ABSTRACT
Despite hybrid rocket motors offering distinct advantages over solid or liquid rocket motors, their low regression rate and insufficient combustion efficiency remain significantly unimproved. This study focuses on the effects of the helix lead on the regression rate distribution and combustion efficiency of vat-polymerized fuel grains with a spiral star port for a hybrid rocket. Both experimental and numerical investigations were conducted to study the combustion characteristics and regression rate distribution of three-dimensional (3D) print grains. Spiral star grains with varying helix leads of 60, 90, and 120 mm were fabricated using light-curing 3D printing technology. A 3D simulation model was developed to obtain the temperature distribution, species mass distribution, and combustion efficiency. Furthermore, firing tests were performed on a two-dimensional radial hybrid combustion test stand to measure the regression rate. Digital image processing of computed tomography images was used to determine the regression rate. Simulation results indicated that the spiral star grain port helps to improve the combustion efficiency compared with those seen with round tube and straight star port grains. With an increase in the axial distance, the flame zone gradually shrinks, and the smaller the helix lead, the faster the shrinkage. At a mass flow rate of 1.50 g/s for oxygen, the regression rate of the spiral star grains is significantly higher than that of the straight star grain and the conventional round tubular grains, and the regression rate gradually increases with a decrease in the helix lead. This finding is expected to solve the problem of the low regression rate of solid fuels with spiral star pore-shaped grains prepared by the light-curing 3D printing method.
ABSTRACT
The mechanical properties of HTPE/PEG interpenetrating polymer network (IPN) binders were systemically studied with molecular dynamics (MDs) simulations and experiments. In this study, an algorithm was used to construct the crosslinking interpenetrating polymer network models and then the mechanical behaviors of Hydroxyl-terminated polyethylene glycol-tetrahydrofuran co-polyether/poly ethylene glycol (HTPE/PEG) IPN models were analyzed at a molecular scale. Firstly, glass transition temperatures (Tg), mean square displacement (MSD) and mechanical properties of IPN crosslinked model simulations showed that better thermomechanical parameters appeared at low temperatures, which were in good agreement with the experimental methods, including dynamic mechanical analysis and uniaxial tensile. Then bond-length distribution was performed to verify the crosslinked structures between prepolymers and curing agents. FTIR-ATR spectra analysis of four IPN binder specimens also gave a convictive result to the special interpenetrating polymer network of polyether polyurethane binders. Cohesive energy density and friction-free volume explained how the micro-structures of IPN crosslinked models and the force of inter-molecule chains affected the mechanical behaviors of the HTPE/PEG polyurethane matrix. Lastly, the morphology of IPN binder specimen tensile fracture indicated the mechanism at different temperatures. These studies were helpful in understanding the mechanical properties of HTPE/PEG interpenetrating polymer network binders and provide molecular insight into mechanisms of mechanical behaviors, which would guide the property improvement of HTPE propellant.
ABSTRACT
The mechanical properties of HTPE binders have been systemically studied through combining the microstructure molecular simulations with macroscopic experiments. In this study, the crosslinking structures of HTPE binders were established by a computational procedure. Based on the optimized crosslinking models, the mechanical properties and the glass transition temperatures (Tg) of HTPE/N-100, HTPE/HDI, HTPE/TDI, and HTPE/IPDI binder systems were simulated; specifically, the Tg were 245.758 K, 244.573 K, 254.877 K, and 240.588 K, respectively. Then the bond-length distributions, conformation properties, cohesive energy densities, and fraction free volume were investigated to analyze how the microstructures of the crosslinking models influenced the mechanical properties of HTPE binders. Simultaneously, FTIR-ATR spectra analysis of HTPE binders proved that the special peaks, such as -NH and -NCO, could be seen in the crosslinking polyurethane structures synthesized between prepolymers and curing agents. The dynamic mechanical analysis was carried out, and it found that the Tg of HTPE/N-100, HTPE/HDI, HTPE/TDI, and HTPE/IPDI binder systems were -68.18 °C, -68.63 °C, -65.67 °C, and -68.66 °C, respectively. In addition, the uniaxial tension verified that both the ultimate stress and Young's modulus of HTPE binder systems declined with the rising temperatures, while the strains at break presented a fluctuant variation. When it was closer to glass temperatures, especially -40 °C, the mechanical properties of HTPE binders were more prominent. The morphology of the fractured surface revealed that the failure modes of HTPE binders were mainly intermolecular slipping and molecular chain breakage. In a word, the experimental results were prospectively satisfied using the simulations, which confirmed the accuracy of the crosslinking models between prepolymers and curing agents. This study could provide a scientific option for the HTPE binder systems and guide the design of polyurethanes for composite solid propellant applications.
ABSTRACT
Cocrystallization is a helpful method for explosives design. However, lack of understanding of the cocrystallization mechanism leads to inefficiency in cocrystal preparation. Therefore, studying the effects of solvent on cocrystal is of great importance for the efficient application of 2,4,6,8,10,12-hexanitrohexaazaisowurtzitane (CL-20). In this paper, the effect of solvent on cocrystallization is investigated by the CL-20/HMX cocrystal/solvent cluster model, the CL-20/HMX/solvent mixture model, the CL-20/HMX cocrystal/solvent interface model combined with quantum chemistry and molecular dynamic methods. The authors find that the hydrogen bond between CL-20 and 1,3,5,7-tetranitro-1,3,5,7-tetrazocane (HMX) is the strongest and the binding energy of cocrystal and solvent molecules is the weakest in ethyl acetate (EA) solvent, indicating that CL-20 and HMX tend to be combined together and there is less hindrance by solvent molecules. Analysis of the CL-20/HMX/solvent mixture and mass density distribution studies show that the solvent effect has a great influence on the crystal faces and the cocrystallization rate of CL-20 and HMX is the highest in EA solvent. The XRD and SEM characterization results are consistent with the theoretical calculations. The present work on the effects of solvent on CL-20/HMX cocrystals is beneficial for understanding the mechanism of the growth of energetic cocrystal materials. It is helpful in selecting more suitable theoretical and experimental conditions and makes access to excellent cocrystals more efficient.
ABSTRACT
In this study, the crosslinking structures of nitrate ester plasticized polyether (NEPE) binders were constructed by a computational procedure. Based on the final crosslinking models, the glass transition temperatures, mechanical properties, and thermal expansion coefficients of polyethylene glycol400/multi-functional isocyanate (PEG400/N-100), polyethylene glycol400/toluene diisocyanate (PEG400/HDI), polyethylene glycol400/hexamethylene diisocyanate (PEG400/TDI) and polyethylene glycol400/isophorone diisocyanate (PEG400/IPDI) models were simulated by molecular dynamics, and could be confirmed by experiments. Then the bond-length distributions, conformation properties and cohesive energy densities were used to analyze in detail how the different cured structures influenced the mechanical and thermal properties. Furthermore, the radial distribution function, mean square radius of gyration, volume shrinkage and fraction free volume were calculated, which could directly explain the relationships between the intermolecular chains and macroscopical properties of the NEPE binders. Lastly, PEG400/N-100 and PEG400/HDI systems were chosen for the experiments. The dynamic mechanical analysis results explained that PEG400-HDI showed better flexibility and its T g value was 45 °C lower than that of PEG400-N100. The mechanical properties illustrated that the ultimate tensile strength and Young's modulus of PEG400/N-100 were both to an extent higher than that of PEG400/HDI in the temperature range of -40 °C to 50 °C, according to the results provided by a universal tensile test machine. The experimental results were in good agreement with the simulation analysis. This work can help us to have an efficient comprehension on the crosslinking structures and micro-property relationships of the NEPE binders and act as a guidance for designing applicable polyurethanes in propellant applications.
ABSTRACT
Fluorinated graphene contains F atoms with high levels of chemical activity, and the application of fluorinated graphene in energetic materials may greatly contribute to the progress of combustion reactions. However, there is a lack of research on the thermal properties of fluorinated graphene and its application on nitrate esters. In this paper, theoretical calculations and experiments were used to study the thermal properties of fluorinated graphene and its application on nitrate esters. The anaerobicity and poor thermal stability of fluorinated graphene were proved by ab initio molecular dynamics (AIMD) calculations and TG-DSC experiments. The ester weakening effect of fluorinated graphene on nitroglycerin was determined via wavefunction analysis, with the greater the fluorination degree, the stronger the ester weakening effect. The existence of fluorinated graphene can significantly increase the heat dissipation of the composites, which was concluded by TG-DSC experiments and TG-DSC-MS-FTIR. The research in this article provides an important reference for the application of fluorinated graphene in energetic materials.