heterogeneity of these two domains. Detailed electron microscopy and synchrotron-based analysis revealed that the nanoscale homogeneity of magnesium silicates driven by cycling significantly affected the lifetime. We found that 8 wt % Mg is the most optimized concentration for enhanced cyclability because MgSiO3, which is the dominant magnesium silicate composition, can be homogeneously mixed with silicon clusters, preventing their aggregation during cycling and suppressing void formation.
ABSTRACT
Understanding the cycling rate-dependent kinetics is crucial for managing the performance of batteries in high-power applications. Although high cycling rates may induce reaction heterogeneity and affect battery lifetime and capacity utilization, such phase transformation dynamics are poorly understood and uncontrollable. In this study, synchrotron-based operando X-ray diffraction is performed to monitor the high-current-induced phase transformation kinetics of LiNi0.6 Co0.2 Mn0.2 O2 . The sluggish Li diffusion at high Li content induces different phase transformations during charging and discharging, with strong phase separation and homogeneous phase transformation during charging and discharging, respectively. Moreover, by exploiting the dependence of Li diffusivity on the Li content and electrochemically tuning the initial Li content and distribution, phase separation pathway can be redirected to solid solution kinetics at a high charging rate of 7 C. Finite element analysis further elucidates the effect of the Li-content-dependent diffusion kinetics on the phase transformation pathway. The findings suggest a new direction for optimizing fast-cycling protocols based on the intrinsic properties of the materials.
ABSTRACT
Sc2Cu2O5 is a non centro-symmetric oxide comprising of zig-zag chains made up of Cu2+ ions in a distorted square planer coordination. We present here a combined experimental and theoretical investigation on this compound, which is based on magnetization, electron spin resonance (ESR), heat capacity as well as density functional theory (DFT) based calculations. Short range magnetic correlation prior to the long range order at [Formula: see text] K is evidenced by a broad hump like feature ([Formula: see text]43 K) found in the magnetic contribution of the heat capacity as well as by deviations from a regular Curie-Weiss behavior observed in the bulk magnetization and the Cu2+ ESR intensity. The DFT results indicate the existence of ferro-orbital ordering at the Cu-sites, which gives rise to chain like arrangements of Cu ions along the crystallographic b axis. It also signifies complex nature of the spin structure with nonuniform magnetic interactions along the zig-zag chains. The ground state energy is found to be minimum for ferromagnetically coupled spin-dimers along the chains, whereas the adjacent chains are themselves antiferromagnetically coupled. The experimentally observed short range magnetic correlations possibly arise due to this chain like structure.
ABSTRACT
The intermetallic semiconductor FeGa3 acquires itinerant ferromagnetism upon electron doping by a partial replacement of Ga with Ge. We studied the electron spin resonance (ESR) of high-quality single crystals of FeGa3-x Ge x for x from 0 up to 0.162 where ferromagnetic order is observed. For x = 0 we observed a well-defined ESR signal, indicating the presence of pre-formed magnetic moments in the semiconducting phase. Upon Ge doping the occurrence of itinerant magnetism clearly affects the ESR properties below ≈40 K, whereas at higher temperatures an ESR signal as seen in FeGa3 prevails independent on the Ge content. The present results show that the ESR of FeGa3-x Ge x is an appropriate and direct tool to investigate the evolution of 3d-based itinerant magnetism.