Ultrasensitive Bio-H2S Gas Sensor Based on Cu2O-MWCNT Heterostructures.

Developing a respiratory analysis disease diagnosis platform for the H2S biomarker has great significance for the real-time detection of various diseases. However, achieving highly sensitive and rapid detection of H2S gas at the parts per billion level at low temperatures is one of the most critical challenges for developing portable exhaled gas sensors. Herein, Cu2O-multiwalled carbon nanotube (MWCNT) heterostructures with excellent gas sensitivity to H2S at room temperature and a lower temperature were successfully synthesized by a facile two-dimensional (2D) electrodeposition in situ assembly method. The combination of Cu2O and MWCNTs via the principle of optimal conductance growth not only reduced the initial resistance of the material but also provided an ideal interfacial barrier structure. Compared to the response of the pure Cu2O sensor, that of the Cu2O-MWCNT sensor to 1 ppm of H2S increased nearly 800 times at room temperature, and the response time decreased by more than 500 s. In addition to the excellent sensitivity with detection limits as low as 1 ppb, the Cu2O-MWCNT sensor was extremely selective with low-temperature adaptability. The sensor had a response value of 80.6 to 0.1 ppm of H2S at -10 °C, which is difficult to achieve with sensors based on oxygen adsorption/desorption mechanisms. The sensor was used for the detection of real oral exhaled breath, confirming its feasibility as a real-time disease monitoring sensor. The Cu2O-MWCNT heterostructures maximized the advantages of the individual components and laid the experimental foundation for future applications of highly sensitive portable breath analysis platforms for monitoring H2S.

Double Modification of Poly(urethane-urea): Toward Healable, Tear-Resistant, and Mechanically Robust Elastomers for Strain Sensors.

Polyurethane elastomers with mechanical robustness, tear resistance, and healing efficiency hold great potential in wearable sensors and soft robots. However, achieving excellent mechanical properties and healable capability simultaneously remains highly desirable but exclusive. Herein, we propose a straightforward procedure for double modification of poly(urethane-urea) (PUU) via thiolactone chemistry, and two different dynamic cross-linking bonds (disulfide linkages and Zn2+/imidazole coordination) are successively incorporated into the side chain of PUU, producing double cross-linking elastomers (PUU-I/Zn-S). The synergy between disulfide linkages and Zn2+/imidazole coordination forms a robust and dynamic network, endowing PUU-I/Zn-S with excellent mechanical and healing properties. The tensile stress, elongation at break, and toughness of the resultant elastomer can reach 44.06 MPa, 1000%, and 181.93 MJ m-3, respectively. Meanwhile, PUU-I/Zn-S exhibits outstanding tearing resistance with a tearing energy of 42.1 kJ m-2. The PUU-I/Zn-S can restore its mechanical robustness after self-healing at room temperature (25 ± 2 °C) or 60 °C and even maintain 91% of its original tensile strength after reprocessing two times. Additionally, PUU-I/Zn-S-based strain sensors are fabricated by introducing conductive nanofillers and demonstrate remarkable sensing capability to diverse human body motions. This work demonstrates a simple and feasible method for the postfunctionalization and enhancement of polyurethane and provides some insights into reconciling the traditional contradictory properties of mechanical robustness and healing efficiency.

A flexible, robust and multifunctional montmorillonite/aramid nanofibers@MXene electromagnetic shielding nanocomposite with an alternating structure for enhanced Joule heating and fire-resistant protective performance.

With the rapidly increasing development of portable devices and flexible electronic devices, multifunctional composites with excellent mechanical strength, great electromagnetic interference shielding, great Joule heating performance and strong fire-resistant protective performance are noticeably required. Herein, inspired by the sandwich structure, we have designed a montmorillonite/aramid nanofibers@MXene (MMT/ANFs@MXene) nanocomposite with an alternating multilayered structure via a simple AVF process. In this nanocomposite, the ANFs/MMT (AT) layer acts as a mechanically reinforced and insulation protection layer, while the MXene layer maintains a complete conductive network. The superior alternating multilayered structure endows the nanocomposite with outstanding mechanical properties (154.66 MPa, 14.22%) and excellent EMI shielding effectiveness values (58.4 dB). In addition, the fire-resistant protective performance of the nanocomposite improves its safety and reliability, especially, the EMI shielding effectiveness is maintained at ∼34 dB after burning for 30 s. Besides, the MMT/ANFs@MXene nanocomposite shows excellent Joule heating performance with a fast thermal response, low driving voltage and long-time temperature stability, which could reach 110.2 °C at only 3 V applied voltage within 10 s. As a result, this work presents a novel strategy for constructing multifunctional composites with outstanding overall performance, which will broaden application areas and prospects in thermal management and EMI shielding in wearable products.

Healable Strain Sensor Based on Tough and Eco-Friendly Biomimetic Supramolecular Waterborne Polyurethane.

Stretchable sensors are essential for flexible electronics, which can be made with polymer elastomers as the matrix. The main challenge in producing practical devices is to obtain polymers with mechanical stability, eco-friendliness, and self-healing properties. Herein, we introduce urea bonds and 2-ureido-4[1H]-pyrimidinone (UPy) to synthesize tailored waterborne polyurethanes (WPU-UPy-x) with a hierarchical hydrogen bond (H-bond). Accordingly, sound tensile performance (strength: 53.33 MPa, toughness: 128.97 MJ m-3), satisfying deformation recovery, and good self-healing capability of the WPU-UPy-x film are demonstrated. With atomic force microscope characterization, we find that UPy groups contribute to the highly improved microphase separation of WPU-UPy-x, responsible for good mechanical properties. As a proof of concept, a strain sensor is successfully configured, thanks to the good interfacial interactions between the polyurethane matrix and the Ti3C2Tx MXene conductive filler, which features sensitive and stable performance for monitoring diverse human and mechanical motions. Intriguingly, this sensor is capable of self-healing after cutting and displays well-retained sensitivity to detect the stretched signal. The as-proposed design concept for healable and sensitive strain sensors can shed light on future wearable electronics.

Preparation of Poly(thiol-urethane) Covalent Adaptable Networks Based on Multiple-Types Dynamic Motifs.

To solve the issue of polymeric materials recycling, developing intrinsic self-healing materials containing dynamic bonds has attracted many researchers' highly concerning. However, the tradeoff between their mechanical strength and stretchability always does not avoid. Herein, to surmount the above tradeoff, metal-ligand (Cu2+ -S) interactions are introduced into the cross-linking polythiourethane covalent adaptable networks (PTU CANs) with three kinds of dynamic motifs (thiourethane, disulfide, and hydrogen bonds). When the molar ratio of Cu2+ to S is 6.37%, the break strength (9.41 ± 0.34 MPa) and Young's modulus (26.02 ± 0.55 MPa) of the metal-ligand coordination complex PTU (Cu2+ -PTU-3) dramatically increase, whereas the peak strain almost does not decline (454.44 ± 3.95%). To conduct the repairing, Cu2+ -PTU-3 is further confirmed excellent repairing capability. Therefore, these new PTU CANs have significant potential for the new self-healing materials.

Conductive Antibacterial Hemostatic Multifunctional Scaffolds Based on Ti3C2Tx MXene Nanosheets for Promoting Multidrug-Resistant Bacteria-Infected Wound Healing.

Chronic bacterial-infected wound healing/skin regeneration remains a challenge due to drug resistance and the poor quality of wound repair. The ideal strategy is combating bacterial infection, while facilitating satisfactory wound healing. However, the reported strategy hardly achieves these two goals simultaneously without the help of antibiotics or bioactive molecules. In this work, a two-dimensional (2D) Ti3C2Tx MXene with excellent conductivity, biocompatibility, and antibacterial ability was applied in developing multifunctional scaffolds (HPEM) for methicillin-resistant Staphylococcus aureus (MRSA)-infected wound healing. HPEM scaffolds were fabricated by the reaction between the poly(glycerol-ethylenimine), Ti3C2Tx MXene@polydopamine (MXene@PDA) nanosheets, and oxidized hyaluronic acid (HCHO). HPEM scaffolds presented multifunctional properties containing self-healing behavior, electrical conductivity, tissue-adhesive feature, antibacterial activity especially for MRSA resistant to many commonly used antibiotics (antibacterial efficiency was 99.03%), and rapid hemostatic capability. HPEM scaffolds enhanced the proliferation of normal skin cells with negligible toxicity. Additionally, HPEM scaffolds obviously accelerated the MRSA-infected wound healing (wound closure ratio was 96.31%) by efficient anti-inflammation effects, promoting cell proliferation, and the angiogenic process, stimulating granulation tissue formation, collagen deposition, vascular endothelial differentiation, and angiogenesis. This study indicates the important role of multifunctional 2D MXene@PDA nanosheets in infected wound healing. HPEM scaffolds with multifunctional properties provide a potential strategy for MRSA-infected wound healing/skin regeneration.

Hydrogen Bonding-Derived Healable Polyacrylate Elastomers via On-demand Copolymerization of n-Butyl Acrylate and tert-Butyl Acrylate.

Achieving a desirable combination of good mechanical properties and healing efficiency is a great challenge in the development of self-healing elastomers. Herein, a class of tough and strong self-healing polyacrylate elastomers (denoted as HPs) was developed simply by free-radical copolymerization of n-butyl acrylate (nBA) and tert-butyl acrylate (tBA) and a subsequent hydrolysis reaction rather than direct copolymerization of nBA and acrylic acid (AA). The tiny difference in reactivity between nBA and tBA makes the structural units of the copolymer easy to control. Precise regulation of molecular composition can be realized just by varying the relative monomer content, making its mechanical properties to vary from ductile to robust. Strikingly, when HP samples are cut off within the gauge length, they can heal into coherent and smooth samples and recover at least 79% of the original strength. Hydrogen bond interactions serve as physical cross-linking points, contributing to the high mechanical performance (fracture energy of up to 73.78 MJ·m-3 and tensile strength of up to 17.80 MPa) as well as shape memory function. Moreover, the HP samples emit strong fluorescence when exposed to a 365 nm UV lamp and exhibit an aggregation-enhanced emission effect in the state of dissolution.