Organic carbon causes interference with nitrate and nitrite measurements by UV/Vis spectrometers: the importance of local calibration.

Compared with sporadic conventional water sampling, continuous water-quality monitoring with optical sensors has improved our understanding of freshwater dynamics. The basic principle in photometric measurements is the incident light at a given wavelength that is either reflected, scattered, or transmitted in the body of water. Here, we discuss the transmittance measurements. The amount of transmittance is inversely proportional to the concentration of the substance measured. However, the transmittance is subject to interference, because it can be affected by factors other than the substance targeted in the water. In this study, interference with the UV/Vis sensor nitrate plus nitrite measurements caused by organic carbon was evaluated. Total or dissolved organic carbon as well as nitrate plus nitrite concentrations were measured in various boreal waters with two UV/Vis sensors (5-mm and 35-mm pathlengths), using conventional laboratory analysis results as references. Organic carbon increased the sensor nitrate plus nitrite results, not only in waters with high organic carbon concentrations, but also at the lower concentrations (< 10 mg C L-1) typical of boreal stream, river, and lake waters. Our results demonstrated that local calibration with multiple linear regression, including both nitrate plus nitrite and dissolved organic carbon, can correct the error caused by organic carbon. However, high-frequency optical sensors continue to be excellent tools for environmental monitoring when they are properly calibrated for the local water matrix.

Nutrient loads from agricultural and forested areas in Finland from 1981 up to 2010-can the efficiency of undertaken water protection measures seen?

Long-term data from a network of intensively monitored research catchments in Finland was analysed. We studied temporal (1981-2010) and spatial variability in nitrogen (N) and phosphorus (P), from 1987 losses, both from agricultural and forestry land. Based on trend analysis, total nitrogen (TN) concentrations increased in two of the four agricultural sites and in most of the forested sites. In agricultural catchments, the total phosphorus (TP) trends were decreasing in two of the four catchments studied. Dissolved P (DRP) concentrations increased in two catchments and decreased in one. The increase in DRP concentration can be a result of reducing erosion by increased non-plough cultivation and direct sowing. In forested catchments, the TP trends in 1987-2011 were significantly decreasing in three of the six catchments, while DRP concentrations decreased significantly in all sites. At the same time, P fertilisation in Finnish forests has decreased significantly, thus contributing to these changes. The mean annual specific loss for agricultural land was on average 15.5 kg ha-1 year-1 for N and 1.1 kg ha-1 year-1 for P. In the national scale, total TN loading from agriculture varied between 34,000-37,000 t year-1 and total P loading 2400-2700 t year-1. These new load estimates are of the same order than those reported earlier, emphasising the need for more efforts with wide-ranging and carefully targeted implementation of water protection measures.