Construction of magnetic MoS2/NiFe2O4/MIL-101(Fe) hybrid nanostructures for separation of dyes and antibiotics from aqueous media.

In this study, MoS2/NiFe2O4/MIL-101(Fe) nanocomposite was synthesized by hydrothermal method and used as an adsorbent for the elimination of organic dyes and some antibiotic drugs in aqueous solutions. The synthesized nanocomposite underwent characterization through different techniques, including scanning electron microscopy (FE-SEM), energy-dispersive X-ray spectroscopy (EDX), Brunauer-Emmett-Teller (BET) surface area analysis, Fourier transform infrared (FT-IR) spectroscopy, X-ray diffraction (XRD), zeta potential analysis, vibrating sample magnetometry (VSM), and UV-vis diffuse reflectance spectroscopy (UV-vis DRS). These results demonstrated the successful insertion of MoS2within the cavities of MIL-101(Fe). The as-prepared magnetic nanocomposite was used as a new magnetic adsorbent for removing methylene blue (MB) and rhodamine B (RhB) organic dyes and tetracycline (TC) and ciprofloxacin (CIP) antibiotic drugs. For achieving the optimized conditions, the effects of initial pH, initial dye and drug concentration, temperature, and adsorbent dose on MB, TC, and CIP elimination were investigated. The results revealed that at a temperature of 25 °C, the highest adsorption capacities of MoS2/NiFe2O4/MIL-101(Fe) for MB, TC, and CIP were determined to be 999.1, 2991.3, and 1994.2 mg g-1, respectively. The pseudo-second-order model and Freundlich model are considered suitable for explaining the adsorption behavior of the MoS2/NiFe2O4/MIL-101(Fe) nanocomposite. The magnetic nanocomposite was very stable and had good recycling capability without any change in its structure.

Application of perovskite oxides and their composites for degrading organic pollutants from wastewater using advanced oxidation processes: Review of the recent progress.

In the recent years, perovskite oxides are gaining an increasing amount of attention owing to their unique traits such as tunable electronic structures, flexible composition, and eco-friendly properties. In contrast, their catalytic performance is not satisfactory, which hinders real wastewater remediation. To overcome this shortcoming, various strategies are developed to design new perovskite oxide-based materials to enhance their catalytic activities in advanced oxidation process (AOPs). This review article is to provide overview of basic principle and different methods of AOPs, while the strategies to design novel perovskite oxide-based composites for enhancing the catalytic activities in AOPs have been highlighted. Moreover, the recent progress of their synthesis and applications in wastewater remediation (pertaining to the period 2016-2022) was described, and the related mechanisms were thoroughly discussed. This review article helps scientists to have a clear outlook on the selection and design of new effective perovskite oxide-based materials for the application of AOPs. At the end of the review, perspective on the challenges and future research directions are discussed.

Novel Gold Nanoparticles: Green Synthesis with Eryngium thyrsoideum Boiss Extract, Characterization, and In Vivo Investigations on Inflammatory Gene Expression and Biochemical Parameters in Type 2 Diabetic Rats.

In this work, we synthesized and reported gold nanoparticles (Au NPs) with Eryngium thyrsoideum Boiss plant extract for first time. The plant extract has important effect as reducing and stabilizing agent for preparation of Au nanoparticles. The synthesized gold nanoparticles were characterized with FT-IR, UV-vis, XRD, SEM, and TEM analyses. All analyses confirmed successful synthesis of gold nanoparticles with high purity. The antidiabetic activity of synthesized Au NPs was investigated on type 2 diabetic rats by studying their influences on serum biochemical parameters and inflammatory markers. Obtained results revealed that hepatic enzymes, TNF-α, and interleukin-6 of diabetic rats receiving gold nanoparticles decreased in compare with healthy control rats. As inflammatory markers are main reasons for hyperglycemic-induced insulin resistance in diabetes, Au NPs have a possible option for management of the diabetes-related complication via their potent anti-inflammatory and hypoglycemic effects.

Biosynthesis of Novel Silver Nanoparticles Using Eryngium thyrsoideum Boiss Extract and Comparison of their Antidiabetic Activity with Chemical Synthesized Silver Nanoparticles in Diabetic Rats.

In the present study, silver nanoparticles (1) were synthesized by green method using Eryngium campestre Boiss aqueous extract and silver nanoparticles (2) were synthesized with chemical method. The silver nanoparticles (1) and (2) were characterized with FT-IR, UV-Vis, XRD, EDX, SEM, and TEM analyses. The effects of silver nanoparticles (1) and (2) were investigated on glucose, hematology, and blood biochemical parameters in alloxan- induced diabetes type 1 model rats. Diabetic or intact rats received intraperitoneal injection of saline or 2.5 mg/kg of silver nanoparticles (1) and (2) for 14 consecutive days. Hematological parameters and serum concentration of FBS, HbA1C, ALT, AST, GGT, ALP, albumin, creatinine, and urea were determined. Interestingly, silver NPs (1) or (2) did not exert toxic influences on hematological parameters and liver and kidney function in intact rats. Both silver nanoparticles (1) and (2) exert hypoglycemic effects in diabetic rats. They did not alter urea, creatinine, and hematological parameters except white blood cell (WBC) count in diabetic rats. Silver nanoparticles (1) decreased significantly liver enzyme levels including ALT and AST of diabetic rats. However silver nanoparticles (2) could not suppress the increased levels of liver enzymes in diabetic rats. In comparison with silver nanoparticles (2), the silver nanoparticles (1) are more protective than the same dose of silver nanoparticles (2) in the regulation and improving the liver function in diabetic rats. Also, silver nanoparticles (1) may exert protective effects on liver damage of diabetic rats rather than kidney damage.

Synthesis and characterization of a series of novel perovskite-type LaMnO3/Keggin-type polyoxometalate hybrid nanomaterials for fast and selective removal of cationic dyes from aqueous solutions.

In this paper, Keggin-type heteropoly acids H3PMo12O40 (PMo12), H3PW12O40 (PW12) and H4SiW12O40 (SiW12) were successfully supported on silica-coated perovskite type LaMnO3 nanoparticles by a simple acid-base reaction. These novel hybrid nanomaterials (denoted as LaMnO3@SiO2/PMo12 (1), LaMnO3@SiO2/PW12 (2), and LaMnO3@SiO2/SiW12 (3)) were characterized by means of FT-IR, PXRD, inductively coupled plasma (ICP) spectrometry, SEM, EDX, TEM and BET surface area analysis. Furthermore, the adsorption abilities of 1-3 were tested towards cationic methylene blue (MB) and anionic methyl orange (MO) dyes. The results revealed that the MB dye can be removed almost completely (≥98%) by adsorbents 1-3 in 1, 30 and 0.5 minutes, respectively. For the most efficient adsorbent 3, the effects of the initial concentration and the initial pH values of MB solution on its adsorption ability were examined. Furthermore, the selective adsorption of the hybrid materials towards mixed MB & MO solution was investigated. The nanomaterials 1-3 could be easily separated from the aqueous solution and reused several times without any impact on their adsorption abilities and structures.