1.
Chem Commun (Camb)
; 58(34): 5285-5288, 2022 Apr 26.
Article
in English
| MEDLINE
| ID: mdl-35398878
ABSTRACT
Liquid crystal oligomers, namely dimers, trimers and tetramers, consisting of cyanobiphenyl and benzylideneaniline-based mesogenic units connected by either linear or bent alkoxy or alkyl spacers are reported. These materials, although built from achiral molecules, show the spontaneously chiral heliconical twist-bend nematic (NTB) phase. We report the relationships between the shape of the oligomer, and the NTB phase stability, the temperature dependence of the helical pitch length and tilt angle, birefringence, and elastic constants.