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Org Lett ; 10(24): 5609-12, 2008 Dec 18.
Article in English | MEDLINE | ID: mdl-19053724

ABSTRACT

Photoinitiated [6pi + 2pi] cycloadditions of allenes with (eta(6)-cycloheptatriene)tricarbonylchromium(0) (1) are described. An example of asymmetric induction obtained by reaction of 1 with a chiral 1,3-disubstituted allene is also reported.


Subject(s)
Alkadienes/chemical synthesis , Chromium/chemistry , Organometallic Compounds/chemistry , Alkadienes/chemistry , Cyclization , Photochemical Processes
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