Integration Construction of Hybrid Electrocatalysts for Oxygen Reductions.

There has been notable progress in the development of efficient oxygen reduction electrocatalysts, which are crucial components of fuel cells. However, these superior activities are limited by imbalanced mass transport and cannot be fully reflected in actual fuel cell applications. Herein, we present the design concepts and development tracks of platinum-nanocarbon hybrid catalysts, aiming to enhance both cathodic electrocatalysts and hydrogen reactors. This review commences with an introduction to Pt/C catalysts, highlighting the diverse architectures developed to date, with particular emphasis on heteroatom modification and microstructure construction of functionalized nanocarbons based on integrated design concepts. This discussion encompasses the structural evolution, property enhancement, and catalytic mechanisms of Pt/C-based catalysts, including rational preparation recipes, superior activity, strong stability, robust metal-support interactions, adsorption regulation, synergistic pathways, confinement strategies, ionomer optimization, mass transport permission, multidimensional construction, and reactor upgrading. Furthermore, this review explores the low-barrier or barrier-free mass exchange interfaces and channels achieved through the impressive multidimensional construction of platinum-nanocarbon integrated catalysts, with the goal of optimizing fuel cell efficiency. In conclusion, this review outlines the challenges associated with platinum-nanocarbon integrated catalysts and provides perspectives on the future development trends of fuel cells and beyond. This article is protected by copyright. All rights reserved.

Surface Redox Chemistry Regulates the Reaction Microenvironment for Efficient Hydrogen Peroxide Generation.

Electrosynthesis has emerged as an enticing solution for hydrogen peroxide (H2O2) production. However, efficient H2O2 generation encounters challenges related to the robust gas-liquid-solid interface within electrochemical reactors. In this work, we introduce an effective hydrophobic coating modified by iron (Fe) sites to optimize the reaction microenvironment. This modification aims to mitigate radical corrosion through Fe(II)/Fe(III) redox chemistry, reinforcing the reaction microenvironment at the three-phase interface. Consequently, we achieved a remarkable yield of up to 336.1 mmol h-1 with sustained catalyst operation for an extensive duration of 230 h at 200 mA cm-2 without causing damage to the reaction interface. Additionally, the Faradaic efficiency of H2O2 exceeded 90% across a broad range of test current densities. This surface redox chemistry approach for manipulating the reaction microenvironment not only advances long-term H2O2 electrosynthesis but also holds promise for other gas-starvation electrochemical reactions.

Low-coordination Nanocrystalline Copper-based Catalysts through Theory-guided Electrochemical Restructuring for Selective CO2 Reduction to Ethylene.

Revealing the dynamic reconstruction process and tailoring advanced copper (Cu) catalysts is of paramount significance for promoting the conversion of CO2 into ethylene (C2H4), paving the way for carbon neutralization and facilitating renewable energy storage. In this study, we initially employed density functional theory (DFT) and molecular dynamics (MD) simulations to elucidate the restructuring behavior of a catalyst under electrochemical conditions and delineated its restructuring patterns. Leveraging insights into this restructuring behavior, we devised an efficient, low-coordination copper-based catalyst. The resulting synthesized catalyst demonstrated an impressive Faradaic efficiency (FE) exceeding 70 % for ethylene generation at a current density of 800 mA cm-2. Furthermore, it showed robust stability, maintaining consistent performance for 230 hours at a cell voltage of 3.5 V in a full-cell system. Our research not only deepens the understanding of the active sites involved in designing efficient carbon dioxide reduction reaction (CO2RR) catalysts but also advances CO2 electrolysis technologies for industrial application.

RhNi Bimetallenes with Lattice-Compressed Rh Skin towards Ultrastable Acidic Nitrate Electroreduction.

Harvesting recyclable ammonia (NH3 ) from acidic nitrate (NO3 - )-containing wastewater requires the utilization of corrosion-resistant electrocatalytic materials with high activity and selectivity towards acidic electrochemical nitrate reduction (NO3 ER). Herein, ultrathin RhNi bimetallenes with Rh-skin-type structure (RhNi@Rh BMLs) are fabricated towards acidic NO3 ER. The Rh-skin atoms on the surface of RhNi@Rh BMLs experience the lattice compression-induced strain effect, resulting in shortened Rh-Rh bond and downshifted d-band center. Experimental and theoretical calculation results corroborate that Rh-skin atoms can inhibit NO2 */NH2 * adsorption-induced Rh dissolution, contributing to the exceptional electrocatalytic durability of RhNi@Rh BMLs (over 400 h) towards acidic NO3 ER. RhNi@Rh BMLs also reveal an excellent catalytic performance, boasting a 98.4% NH3 Faradaic efficiency and a 13.4 mg h-1 mgcat -1 NH3 yield. Theoretical calculations reveal that compressive stress tunes the electronic structure of Rh skin atoms, which facilitates the reduction of NO* to NOH* in NO3 ER. The practicality of RhNi@Rh BMLs has also been confirmed in an alkaline-acidic hybrid zinc-nitrate battery with a 1.39 V open circuit voltage and a 10.5 mW cm-2 power density. This work offers valuable insights into the nature of electrocatalyst deactivation behavior and guides the development of high-efficiency corrosion-resistant electrocatalysts for applications in energy and environment.

Durable CO2 conversion in the proton-exchange membrane system.

Electrolysis that reduces carbon dioxide (CO2) to useful chemicals can, in principle, contribute to a more sustainable and carbon-neutral future1-6. However, it remains challenging to develop this into a robust process because efficient conversion typically requires alkaline conditions in which CO2 precipitates as carbonate, and this limits carbon utilization and the stability of the system7-12. Strategies such as physical washing, pulsed operation and the use of dipolar membranes can partially alleviate these problems but do not fully resolve them11,13-15. CO2 electrolysis in acid electrolyte, where carbonate does not form, has therefore been explored as an ultimately more workable solution16-18. Herein we develop a proton-exchange membrane system that reduces CO2 to formic acid at a catalyst that is derived from waste lead-acid batteries and in which a lattice carbon activation mechanism contributes. When coupling CO2 reduction with hydrogen oxidation, formic acid is produced with over 93% Faradaic efficiency. The system is compatible with start-up/shut-down processes, achieves nearly 91% single-pass conversion efficiency for CO2 at a current density of 600 mA cm-2 and cell voltage of 2.2 V and is shown to operate continuously for more than 5,200 h. We expect that this exceptional performance, enabled by the use of a robust and efficient catalyst, stable three-phase interface and durable membrane, will help advance the development of carbon-neutral technologies.

Recent advances in proton exchange membrane water electrolysis.

Proton exchange membrane water electrolyzers (PEMWEs) are an attractive technology for renewable energy conversion and storage. By using green electricity generated from renewable sources like wind or solar, high-purity hydrogen gas can be produced in PEMWE systems, which can be used in fuel cells and other industrial sectors. To date, significant advances have been achieved in improving the efficiency of PEMWEs through the design of stack components; however, challenges remain for their large-scale and long-term application due to high cost and durability issues in acidic conditions. In this review, we examine the latest developments in engineering PEMWE systems and assess the gap that still needs to be filled for their practical applications. We provide a comprehensive summary of the reaction mechanisms, the correlation among structure-composition-performance, manufacturing methods, system design strategies, and operation protocols of advanced PEMWEs. We also highlight the discrepancies between the critical parameters required for practical PEMWEs and those reported in the literature. Finally, we propose the potential solution to bridge the gap and enable the appreciable applications of PEMWEs. This review may provide valuable insights for research communities and industry practitioners working in these fields and facilitate the development of more cost-effective and durable PEMWE systems for a sustainable energy future.

Regulating Reversible Oxygen Electrocatalysis by Built-in Electric Field of Heterojunction Electrocatalyst with Modified d-Band.

Developing bifunctional catalysts for oxygen electrochemical reactions is essential for high-performance electrochemical energy devices. Here, a Mott-Schottky heterojunction composed of porous cobalt-nitrogen-carbon (Co-N-C) polyhedra containing abundant metal-phosphides for reversible oxygen electrocatalysis is reported. As a demonstration, this catalyst shows excellent activity in the oxygen electrocatalysis and thus delivers outstanding performance in rechargeable zinc-air batteries (ZABs). The built-in electric field in the Mott-Schottky heterojunction can promote electron transfer in oxygen electrocatalysis. More importantly, an appropriate d-band center of the heterojunction catalyst also endows oxygen intermediates with a balanced adsorption/desorption capability, thus enhancing oxygen electrocatalysis and consequently improving the performance of ZABs. The work demonstrates an important design principle for preparing efficient multifunctional catalysts in energy conversion technologies.

An integrated platinum-nanocarbon electrocatalyst for efficient oxygen reduction.

Efficient and robust platinum-carbon electrocatalysts are of great significance for the long-term service of high-performance fuel cells. Here, we report a Pt alloy integrated in a cobalt-nitrogen-nanocarbon matrix by a multiscale design principle for efficient oxygen reduction reaction. This Pt integrated catalyst demonstrates an increased mass activity, 11.7 times higher than that of commercial Pt catalyst, and retains a stability of 98.7% after 30,000 potential cycles. Additionally, this integrated catalyst delivers a current density of 1.50 A cm-2 at 0.6 V in the hydrogen-air fuel cell and achieves a power density of 980 mW cm-2. Comprehensive investigations demonstrate that the synergistic contribution of components and structure in the platinum-carbon integrated catalyst is responsible for the high-efficiency ORR in fuel cells.

Ultrathin rhodium nanosheet-gold nanowire nanocomposites for alkaline methanol oxidation reaction.

Electrostatically assembled ultrathin rhodium nanosheet-gold nanowire nanocomposites (Rh-Au CNSs) were used as an advanced electrocatalyst for the methanol oxidation reaction, which revealed a mass activity of 355 mA mgRh-1 at 0.607 V potential, much higher than single metal Rh nanosheets (273 mA mgRh-1) and commercial Rh nanoparticles (165 mA mgRh-1).

Corrosion Chemistry of Electrocatalysts.

Electrocatalysts are the core components of many sustainable energy conversion technologies that are considered the most potential solution to the worldwide energy and environmental crises. The reliability of structure and composition pledges that electrocatalysts can achieve predictable and stable performance. However, during the electrochemical reaction, electrocatalysts are influenced directly by the applied potential, the electrolyte, and the adsorption/desorption of reactive species, triggering structural and compositional corrosion, which directly affects the catalytic behaviors of electrocatalysts (performance degradation or enhancement) and invalidates the established structure-activity relationship. Therefore, it is necessary to elucidate the corrosion behavior and mechanism of electrocatalysts to formulate targeted corrosion-resistant strategies or use corrosion reconstruction synthesis techniques to guide the preparation of efficient and stable electrocatalysts. Herein, the most recent developments in electrocatalyst corrosion chemistry are outlined, including corrosion mechanisms, mitigation strategies, and corrosion syntheses/reconstructions based on typical materials and important electrocatalytic reactions. Finally, potential opportunities and challenges are also proposed to foresee the possible development in this field. It is believed that this contribution will raise more awareness regarding nanomaterial corrosion chemistry in energy technologies and beyond.

Scalable Molten Salt Synthesis of Platinum Alloys Planted in Metal-Nitrogen-Graphene for Efficient Oxygen Reduction.

Fuel cells are considered as a promising alternative to the existing traditional energy systems towards a sustainable future. Nevertheless, the synthesis of efficient and robust platinum (Pt) based catalysts remains a challenge for practical applications. In this work, we present a simple and scalable molten-salt synthesis method for producing a low-platinum (Pt) nanoalloy implanted in metal-nitrogen-graphene. The as-prepared low-Pt alloyed graphene exhibits a high oxygen reduction activity of 1.29 A mgPt -1 and excellent durability over 30 000 potential cycles. The catalyst nanoarchitecture of graphene encased Pt nanoalloy provides a robust capability against nanoparticle migration and corrosion due to a strong metal-support interaction. Similarly, advanced characterization and theoretical calculations show that the multiple active sites in platinum alloyed graphene synergistically account for the improved oxygen reduction. This work not only provides an efficient and robust low-Pt catalyst but also a facile design idea and scalable preparation technique for integrated catalysts to achieve more profound applications in fuel cells and beyond.

Efficient Nitrate-to-Ammonia Electroreduction at Cobalt Phosphide Nanoshuttles.

The nitrate electroreduction reaction (NO3--ERR) is an efficient and green approach for nitrate remediation, which requires a highly active and selective electrocatalyst. In this work, porous and amorphous cobalt phosphide nanoshuttles (CoP PANSs) are successfully synthesized by using Mg2+ ion-doped calcium carbonate nanoshuttles (Mg-CaCO3 NSs) as the initial reaction precursor via precipitation transformation and a high-temperature phosphidation strategy. Various physical characterizations show that CoP PANSs have porous architecture, amorphous crystal structure, and big surface area. Electrochemical measurements reveal for the first time that CoP PANSs have outstanding electroactivity for NO3--ERR in a neutral electrolyte. At an applied potential of -0.5 V vs reversible hydrogen electrode, CoP PANSs can achieve a high Faraday efficiency (94.24 ± 2.8%) and high yield rate (19.28 ± 0.53 mg h-1 mgcat-1) for ammonia production, which exceeds most reported values at various electrocatalysts for NO3--ERR. Thus, the present result indicates that cobalt phosphide nanomaterials have promising application for NO3--ERR.

Ultrathin NiSe Nanosheets on Ni Foam for Efficient and Durable Hydrazine-Assisted Electrolytic Hydrogen Production.

Hydrazine-assisted electrochemical water splitting is an important avenue toward low cost and sustainable hydrogen production. An efficient and stable bifunctional electrocatalyst for the hydrogen evolution reaction (HER) and the anodic hydrazine oxidation reaction (HzOR) is fundamental to this goal. Herein, we employed a facile method to fabricate ultrathin NiSe nanosheet arrays on nickel foam (NiSe/NF), which exhibits predominant electrocatalytic activity for both HER and HzOR. Our investigations revealed that the excellent electrocatalytic activity of the NiSe/NF mainly arises from the abundant electrocatalytic active sites endowed by the ultrathin nanosheet morphology, the rugged feature of the extended (100) nanosheet surface, the rich presence of Se on the nanosheet surface, and the three-dimensional (3D) porous structure of the NF and other factors such as high conductivity of the NiSe/NF and strong NiSe-NF adhesion. We assembled a hydrazine-boosted electrochemical water splitting cell using NiSe/NF as a bifunctional catalyst for both of the electrodes, and the constructed cell exhibits an ultralow overpotential (310 mV at 10 mA cm-2), which is robust for 30 h continuous electrolysis in a 1 M KOH electrolyte. This work provides a promising avenue toward low cost, high-efficiency, and stable hydrogen production based on hydrazine-assisted electrolytic water splitting for future.

Bifunctional Pd@RhPd Core-Shell Nanodendrites for Methanol Electrolysis.

Methanol electrolysis is a promising strategy to achieve energy-saving and efficient electrochemical hydrogen (H2) production. In this system, the advanced electrocatalysts with high catalytic performance for both the methanol oxidation reaction (MOR) and hydrogen evolution reaction (HER) are highly desirable. Inspired by the complementary catalytic properties of rhodium (Rh) and palladium (Pd) for MOR and HER, herein, several Pd core-RhPd alloy shell nanodendrites (Pd@RhPd NDs) are synthesized through the galvanic replacement reaction between Pd nanodendrites (Pd NDs) and rhodium trichloride. For MOR, Pd@RhPd NDs exhibit Rh content-determined catalytic activity, in which Pd@Rh0.07Pd NDs have an optimal combination of oxidation potential and oxidation current due to the synergistic catalytic process of Pd/Rh double active sites. For HER, the introduction of Rh greatly improves the catalytic activity of Pd@RhPd NDs compared to that of Pd NDs, suggesting that Rh is the main activity site for HER. Unlike MOR, however, the HER activity of Pd@RhPd NDs is not sensitive to the Rh content. Using Pd@Rh0.07Pd NDs as robust bifunctional electrocatalysts, the as-constructed two-electrode methanol electrolysis cell shows a much lower voltage (0.813 V) than that of water electrolysis (1.672 V) to achieve electrochemical H2 production at 10 mA cm-2, demonstrating the application prospect of methanol electrolysis for H2 production.

Bifunctional Palladium Hydride Nanodendrite Electrocatalysts for Hydrogen Evolution Integrated with Formate Oxidation.

The rational design of advanced electrocatalysts and energy-saving electrolysis strategies is highly desirable for achieving high-efficiency electrochemical H2 generation yet challenging. In this work, we report highly branched Pd hydride nanodendrites (PdH-NDs) formed by a very facial solvothermal method and a succedent chemical H intercalation method in N,N-dimethylformamide. The electrocatalytic performance of PdH-NDs is experimentally and theoretically correlated with the morphology and composition, which has demonstrated substantially enhanced electrochemical activity and stability for formate oxidation reaction and hydrogen evolution reaction in alkaline electrolyte compared with Pd nanodendrites. Density functional theory calculations suggest a downshift of the Pd d-band center of PdH-NDs due to the dominant Pd-H ligand effects that weaken the binding energies of the intermediate catalytic species and toxic carbon monoxide. The asymmetric formate electrolyzer based on bifunctional PdH-ND electrocatalysts is first constructed, which only requires a low voltage of 0.54 V at 10 mA cm-2 for continuous H2 generation. This study reveals significant insights about the morphology/composition-performance relationship for palladium hydrides with bifunctional electroactivity.

Hydrogen and Potassium Acetate Co-Production from Electrochemical Reforming of Ethanol at Ultrathin Cobalt Sulfide Nanosheets on Nickel Foam.

The sluggish reaction kinetics of the anodic oxygen evolution reaction increases the energy consumption of the overall water electrolysis for high-purity hydrogen generation. In this work, ultrathin cobalt sulfide nanosheets (Co3S4-NSs) on nickel foam (Ni-F) nanohybrids (termed as Co3S4-NSs/Ni-F) are synthesized using cyanogel hydrolysis and a sulfurization two-step approach. Physical characterizations reveal that Co3S4-NSs with a 1.7 nm thickness have abundant holes, implying the big surface area, abundant active edge atoms, and sufficient active sites. Electrochemical measurements show that as-synthesized Co3S4-NSs/Ni-F have excellent electrocatalytic activity and selectivity for ethanol oxidation reaction and hydrogen evolution reaction. Due to their bifunctional property of Co3S4-NSs/Ni-F nanohybrids, a symmetric Co3S4-NSs/Ni-F∥Co3S4-NSs/Ni-F ethanol electrolyzer can be effectively constructed, which only requires a 1.48 V electrolysis voltage to reach a current density of 10 mA cm-2 for high-purity hydrogen generation at the cathode as well as value-added potassium acetate generation at the anode, much lower than the electrolysis voltage of traditional electrochemical water splitting (1.64 V).

Holey platinum nanotubes for ethanol electrochemical reforming in aqueous solution.

The catalytic/electrocatalytic performance of platinum (Pt) nanostructures highly relates to their morphology. Herein, we propose a facile self-template pyrolysis strategy at high temperature to synthesize one-dimensionally holey Pt nanotubes (Pt-hNTs) using PtII-dimethylglyoxime complex (PtII-DMG) nanorods as the reaction precursor. The coordination capability of DMG results in the generation of PtII-DMG nanorods, whereas the reducibility of DMG at high temperature leads to the reduction of PtII species in PtII-DMG nanorods. During the reaction process, the inside-out Ostwald ripening phenomenon leads to the hollow morphology of Pt-hNTs. Benefiting from the physical characteristics of hollow and holey structure, Pt-hNTs with clean surface show superior electroactivity and durability for catalyzing ethanol electrooxidation as well as hydrogen evolution reaction in alkaline media. Under optimized experimental conditions, the constructed symmetric Pt-hNTs||Pt-hNTs ethanol electrolyzer only requires an electrolysis voltage of 0.40 V to achieve the electrochemical hydrogen production, demonstrating a highly energy saving strategy relative to traditional water electrolysis.

Anodic hydrazine electrooxidation boosted overall water electrolysis by bifunctional porous nickel phosphide nanotubes on nickel foam.

Water electrolysis is an environmentally friendly and sustainable technique for ultra-pure hydrogen production, while expensive electrode materials and high driving voltage have seriously hindered its commercialization process. Here, Earth-abundant bifunctional porous Ni2P hollow nanotubes on nickel foam (Ni2P-HNTs/NF) electrocatalysts are synthesized through a facile self-template method and a phosphating process, which are perfectly combined with the hydrazine electrooxidation reaction (HzOR) boosted water electrolysis. Benefiting from the unique structural characteristic of open-framework and abundant step atoms, Ni2P-HNTs/NF achieves 10 mA cm-2 at 91 mV (vs. RHE) for the cathodic hydrogen evolution reaction and 18 mV (vs. RHE) for the anodic HzOR in a three electrode system, respectively. The corresponding two-electrode hydrazine electrolyzer produces 10 mA cm-2 with a total voltage of only 152 mV for ultra-pure hydrogen production, highlighting a cost-effective and energy-saving water electrolysis mode.