From grape bagasse to graphene-like porous carbon nanosheets for CO2 capture.

Graphene-based materials have increasingly attracted attention in recent years. It is a material is recognized worldwide due to its numerous applications in several sectors. However, graphene production involves several challenges: scalability, high costs, and high-quality production. This study synthesized graphene-like porous carbon nanosheets (GPCNs) through a thermochemical process under a nitrogen atmosphere using grape bagasse as a precursor. Three temperatures (700, 800, and 900 ºC) of the pyrolysis process were studied. Chemical graphitization and activation were used to form high-specific surface area materials: FeCl3.6H2O(aq) and ZnCl2(s) in a simultaneous activation-graphitization (SAG) method. The materials obtained (GPCN700, GPCN800, and GPCN900) were compared to previously produced chars (C700, C800, and C900). A high specific surface area and total pore volume were obtained for GPCN materials, and GPCN900 presented the highest values: 1062.7 m2g-1 and 0.635 cm3 g-1, respectively. The GPCN and char materials were classified as mesoporous and applied as adsorbents for CO2(g). The GPCN800 presented the best CO2(g) adsorbent, with a CO2(g) adsorption capacity of 168.71 mg g-1.

Citrus fruit residues as alternative precursors to developing H2O and CO2 activated carbons and its application for Cu(II) adsorption.

Due to its toxicity, the presence of Cu(II) ions released in aquatic environments presents a serious threat to the environment and human health. In search of sustainable and low-cost alternatives, there are citrus fruit residues, which are generated in large quantities by the juice industries and can be used to produce activated carbons. Therefore, the physical route was investigated for producing activated carbons to reuse citrus wastes. In this work, eight activated carbons were developed, varying the precursor (orange peel-OP, mandarine peel-MP, rangpur lime peel-RLP, and sweet lime peel-SLP) and the activating agent (CO2 and H2O) to remove Cu(II) ions of the aqueous medium. Results revealed promising activated carbons with a micro-mesoporous structure, a specific surface area of around 400 m2 g-1, and a pore volume of around 0.25 cm3 g-1. In addition, Cu (II) adsorption was favored at pH 5.5. The kinetic study showed that the equilibrium was reached within 60 min removing about 80% of Cu(II) ions. The Sips model was the most suitable for the equilibrium data, providing maximum adsorption capacities (qmS) values of 69.69, 70.27, 88.04, 67.83 mg g-1 for activated carbons (AC-CO2) from OP, MP, RLP, and SLP, respectively. The thermodynamic behavior showed that the adsorption process of Cu(II) ions was spontaneous, favorable, and endothermic. It was suggested that the mechanism was controlled by surface complexation and Cu2+-π interaction. Desorption was possible with an HCl solution (0.5 mol L-1). From the results obtained in this work, it is possible to infer that citrus residues could be successfully converted into efficient adsorbents to remove Cu(II) ions from aqueous solutions.

Pyrolysis of citrus wastes for the simultaneous production of adsorbents for Cu(II), H2, and d-limonene.

A route based on pyrolysis and physical activation with H2O and CO2 was proposed to reuse citrus waste traditionally discarded. The citrus wastes were orange peel (OP), mandarine peel (MP), rangpur lime peel (RLP), and sweet lime peel (SLP). The main aim was to use the solid products of this new route as adsorbents for Cu(II) ions. Copper ions are among the most important water pollutants due to their non-degradability, toxicity, and bioaccumulation, facilitating their inclusion and long persistence in the food chain. Besides the solid products, the liquid and gaseous fractions were evaluated for possible applications. Results showed that the citrus waste composition favored the thermochemical treatment. In addition, the following yields were obtained from the pyrolysis process: approximately 30 % wt. of biochar, 40 % wt. of non-condensable gases, and 30 % wt. of bio-oil. The biochars did not present a high specific surface area. Nevertheless, activated carbons with CO2 and H2O presented specific surface areas of 212.4 m2/g and 399.4 m2/g, respectively, and reached Cu(II) adsorption capacities of 28.2 mg g-1 and 27.8 mg g-1. The adsorption kinetic study revealed that the equilibrium was attained at 60 min and the pseudo-second-order model presented a better fit to the experimental data. The main generated gases were CO2, which could be employed as an activating agent for activated carbon production. d-limonene, used for food and medicinal purposes, was the main constituent of the bio-oil.

Development of activated carbon from Schizolobium parahyba (guapuruvu) residues employed for the removal of ketoprofen.

Schizolobium parahyba species can be found in all of South America, producing several residues that can be a major opportunity to develop activated carbon. This work presents the investigation regarding the development of a high specific surface activated carbon (981.55 m2 g-1) and its application in the adsorption of ketoprofen from the aqueous media. The ketoprofen molecules were better adhered to the adsorbent surface under acidic conditions (pH = 2), being the ideal adsorbent dosage determined as 0.7 g L-1, resulting in satisfactory values. It was found that the system reached equilibrium in 200 to 250 min depending on the initial concentration studied, achieving an adsorption capacity of 229 mg g-1. The general order was the most suitable model for describing the experimental data, with an R2 ≥ 0.9985 and MSR ≤ 63.40 (mg g-1)2. The equilibrium adsorption found that the temperature increases the adsorption capacity, achieving 447.35 mg g-1 at 328 K. Besides that, the Tóth model was the most suitable for describing the isotherms R2 ≥ 0.9990 and MSR ≤ 25.67 (mg g-1)2, indicating a heterogeneous adsorbent. The thermodynamic values found that the adsorption of ketoprofen is spontaneous (average ΔG0 of - 32.79 kJ mol-1) and endothermic (ΔH0 10.44 kJ mol-1). The treatment of simulated effluent with the developed adsorbent was efficient, removing 90% of ketoprofen, ibuprofen, and salts. It was found that the adsorbent is reaming its adsorption capacity up to the 5th cycle, progressively decreasing the adsorption capacity until the adsorption does not occur past the 12th cycle. Overall, the results demonstrated that the activated carbon from residual biomass of the Schizolobium parahyba species could be an excellent alternative in obtaining an effective adsorbent to treat wastewater-containing drugs.

Graywater treatment of emerging pollutant linear alkylbenzene sulfonate by adsorption with leather shave waste activated carbon.

The purpose of this research is to evaluate the use of leather shave waste activated carbon (ACLW) as an alternative for the treatment of wastewater containing linear alkylbenzene sulfonate (LAS). Batch adsorption tests were carried out (pH effect, isotherms, kinetics). The activated carbon was tested for its life cycle by desorption with solvent and it was further evaluated as real wastewater treatment for bath graywater. Under the optimum pH of 2.5, kinetic studies showed a better correlation with the pseudo-second order model, with an activation energy of 27.5 kJ mol-1. Equilibrium isotherms correlated better with the double layer model, indicating hemi-micelle formation and performing a high-affinity isotherm. Adsorption was shown to be endothermic (∆H0 = + 73.89 kJ mol-1), entropy driven (∆S0 = + 0.46 kJ mol-1 K-1), and occurring spontaneously. The use of ethanol solution was effective for the regeneration of the adsorbent. Adsorption was applied in real wastewater, removing contaminants from bath graywater, especially anionic surfactants with up to 95% removal efficiency.

Synergistic effect of the activated carbon addition from leather wastes in chitosan/alginate-based composites.

In this work, chitosan/alginate composites were developed by the gelation method with the addition of different amounts of activated carbon produced from tannery waste (ACTW). The performance of these composites was verified through the adsorption of the textile dye Remazol Brilliant Blue R (RBBR). A synergistic effect was observed by the addition of ACTW; with a specific surface area up to 45.584 m2/g, the maximum adsorption capacity was 300.96 mg/g. The synergy was due to the reduction in steric hindrance, with the adsorption capacity 1.2 times higher than expected. The material was regenerated with sodium hydroxide for 10 cycles. The composite containing 30% ACTW (AC30) was applied in the treatment of real textile effluent, with 30% reductions in the biochemical oxygen demand (BOD), 39% in the chemical oxygen demand (COD), 78% in turbidity, and 67% in color.

Ultrasonication-promoted synthesis of Ni/mayenite for catalytic reforming of biomass tar.

Ultrasound-assisted approach was successfully applied for the synthesis of mayenite from calcium and aluminum hydroxides and then subsequently impregnated with Ni by the wet impregnation method. The synthesis was performed with a 13 mm probe-type ultrasound, operating under an acoustic power of 30.5 W and a frequency of 20 kHz. Ultrasound application was studied in detail from a 3k experimental design, where the variables studied were ultrasound time (10-50 min) and calcination temperature (900-1200 °C). Ultrasound promoted an effective dispersion of the precursors in a short time of 10 min leading to a high conversion to mayenite after calcination at 1200 °C. Ultrasound treatment also had a positive effect on Ni impregnation, increasing the dispersion of the metal in the support and leading to a stronger interaction of nickel-containing species with mayenite support. The use of ultrasound application has proved to be attractive both for catalyst properties and for facilitating catalyst synthesis.

Adsorption of leather dyes on activated carbon from leather shaving wastes: kinetics, equilibrium and thermodynamics studies.

In this work, the adsorption of Acid Black 210 (AB210) and Acid Red 357 (AR357) onto activated carbon prepared from leather shaving wastes (ACLW) was investigated. The activated carbon presented a surface area of 800.4 m²/g with an average pore size of 1.27 nm. The kinetic study showed that the adsorption of both dyes followed the Elovich kinetic model while the AB210 and AR357 isotherm data were well described by the Langmuir and BET models, respectively. Furthermore, the Boyd plot revealed that the adsorption of the leather dyes on activated carbon was mainly governed by film diffusion. The pH had a strong influence on the adsorption, and the higher amounts of dye adsorbed were obtained at pH 2. The obtained activated carbon exhibited a high monolayer adsorption capacity of 573.9 and 204.4 mg/g for AB210 and AR357, respectively. Its high capacity is mainly attributed to its basicity (0.17 mmol/g) and high surface area. Desorption efficiency of the spent activated carbon was found to be 54.3% and 43.0% for AB210 and AR357, respectively. The spontaneity of the process was demonstrated by the negative values of the Gibbs free energy change.