Methane sources from waste and natural gas sectors detected in Pune, India, by concentration and isotopic analysis.

Methane (CH4) is a potent greenhouse gas and also plays a significant role in tropospheric chemistry. High-frequency (sub-hourly) measurements of CH4 and carbon isotopic ratio (δ13CH4) have been conducted at Pune (18.53°N, 73.80°E), an urban environment in India, during 2018-2020. High CH4 concentrations were observed, with a mean of 2100 ± 196 ppb (1844-2749 ppb), relative to marine background concentrations. The δ13CH4 varied between -45.11 and -50.03 ‰ for the entire study period with an average of -47.41 ± 0.94 ‰. The diurnal variability of CH4 typically showed maximum values in the morning (08:00-09:00 local time) and minimum in the afternoon (15:00 local time). The deepest diurnal amplitude of ~500 ppb was observed during winter (December-February), which was reduced to less than half, ~200 ppb, during the summer (March-May). CH4 concentration at Pune showed a strong seasonality (470 ppb), much higher than that at Mauna Loa, Hawaii. On the other hand, δ13CH4 records did not show distinct seasonality at Pune. The δ13CH4 values revealed that the significant sources of CH4 in Pune were from the waste sector (enhanced during the monsoon season; signature of depleted δ13CH4), followed by the natural gas sector with a signature of enriched δ13CH4. Our analysis of Covid-19 lockdown (April to May 2020) effect on the CH4 variability showed no signal in the CH4 variability; however, the isotopic analysis indicated a transient shift in the CH4 source to the waste sector (early summer of 2020).

Interannual variability of the frequency of MJO phases and its association with two types of ENSO.

In this study, we reexamine the effect of two types of El Niño Southern Oscillation (ENSO) modes on Madden Julian Oscillation (MJO) activity in terms of the frequency of MJO phases. Evaluating all-season data, we identify two dominant zonal patterns of MJO frequency exhibiting prominent interannual variability. These patterns are structurally similar to the Wheeler and Hendon (Mon. Weather Rev. 132:1917-1932, 2004) RMM1 and RMM2 spatial patterns. The first pattern explains a higher frequency of MJO activity over the Maritime Continent and a lower frequency over the central Pacific Ocean and the western Indian Ocean, or vice versa. The second pattern is associated with a higher frequency of MJO active days over the eastern Indian Ocean and a lower frequency over the western Pacific, or vice versa. We find that these two types of MJO frequency patterns are related to the central Pacific and eastern Pacific ENSO modes. From the positive to the negative ENSO (central Pacific or eastern Pacific) phases, the respective MJO frequency patterns change their sign. The MJO frequency patterns are the lag response of the underlying ocean state. The coupling between ocean and atmosphere is exceedingly complex. The first MJO frequency pattern is most prominent during the negative central-Pacific (CP-type) ENSO phases (specifically during September-November and December-February seasons). The second MJO frequency pattern is most evident during the positive eastern-Pacific (EP-type) ENSO phases (specifically during March-May, June-August and September-November). Different zonal circulation patterns during CP-type and EP-type ENSO phases alter the mean moisture distribution throughout the tropics. The horizontal convergence of mean background moisture through intraseasonal winds are responsible for the MJO frequency anomalies during the two types of ENSO phases. The results here show how the MJO activity gets modulated on a regional scale in the presence of two types of ENSO events and can be useful in anticipating the seasonal MJO conditions from a predicted ENSO state.

Diurnal and seasonal variability of CO2 and CH4 concentration in a semi-urban environment of western India.

Amongst all the anthropogenically produced greenhouse gases (GHGs), carbon dioxide (CO2) and methane (CH4) are the most important, owing to their maximum contribution to the net radiative forcing of the Earth. India is undergoing rapid economic development, where fossil fuel emissions have increased drastically in the last three decades. Apart from the anthropogenic activities, the GHGs dynamics in India are governed by the biospheric process and monsoon circulation; however, these aspects are not well addressed yet. Towards this, we have measured CO2 and CH4 concentration at Sinhagad, located on the Western Ghats in peninsular India. The average concentrations of CO2 and CH4 observed during the study period are 406.05 ± 6.36 and 1.97 ± 0.07 ppm (µ ± 1σ), respectively. They also exhibit significant seasonal variabilities at this site. CH4 (CO2) attains its minimum concentration during monsoon (post-monsoon), whereas CO2 (CH4) reaches its maximum concentration during pre-monsoon (post-monsoon). CO2 poses significant diurnal variations in monsoon and post-monsoon. However, CH4 exhibits a dual-peak like pattern in pre-monsoon. The study suggests that the GHG dynamics in the western region of India are significantly influenced by monsoon circulation, especially during the summer season.

Exploring the long-term changes in the Madden Julian Oscillation using machine learning.

The Madden Julian Oscillation (MJO), the dominant subseasonal variability in the tropics, is widely represented using the Real-time Multivariate MJO (RMM) index. The index is limited to the satellite era (post-1974) as its calculation relies on satellite-based observations. Oliver and Thompson (J Clim 25:1996-2019, 2012) extended the RMM index for the twentieth century, employing a multilinear regression on the sea level pressure (SLP) from the NOAA twentieth century reanalysis. They obtained an 82.5% correspondence with the index in the satellite era. In this study, we show that the historical MJO index can be successfully reconstructed using machine learning techniques and improved upon. We obtain a significant improvement of up to 4%, using the support vector regressor (SVR) and convolutional neural network (CNN) methods on the same set of predictors used by Oliver and Thompson. Based on the improved RMM indices, we explore the long-term changes in the intensity, phase occurrences, and frequency of the winter MJO events during 1905-2015. We show an increasing trend in MJO intensity (22-27%) during this period. We also find a multidecadal change in MJO phase occurrence and periodicity corresponding to the Pacific Decadal Oscillation (PDO), while the role of anthropogenic warming cannot be ignored.