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1.
Dent Mater ; 2024 Jun 13.
Article in English | MEDLINE | ID: mdl-38876828

ABSTRACT

OBJECTIVES: This study aimed to assess antimicrobial efficacy, cytotoxicity, and cytokine release (IL-1b, IL-6, IL-10, TNF-α) from human dental pulp stem cells (hDPSCs) of chitosan (CH) and hydroxyapatite (HAp)-modified glass ionomer cements (GIC). METHODS: GICs with varied CH and HAp concentrations (0 %, 0.16 %, 2 %, 5 %, 10 %) were tested against S. mutans for 24 h or 7 days. Antimicrobial activity was measured using an MTT test. Cytotoxicity evaluation followed for optimal concentrations, analyzing mitochondrial activity and apoptosis in hDPSCs. Cytokine release was assessed with MAGPIX. Antimicrobial analysis used Shapiro-Wilk, Kruskal-Wallis, and Dunnett tests. Two-way ANOVA, Tukey, and Dunnett tests were applied for hDP metabolism and cytokine release. RESULTS: CH 2 % and HAp 5 % significantly enhanced GIC antimicrobial activity, especially after seven days. In immediate analysis, all materials showed reduced mitochondrial activity compared to the control. After 24 h, CH demonstrated mitochondrial metabolism similar to the control. All groups exhibited mild cytotoxicity (∼30 % cell death). Only IL-6 was influenced, with reduced release in experimental groups. SIGNIFICANCE: CH 2 % and HAp 5 % were most effective for antibacterial effects. GIC-CH 2 % emerged as the most promising formula, displaying significant antibacterial effects with reduced hDPSC toxicity.

2.
RFO UPF ; 26(2): 299-312, 20210808. tab
Article in Portuguese | LILACS, BBO - Dentistry | ID: biblio-1452536

ABSTRACT

Objetivo: Várias fontes de luz têm sido utilizadas desde que os materiais fotoativados foram introduzidos na odontologia. Diodos emissores de luz (LEDs) se popularizaram como a principal opção para a polimerização dos materiais restauradores. O objetivo nessa revisão da literatura foi avaliar a influência das fontes de luz emitidas por diodo (LEDs) de segunda e terceira geração sobre a dureza de compósitos restauradores. Revisão de literatura: Nas bases de dados PubMed e Google Scholar foram pré-selecionados 239 artigos na língua inglesa entre os anos de 2010 e 2020, utilizando os termos: lightcuring, LED light sources, and dental LEDs. Dos 239 artigos inicialmente selecionados, 37 artigos foram avaliados devido aos critérios de inclusão/exclusão no estudo. Considerações finais: Vários estudos apontaram diferenças importantes na dureza dos compósitos restauradores testados, tanto na superfície de topo quanto na base. No entanto, essas diferenças estavam mais associadas a características como: estado de conservação do LED, irradiância, tempo de ativação, espectro de emissão dos aparelhos e sua compatibilidade ao fotoiniciador presente no compósito. Assim, podemos considerar que o monitoramento das condições do aparelho, e a escolha correta da fonte de luz de acordo com o compósito a ser utilizado são essenciais para maximizar a dureza dos compósitos restauradores, pois embora os aparelhos de terceira geração sejam preferencialmente indicados para compósitos com fotoiniciadores alternativos, os aparelhos que emitem luz azul apresentam vantagens quando o compósito é ativado apenas pela Canforoquinona.(AU)


Objective: Several light sources have been used since the light-curing materials were introduced in dentistry. Light-emitting diodes (LEDs) have become popular as the main option for the polymerization of restorative materials. This literature review aimed to evaluate the influence of second and third generation Light-emitting Diode (LEDs) sources on the hardness of restorative composites. Literature Review: In the PubMed and Google Scholar databases, 239 scientific papers in English were pre-selected between 2010 and 2020 using light-curing, LED light sources, and dental LEDs. After reading, 37 articles were selected to compose the review. Several studies have pointed out significant differences in the hardness of the tested restorative composites, both on the top and base surfaces. However, these differences were more associated with characteristics such as: LED conservation conditions, irradiance, curing time, the emission spectrum of the devices and their compatibility with the photoinitiator used in the composite. Final Considerations: Thus, it can be considered that monitoring the condition of the device and the correct choice of light sources according to the composite to be used is essential to maximize the hardness of the restorative composites, because although third-generation devices are preferably indicated for composites with alternative photoinitiators, devices that emit blue light have advantages when the composite is activated only by Camphorquinone.(AU)


Subject(s)
Humans , Composite Resins/chemistry , Curing Lights, Dental , Hardness , Dental Materials/chemistry , Light-Curing of Dental Adhesives/methods , Polymerization
3.
J Mech Behav Biomed Mater ; 110: 103875, 2020 10.
Article in English | MEDLINE | ID: mdl-32957185

ABSTRACT

The chemistry of resin-based dental adhesives is critical for its interaction with dental tissues and long-term bonding stability. Changes in dental adhesives composition influences the materials' key physical-chemical properties, such as rate and degree of conversion, water sorption, solubility, flexural strength and modulus, and cohesive strength and improves the biocompatibility to dental tissues. Maintaining a suitable reactivity between photoinitiators and monomers is important for optimal properties of adhesive systems, in order to enable adequate polymerisation and improved chemical, physical and biological properties. The aim of this article is to review the current state-of-the-art of dental adhesives, and their chemical composition and characteristics that influences the polymerisation reaction and subsequent materials properties and performance.


Subject(s)
Dental Bonding , Dentin-Bonding Agents , Adhesives , Composite Resins , Dental Cements , Dentin , Materials Testing , Resin Cements
4.
Dent Mater ; 36(10): 1282-1288, 2020 10.
Article in English | MEDLINE | ID: mdl-32690220

ABSTRACT

OBJECTIVE: To evaluate the influence of different co-initiators (diphenyliodonium hexafluorophosphate - DPI - and bis(4-methyl phenyl)iodonium hexafluorophosphate - BPI) on chemical and mechanical properties of resins. METHODS: Nine experimental resins (50% Bis-GMA and 50% TEGDMA, w/w) with 60 wt% filler particles were formulated. The initiating system used was camphorquinone (CQ-1 mol%) and ethyl dimethylaminobenzoate (EDAB-2 mol%). Experimental groups were established according to DPI and BPI quantities (0.25, 0.5, 0.75, and 1 mol%). The control group was a resin containing only CQ-EDAB. Light transmission through the resin during polymerisation was analysed with a UV-vis spectrophotometer. Real-time polymerisation of the systems was evaluated using an FTIR spectrometer. Real-time polymerisation shrinkage strain was evaluated, and the flexural strength and modulus of materials were obtained by 3-point bending. Experimental groups were statistically analysed by Analysis of Variance and Tukey's test (α = 0.05). Dunnett's test was applied to compare experimental groups with control. RESULTS: Light transmission rapidly increased initially for resins containing DPI or BPI. After 30 s cure, the irradiance on the lower surface of resin specimens was similar for all groups. After 10 s of light irradiation, groups containing DPI and BPI had higher conversion than the control. However, conversion after 120 s post-irradiation was similar for all groups. The rate of polymerisation, shrinkage strain, and the maximum strain rate were higher for groups containing DPI/BPI. The use of iodonium salts increased the flexural strength and flexural moduli of resins. SIGNIFICANCE: DPI and BPI increased resin reactivity similarly. Increased rate of polymerization influenced light transmission through the resin in the first seconds of polymerisation and increased resin shrinkage and rate of shrinkage, as well as flexural strength and moduli.


Subject(s)
Biphenyl Compounds , Onium Compounds , Bisphenol A-Glycidyl Methacrylate , Camphor/analogs & derivatives , Composite Resins , Materials Testing , Methacrylates , Polyethylene Glycols , Polymerization , Polymethacrylic Acids
5.
Restor Dent Endod ; 44(3): e28, 2019 Aug.
Article in English | MEDLINE | ID: mdl-31485424

ABSTRACT

OBJECTIVES: The aim of this study was to evaluate the influence of different concentrations of nanofillers on the chemical and physical properties of ethanol-solvated and non-solvated dental adhesives. MATERIALS AND METHODS: Eight experimental adhesives were prepared with different nanofiller concentrations (0, 1, 2, and 4 wt%) and 2 solvent concentrations (0% and 10% ethanol). Several properties of the experimental adhesives were evaluated, such as water sorption and solubility (n = 5, 20 seconds light activation), real-time degree of conversion (DC; n = 3, 20 and 40 seconds light activation), and stability of cohesive strength at 6 months (CS; n = 20, 20 seconds light activation) using the microtensile test. A light-emitting diode (Bluephase 20i, Ivoclar Vivadent) with an average light emittance of 1,200 mW/cm2 was used. RESULTS: The presence of solvent reduced the DC after 20 seconds of curing, but increased the final DC, water sorption, and solubility of the adhesives. Storage in water reduced the strength of the adhesives. The addition of 1 wt% and 2 wt% nanofillers increased the polymerization rate of the adhesives. CONCLUSIONS: The presence of nanofillers and ethanol improved the final DC, although the DC of the solvated adhesives at 20 seconds was lower than that of the non-solvated adhesives. The presence of ethanol reduced the strength of the adhesives and increased their water sorption and solubility. However, nanofillers did not affect the water sorption and strength of the tested adhesives.

6.
J Mech Behav Biomed Mater ; 98: 71-78, 2019 10.
Article in English | MEDLINE | ID: mdl-31203099

ABSTRACT

To evaluate the effects of Type I and Type II photoinitiator systems on curing efficiency, degree of conversion (DC) and chemico-physical properties of resin based materials. A comonomer base containing 50%wt 2.2-bis[4-(2-hydroxy-3-methacryloxypropoxy)phenyl]propane (bis-GMA) and 50%wt triethyleneglycol dimethacrylate (TEGDMA) was formulated with either 0.5 or 1mol% of Type II camphoroquinone (CQ), Type I monoacylphosphine oxide (MAPO) or bis-acylphosphine oxide (BAPO) photoinitiators. The Type II system was either a binary (1: 2 CQ:amine) or ternary system (1: 2 CQ:amine + 0.5 mol% DPI). Degree and rate of polymerization was measured by Fourier Transform Infrared Spectroscopy (FTIR). Knoop micro-hardness prior to and following ethanol immersion was assessed. Flexural strength and modulus was measured under three-point bend test. Water sorption and solubility was also evaluated. The photoinitiator absorption spectra and the total absorbed energy per unit volume (Eabs) for 0.5mol% photoinitiator in each material was calculated. Despite the reduced total absorbed energy per unit volume for CQ based systems, ternary Type II system significantly improved curing efficiency (P < 0.05) compared to both Type I photoinitiators and degree of conversion compared to MAPO only, whilst exhibiting comparable mechanical and physical properties compared to both Type I based materials at equivalent molar concentrations of photoinitiator (P > 0.05). Ternary Type II systems is an efficient alternative to improve the polymerization of resin materials, promoting similar or even better properties than Type I initiators. DPI can increase the reactivity of CQ systems and promote polymerization rates superior than Type I photoinitiators.


Subject(s)
Photochemical Processes , Polymerization , Resins, Synthetic/chemistry , Kinetics , Solubility
7.
Braz Oral Res ; 32: e116, 2018 Nov 14.
Article in English | MEDLINE | ID: mdl-30462750

ABSTRACT

The aim of this study was to analyze the efficiency of experimental light-curing resin cements (ERCs) with a ternary photo-initiator system containing diphenyliodonium hexafluorphosphate (DPI) and different amines on retention of glass-fiber posts to dentin (GFP). ERCs formulations: a 1:1 mass ratio of 2,2-bis[4-(2-hydroxy-3-methacryloxypropoxy)phenylpropane and triethyleneglycol dimethacrylate. Camphorquinone was used as initiator. Six experimental groups were established according to the amine used: [ethyl-4-(dimethylamino)benzoate-EDMAB or 2-(dimethylamino)ethyl methacrylate-DMAEMA] and the concentration of DPI (0, 0.5 mol%, 1 mol%). The resin cements Variolink II (dual- and light-cured versions) were used as commercial reference. Eighty recently extracted bovine incisors (n = 10) were selected for this study. The roots were prepared and the fiber posts were cemented with the resin cement specified for each experimental group. Specimens from coronal, middle, and apical thirds of the root were subjected to push-out bond strength test 24 hours after bonding. Data were subjected to split-plot ANOVA and the Tukey test (p = 0.05). ERCs containing DPI showed statistically significant higher bond strengths compared with ERCs without DPI. ERCs containing DPI were statistically similar to VARIOLINK II - dual-cured and superior to VARIOLINK II - light-cured (except for EDMAB - 1DPI in the medium third and DMAEMA - 1DPI in the coronal third). Different amines did not influence post retention. The apical root region showed the lowest bond strength for the groups EDAB-0DPI, DMAEMA-0DPI and VARIOLINK II light-cured. Light-cured ERCs containing DPI were efficient for GFP retention to radicular dentin, with similar behaviour to that of dual-curing commercial resin cement.


Subject(s)
Biphenyl Compounds/chemistry , Dentin/drug effects , Light-Curing of Dental Adhesives/methods , Onium Compounds/chemistry , Photoinitiators, Dental/chemistry , Post and Core Technique , Resin Cements/chemistry , Tooth Apex/drug effects , Analysis of Variance , Biphenyl Compounds/radiation effects , Curing Lights, Dental , Dentin/radiation effects , Glass/chemistry , Glass/radiation effects , Materials Testing , Methacrylates/chemistry , Methacrylates/radiation effects , Onium Compounds/radiation effects , Photoinitiators, Dental/radiation effects , Polymerization , Resin Cements/radiation effects , Time Factors , Tooth Apex/radiation effects , Tooth Fractures , para-Aminobenzoates/chemistry , para-Aminobenzoates/radiation effects
8.
Restor Dent Endod ; 43(3): e32, 2018 Aug.
Article in English | MEDLINE | ID: mdl-30135851

ABSTRACT

OBJECTIVES: This study evaluated the effects of a bleaching agent on the composition, mechanical properties, and surface topography of 6 conventional glass-ionomer cements (GICs) and one resin-modified GIC. MATERIALS AND METHODS: For 3 days, the specimens were subjected to three 20-minute applications of a 37% H2O2-based bleaching agent and evaluated for water uptake (WTK), weight loss (WL), compressive strength (CS), and Knoop hardness number (KHN). Changes in surface topography and chemical element distribution were also analyzed by energy-dispersive X-ray spectroscopy and scanning electron microscopy. For statistical evaluation, the Kruskal-Wallis and Wilcoxon paired tests (α = 0.05) were used to evaluate WTK and WL. CS specimens were subjected to 2-way analysis of variance (ANOVA) and the Tukey post hoc test (α = 0.05), and KH was evaluated by one-way ANOVA, the Holm-Sidak post hoc test (α = 0.05), and the t-test for independent samples (α = 0.05). RESULTS: The bleaching agent increased the WTK of Maxxion R, but did not affect the WL of any GICs. It had various effects on the CS, KHN, surface topography, and the chemical element distribution of the GICs. CONCLUSIONS: The bleaching agent with 37% H2O2 affected the mechanical and surface properties of GICs. The extent of the changes seemed to be dependent on exposure time and cement composition.

9.
PLoS One ; 13(8): e0202295, 2018.
Article in English | MEDLINE | ID: mdl-30133509

ABSTRACT

OBJECTIVE: The aim of this in vitro study, is to evaluate the penetration of a bioceramic root canal sealer into dentinal tubules at 3 mm and 5 mm from the apex after Nd:YAG laser irradiation. METHODS: Forty freshly extracted human mandibular premolars were prepared using Reciproc® and irrigated with 17% ethylenediaminetetraacetic acid (EDTA). Teeth were divided into 4 groups: group 1, obturated with control sealer (AH Plus®); group 2, obturated with bioceramic sealer (Endosequence BC Sealer®); group 3, Nd:YAG laser + control sealer (AH Plus®); and group 4, Nd:YAG laser + bioceramic sealer (Endosequence BC Sealer®). The samples were transversely sectioned 3 mm and 5 mm from the apex and examined using confocal laser scanning microscopy. Two parameters were measured: 1) sealer penetration into dentinal tubules of the root canal and 2) sealer penetration into the perimeter of the root canal walls. RESULTS: Penetration analysis showed that bioceramic sealer had a higher penetration at depths of 3 and 5 mm than that of the control sealer, regardless of laser use (p <0.05). Perimeter analysis showed that there was no difference between both sealers at a depth of 3 mm (p <0.05), regardless of laser use. At a depth of 5 mm, bioceramic sealer and laser showed a greater perimeter of penetration (p <0.05) than the control sealer. CONCLUSION: The use of Nd:YAG laser did not compromise the penetration of bioceramic sealer into dentinal tubules of root canals at 3 mm and 5 mm from the apex.


Subject(s)
Dental Pulp Cavity/radiation effects , Lasers, Solid-State , Root Canal Filling Materials/radiation effects , Zinc Oxide-Eugenol Cement/radiation effects , Bicuspid/pathology , Bicuspid/radiation effects , Dental Pulp Cavity/pathology , Humans , In Vitro Techniques , Materials Testing , Microscopy, Confocal , Root Canal Therapy
10.
Stomatologija ; 20(4): 119-124, 2018.
Article in English | MEDLINE | ID: mdl-31074458

ABSTRACT

OBJECTIVE: To evaluate the effects of dyphenyliodonium hexafluorophosphate (DPI) on crosslink density (CLD), flexural strength (FS), and flexural modulus (FM) of a light-cured experimental resin cement compared with a commercial dual-cured cement. MATERIALS AND METHODS: Bis-GMA combined with TEGDMA (50-50%) was used as resin matrix. Silanated barium-aluminum-silica glass was used as inorganic filler. Camphorquinone (CQ) - 1 mol%, 2-(dimethylamino)ethyl methacrylate (DMAEMA) - 2 mol%, and two concentrations of DPI (0 or 0.5 mol%) were used as the photoinitiator system. Two light-curing units (LCUs) were used (a single-peak (Radii-Cal) and a polywave (Bluephase)). The CLD was indirectly assessed in a softening test by Knoop hardness indentation; FS and FM were measured by means of a three-point bending test. RESULTS: DPI positively influenced Knoop hardness when compared with experimental resin without DPI. The flexural strength of experimental cements was lower than that found with Variolink II. The crosslinking density (obtained by reduction of Knoop hardness) of cement with 0.5% DPI was similar to that of dual - cured Variolink II. CONCLUSIONS: DPI showed an improvement in some of the properties tested but was inferior to the commercial dual-cured resin cement. The LCUs had no influence on the flexural strength of the resin cements.


Subject(s)
Biphenyl Compounds , Curing Lights, Dental , Materials Testing , Onium Compounds , Resin Cements , Mechanical Phenomena
11.
Braz. oral res. (Online) ; 32: e116, 2018. tab, graf
Article in English | LILACS | ID: biblio-974442

ABSTRACT

Abstract The aim of this study was to analyze the efficiency of experimental light-curing resin cements (ERCs) with a ternary photo-initiator system containing diphenyliodonium hexafluorphosphate (DPI) and different amines on retention of glass-fiber posts to dentin (GFP). ERCs formulations: a 1:1 mass ratio of 2,2-bis[4-(2-hydroxy-3-methacryloxypropoxy)phenylpropane and triethyleneglycol dimethacrylate. Camphorquinone was used as initiator. Six experimental groups were established according to the amine used: [ethyl-4-(dimethylamino)benzoate-EDMAB or 2-(dimethylamino)ethyl methacrylate-DMAEMA] and the concentration of DPI (0, 0.5 mol%, 1 mol%). The resin cements Variolink II (dual- and light-cured versions) were used as commercial reference. Eighty recently extracted bovine incisors (n = 10) were selected for this study. The roots were prepared and the fiber posts were cemented with the resin cement specified for each experimental group. Specimens from coronal, middle, and apical thirds of the root were subjected to push-out bond strength test 24 hours after bonding. Data were subjected to split-plot ANOVA and the Tukey test (p = 0.05). ERCs containing DPI showed statistically significant higher bond strengths compared with ERCs without DPI. ERCs containing DPI were statistically similar to VARIOLINK II - dual-cured and superior to VARIOLINK II - light-cured (except for EDMAB - 1DPI in the medium third and DMAEMA - 1DPI in the coronal third). Different amines did not influence post retention. The apical root region showed the lowest bond strength for the groups EDAB-0DPI, DMAEMA-0DPI and VARIOLINK II light-cured. Light-cured ERCs containing DPI were efficient for GFP retention to radicular dentin, with similar behaviour to that of dual-curing commercial resin cement.


Subject(s)
Onium Compounds/chemistry , Biphenyl Compounds/chemistry , Post and Core Technique , Tooth Apex/drug effects , Resin Cements/chemistry , Dentin/drug effects , Light-Curing of Dental Adhesives/methods , Photoinitiators, Dental/chemistry , Onium Compounds/radiation effects , Time Factors , Tooth Fractures , Biphenyl Compounds/radiation effects , Materials Testing , Analysis of Variance , Tooth Apex/radiation effects , Resin Cements/radiation effects , Dentin/radiation effects , Curing Lights, Dental , Photoinitiators, Dental/radiation effects , Polymerization , para-Aminobenzoates/radiation effects , para-Aminobenzoates/chemistry , Glass/radiation effects , Glass/chemistry , Methacrylates/radiation effects , Methacrylates/chemistry
12.
Restor Dent Endod ; 41(4): 271-277, 2016 Nov.
Article in English | MEDLINE | ID: mdl-27847748

ABSTRACT

OBJECTIVES: In this study, we evaluated the influence of different radiant exposures provided by single-peak and polywave light-curing units (LCUs) on the degree of conversion (DC) and the mechanical properties of resin cements. MATERIALS AND METHODS: Six experimental groups were established for each cement (RelyX ARC, 3M ESPE; LuxaCore Dual, Ivoclar Vivadent; Variolink, DMG), according to the different radiant exposures (5, 10, and 20 J/cm2) and two LCUs (single-peak and polywave). The specimens were made (7 mm in length × 2 mm in width × 1 mm in height) using silicone molds. After 24 hours of preparation, DC measurement was performed using Fourier transform infrared spectrometry. The same specimens were used for the evaluation of mechanical properties (flexural strength, FS; elastic modulus, E) by a three-point bending test. Data were assessed for normality, after which two-way analysis of variance (ANOVA) and post hoc Tukey's test were performed. RESULTS: No properties of the Variolink cement were influenced by any of the considered experimental conditions. In the case of the RelyX ARC cement, DC was higher when polywave LCU was used; FS and E were not influenced by the conditions evaluated. The LuxaCore cement showed greater sensitivity to the different protocols. CONCLUSIONS: On the basis of these results, both the spectrum of light emitted and the radiant exposure used could affect the properties of resin cements. However, the influence was material-dependent.

13.
Dent Mater ; 32(6): 749-55, 2016 06.
Article in English | MEDLINE | ID: mdl-27056595

ABSTRACT

OBJECTIVE: The present study evaluated the influence of diphenyliodonium hexafluorphosphate (DPI) combined with two different amines [ethyl 4-(dimethylamino)benzoate (EDAB) and 2-(dimethylamino)ethyl methacrylate (DMAEMA)] on the properties of model resin cements. METHODS: A comonomer base containing a 1:1 mass ratio of 2.2-bis[4-(2-hydroxy-3-methacryloxypropoxy)phenyl]propane (bis-GMA) and triethyleneglycol dimethacrylate (TEGDMA) was obtained, after which 1mol% of camphorquinone and 0.1mol% of hydroxyl butyl toluene were added to the comonomer blend. Concentrations of co-initiators varied at 0, 0.5 or 1mol% for DPI and in 1 or 2mol% for amines (DMAEMA or EDAB). Silanated Ba-Al-Si glass (60wt%) was added as filler. The combination of each amine and DPI concentration resulted in 12 formulations, which had the following properties analyzed: degree of conversion (DC), water sorption (Wsp) and solubility (Wsl), flexural strength (FS) and flexural modulus (Ef). Data for DC, FS and Ef were analyzed by two-way ANOVA and Tukey's test (α=0.05) and Wsp and Wsl by Kruskal-Wallis and Dunn tests (α=0.05). RESULTS: EDAB promoted a higher DC than did DMAEMA; however, DPI increased DC for all materials with DMAEMA. The physical properties of resin formulations containing EDAB were significantly better than those of groups with DMAEMA; however, DPI had a positive influence on the chemical and physical properties of the model resin cement containing DMAEMA, especially with higher concentrations of amine. SIGNIFICANCE: EDAB proved to be more reactive than DMAEMA, being less influenced by DPI. Resins containing a 1:2 CQ/amine ratio had better properties than those with 1:1.


Subject(s)
Methacrylates , Resin Cements , Benzoates , Biphenyl Compounds , Humans , Materials Testing , Onium Compounds
14.
Dent Mater ; 32(6): 756-64, 2016 06.
Article in English | MEDLINE | ID: mdl-27048975

ABSTRACT

OBJECTIVES: To evaluate the effects of the diphenyliodonium hexafluorophosphate (DPI) on the physical and mechanical properties of solvated dental adhesive resins containing camphorquinone (CQ) and/or 1-phenyl-1,2-propanedione (PPD) as initiators. METHODS: Model solvated resins containing bisphenol glycidyl methacrylate (BisGMA); triethyleneglycol dimethacrylate (TEGDMA); 1,3-glycerol dimethacrylate (GDMA); 2-hydroxyethyl methacrylate (HEMA); dimethylaminoethyl amine benzoate (EDAB) and ethanol were prepared. The resins were divided in 24 test groups according to the incorporated initiator systems (CQ-0.5 or 1mol%; PPD-0.5 or 1mol%; CQ+PPD-0.5 or 1mol%) as well the presence of DPI (0, 0.5 or 1mol%). Degree of conversion (using Fourier-transformed near infra-red spectroscopy), flexural strength and modulus by three point bending, cohesive strength and water sorption and solubility were measured. Data were statistically analyzed by one and two way ANOVA and Tukey's test (α=0.05). RESULTS: DPI increased the degree of conversion of all materials tested. Camphorquinone promoted higher degree of conversion than resins containing only PPD or CQ+PPD. Generally, the resins containing PPD+CQ with DPI presented higher flexural strength and modulus, cohesive strength, as well lower water sorption and solubility. SIGNIFICANCE: The use of PPD combined with CQ can increase the physical properties of the solvated resins. DPI improved the monomer conversion of all experimental materials and can positively modulate most of the physical properties of the solvated resins.


Subject(s)
Biphenyl Compounds , Chalcones , Composite Resins , Onium Compounds , Camphor/analogs & derivatives , Materials Testing , Methacrylates
15.
Restor Dent Endod ; 41(1): 44-54, 2016 Feb.
Article in English | MEDLINE | ID: mdl-26877990

ABSTRACT

OBJECTIVES: The purpose of this study was to evaluate the histopathological effects of an antioxidant therapy on the pulp tissue of rat teeth exposed to a bleaching gel with 35% hydrogen peroxide. MATERIALS AND METHODS: Forty rats were subjected to oral ingestion by gavage of distilled water (DW) or ascorbic acid (AA) 90 min before the bleaching therapy. For the bleaching treatment, the agent was applied twice for 5 min each to buccal surfaces of the first right mandibular molars. Then, the animals were sacrificed at 6 hr, 24 hr, 3 day, or 7 day post-bleaching, and the teeth were processed for microscopic evaluation of the pulp tissue. RESULTS: At 6 hr, the pulp tissue showed moderate inflammatory reactions in all teeth of both groups. In the DW and AA groups, 100% and 80% of teeth exhibited pulp tissue with significant necrosis and intense tissue disorganization, respectively. At 24 hr, the AA-treated group demonstrated a greater regenerative capability than the DW group, with less intense inflammatory reaction and new odontoblast layer formation in 60% of the teeth. For up to the 7 day period, the areas of pulpal necrosis were replaced by viable connective tissue, and the dentin was underlined by differentiated odontoblast-like cells in most teeth of both groups. CONCLUSIONS: A slight reduction in initial pulpal damage during post-bleaching was promoted by AA therapy. However, the pulp tissue of AA-treated animals featured faster regenerative potential over time.

16.
Clín. int. j. braz. dent ; 11(3): 272-279, jul.-set.2015. ilus
Article in Portuguese | LILACS | ID: lil-790482

ABSTRACT

A contração de polimerização da resina composta pode desenvolver tensões na interface dente-restauração e estrutura dental remanescente, resultando em deformação de cúspide, sensibilidade pós-operatória e fenda marginal. Este artigo apresenta, por meio da associação de evidência científica e relato de caso, uma reflexão de como o clínico pode minimizar os efeitos da contração de resina composta em dentes posteriores. Ainda persistem dúvidas sobre resinas em dentes posteriores, um dos procedimentos mais prevalentes em saúde bucal. A associação de estudos laboratoriais e simulação computacional, por meio de elementos finitos, pode auxiliar na solução de problemas clínicos constantes. A odontologia baseada em evidências, que dá suporte à tomada de decisão, é fundamental para o sucesso clínico desses procedimentos...


The polymerization shrinkage of composite resin is responsible for developing stresses in the tooth/restoration interface and the remaining tooth structure, causing cusp deflection, pos-operative sensitivity and marginal gap. This article presents thoughts based in scientific evidence associated to a case report, on how clinicians may minimize the effects of the polymerization shrinkage in posterior teeth. There are still remaining doubts about posterior composite resin restorations, one of the most prevalent dental procedures. The association of laboratory studies and computer simulation using finite element analysis can assist clinicians to solve frequent problems. Evidence-based Dentistry supporting the decision-making process is critical to the clinical success of these restorative procedures...


Subject(s)
Humans , Composite Resins , Dental Restoration, Permanent , Esthetics, Dental , Polymerization
17.
Gen Dent ; 63(4): 22-6, 2015.
Article in English | MEDLINE | ID: mdl-26147163

ABSTRACT

The aim of this in vitro study was to evaluate the influence of different irrigation protocols on the bond strength, at different root depths, of fiber posts cemented with a self-adhesive cement 24 hours after endodontic treatment. Fifty-six bovine incisor roots were endodontically prepared and separated into 7 groups (n = 8) according to irrigation protocols: group 1, sterile saline (control); group 2, chlorhexidine (CHX) gel 2% and saline; group 3, sodium hypochlorite (NaOCl) 5.25% and saline; group 4, CHX and saline (final irrigation with ethylenediaminetetraacetic acid [EDTA] 17%); group 5, NaOCl and saline (final irrigation with EDTA); group 6, CHX and saline (final irrigation with NaOCl and EDTA); and group 7, NaOCl (final irrigation with CHX and EDTA). No statistically significant difference was found among the groups. Within the limitations of this study, it can be concluded that the different irrigation protocols did not influence the bond strength of self-adhesive resin cement, which presented similar behaviors at the 3 root depths studied.


Subject(s)
Dental Bonding/methods , Dental Cements/therapeutic use , Post and Core Technique , Root Canal Irrigants/therapeutic use , Root Canal Therapy/methods , Animals , Cattle , Chlorhexidine/administration & dosage , Chlorhexidine/therapeutic use , Dental Stress Analysis , Edetic Acid/administration & dosage , Edetic Acid/therapeutic use , Root Canal Irrigants/administration & dosage , Root Canal Preparation/methods , Sodium Hypochlorite/administration & dosage , Sodium Hypochlorite/therapeutic use
18.
Clín. int. j. braz. dent ; 10(4): 394-400, out.-dez. 2014. ilus
Article in Portuguese | LILACS, BBO - Dentistry | ID: lil-789878

ABSTRACT

Atualmente a estética tem sido o principal motivo pelo qual diversos pacientes buscam o consultório odontológico. Em muitas situações, as cerâmicas são os materiais de escolha para a restauração dos dentes anteriores, no entanto diversos fatores devem ser avaliados na decisão do melhor protocolo a ser realizado. Uma visão ampla sobre o quadro apresentado também é necessária, observando-se a necessidade de realização não só de procedimentos restauradores, mas também ortodônticos e periodontais. Diante disso, o presente artigo demonstra a abordagem multidisciplinar na obtenção da estética dos dentes anteriores, através de cirurgia plástica periodontal e finalização do caso utilizando resinas compostas diretas. A combinação dessas técnicas permitiu devolver harmonia e naturalidade ao sorriso, restabelecendo as características da região anterior.


Currently, aesthetics has been the main reason why many patients seek the dental office. In many situations, ceramics is the material of choice for the restoration of anterior teeth. However, many factors must be evaluated when deciding the best protocol to be performed. A comprehensive view of the situation presented is also required, observing, not only, the need to perform restorative, but orthodontic and periodontal procedures. In view of this, the present article demonstrates a multidisciplinary approach in obtaining the aesthetics of anterior teeth through periodontal plastic surgery, finalizing the case using direct composite resins. The combination of these techniques made it possible to restore harmony and naturality to the smile, by restoring the characteristics of the anterior region.


Subject(s)
Humans , Female , Composite Resins , Esthetics, Dental , Gingiva/surgery , Smiling
19.
Clín. int. j. braz. dent ; 10(4): 420-427, out.-dez. 2014. ilus
Article in Portuguese | LILACS, BBO - Dentistry | ID: lil-789881

ABSTRACT

A remodelação estética do sorriso pode ser realizada de duas maneiras: por meio de restaurações diretas, utilizando-se resinas compostas; ou com restaurações indiretas, utilizando-se coroas, facetas e/ou laminados cerâmicas. A abordagem minimamente invasiva, em foco nos últimos anos, tem-se mostrado efetiva na obtenção de excelentes resultados estéticos, com restaurações imperceptíveis. Desse modo, o presente trabalho demonstra, mediante relato de caso clínico, a abordagem minimamente invasiva, suas vantagens e desvantagens, utilizadas para a remodelação de dois laterais conoides, a qual influenciou a harmonia dos elementos anteriores e a estética do sorriso.


The aesthetic reshaping of the smile can be reached, basically, in two ways: direct restorations using composite resins; or using indirect restorations, such as full crowns and laminate veneers. A minimally invasive approach in focus in the last years, has obtained great results, with imperceptible restorations. In this way, this case report demonstrates the pros and cons of the minimal invasive approach for reshaping lateral conoid shaped incisors, which directly influenced the harmony of the maxillary anterior teeth and the aesthetics of the smile.


Subject(s)
Humans , Female , Young Adult , Ceramics , Dental Veneers , Esthetics, Dental , Incisor , Diastema
20.
J. res. dent ; 2(5): 370-375, sep.-oct2014.
Article in English | LILACS, BBO - Dentistry | ID: biblio-1363352

ABSTRACT

AIM: To evaluate the effect of composite pre-heating on the microhardness of different monomer resin-based. MATERIALS AND METHOD: Circular specimens of methacrylate- and silorane-based composite resins pre-heated at 23, 39, and 55˚ C were carried out, and cured using a halogen light-curing unit at 650 mW/cm². After 24 h, the specimens were polished and Knoop hardness number (KHN) was measured using a microhardness tester with 50-g load for 15 s. The data were analyzed with ANOVA and Tukey's tests (α = 0.05). RESULTS: Top surface presented higher KHN than bottom, methacrylate-based composite showed higher KHN compared to silorane, and pre-heating increased the KHN of the composites tested. CONCLUSION: Pre-heating can be used to improve the microhardness of methracrylate- and silorane-based composites.


Subject(s)
Humans , Composite Resins , Polymerization , Silorane Resins , Methacrylates
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