Estimation of the age of polyethylene microplastics collected from oceans: Application to the western North Pacific Ocean.

The knowledge of microplastic (MP) age could aid the deduction of the origin and fate of a fragment carried by ocean currents over long time periods and distances. The present study developed a novel method to estimate the age of MPs (i.e., UV radiation exposure time) using the oxidation level of polyethylene (i.e., carbonyl index) from infrared spectrometry, ultraviolet erythemal radiation (UVER) data, and ambient seawater temperatures. Accelerated and outdoor exposure experiments were conducted to establish relationships among the temporally integrated UVER, ambient temperature, and carbonyl index. Thereafter, the age of MPs was computed, with Miyakojima Island serving as the reference location. The estimated ages of MPs collected from the western North Pacific Ocean ranged from 1 to 3 years, and those MPs from nearshore waters ranged from 0 to 5 years.

Spin-Trapping Analysis of the Thermal Degradation Reaction of Polyamide 66.

The radical mechanisms of the thermal degradation of polyamide 66 (PA66) occurring under a vacuum at a temperature range between 80 °C and 240 °C (which includes the temperature of practical applications) were investigated using a spin-trapping electron spin resonance (ST-ESR) technique, as well as FTIR, TG-DTA, and GPC methods. No significant weight loss and no sign of thermal degradation are observed at this temperature range under oxygen-free conditions, but a slight production of secondary amine groups is confirmed by FTIR. GPC analysis shows a small degradation by the main chain scission. ST-ESR analysis reveals two intermediate radicals which are produced in the thermal degradation of PA66: (a) a ●CH2- radical generated by main chain scission and (b) a -●CH- radical generated by hydrogen abstraction from the methylene group of the main chain. The ST-ESR result does not directly confirm that a -NH-●CH- radical is produced, although this reaction has been previously inferred as the initiation reaction of the thermal degradation of PA; however, the presence of -●CH- radicals strongly suggests the occurrence of this initiation reaction, which takes place on the α-carbon next to the NH group. The ST-ESR analysis reveals very small levels of reaction, which cannot be observed by common analytical methods such as FTIR and NMR.