Bamboo for producing charcoal and biochar for versatile applications.

Bamboo, the fastest-growing plant, has several unique characteristics that make it appropriate for diverse applications. It is low-cost, high-tensile, lightweight, flexible, durable, and capable of proliferating even in ineffectual areas (e.g., incline). This review discusses the unique properties of bamboo for making charcoal and biochar for diverse applications. To produce bamboo charcoal and biochar, this study reports on the pyrolysis process for the thermal degradation of organic materials in an oxygen-depleted atmosphere under a specific temperature. This is an alternative method for turning waste biomass into products with additional value, such as biochar. Due to various advantages, bamboo charcoal is preferred over regular charcoal as it has four times the absorption rate and ten times more surface area reported. According to the reports, the charcoal yield ranges from 24.60 to 74.27%. Bamboo chopsticks were the most useful source for producing charcoal, with a high yield of 74.27% at 300 °C in nitrogen, but the thorny bamboo species have a tremendous amount of minimal charcoal, i.e., 24.60%. The reported biochar from bamboo yield ranges from 32 to 80%. The most extensive biochar production is produced by the bamboo D. giganteus, which yields 80% biochar at 300 °C. Dry bamboo stalks at 400 °C produced 32% biochar. One of the sections highlights biochar as a sustainable solution for plastic trash management produced during the COVID-19 pandemic. Another section is dedicated to the knowledge enhancement about the broad application spectrum of the charcoal and biochar. The last section highlights the conclusions, future perspectives, and recommendations on the charcoal and biochar derived from bamboo.

Preparation of nanolignin rich fraction from bamboo stem via green technology: assessment of its antioxidant, antibacterial and UV blocking properties.

This work reports the preparation of nano lignin-rich fraction material via green technology from the holistic use of lignocellulosic biomass bamboo. The bamboo is first chemically treated, followed by acid precipitation to extract bamboo-derived macro lignin-rich fraction material. The nano lignin-rich fraction material was then prepared via ultrasonication technique from the extracted bamboo-derived macro lignin-rich fraction material. The confirmation of the distinct lignin functional groups in the extracted lignin-rich fractions has been done by FTIR. Surface morphology by FESEM and TEM revealed spherical nano-lignin-rich fraction materials from extracted bamboo-derived macro lignin-rich fraction materials. DPPH assays indicated that both the obtained fractions depict beneficial antioxidant characteristics. They were found to be effective in terms of their antibacterial activity against both gram-positive bacteria Staphylococcus aureus (S.aureus) and gram-negative bacteria Escherichia coli (E.coli), using the disc diffusion method. These fractions have UV blocking property, and nano-lignin-rich fraction material acts as a more potential UV blocking agent than others. Thus, the nano-lignin-rich fraction material has great potential as a high antioxidant, antibacterial, and UV blocking agent useful in biomedical applications.Highlights Extraction of macro-lignin rich fraction material using chemical treatment of lignocellulosic biomass bamboo via refluxing followed by acid precipitation.Preparation of nano-lignin rich fraction material from extracted bamboo-derived macro-lignin rich fraction material via ultrasonication technique as a green technology.Structural and surface morphology of the extracted macro-lignin & nano lignin-rich fraction materials have been analyzed by XRD, FTIR, EDX, SEM and TEM.The macro lignin & nano lignin-rich fraction materials showed good antioxidant, antibacterial activity and UV-blocking properties, but the nano-lignin rich fraction material exhibited more efficient properties.

Advances in Nanoarchitectonics of Antimicrobial Tiles and a Quest for Anti-SARS-CoV-2 Tiles.

Design of antimicrobial tiles seems necessary to combat against contagious diseases, especially COVID-19. In addition to personal hygiene, this technology facilitates public hygiene as antimicrobial tiles can be installed at hospitals, schools, banks, offices, lobbies, railway stations, etc. This review is primarily focused on preparing antimicrobial tiles using an antimicrobial layer or coatings that fight against germs. The salient features and working mechanisms of antimicrobial tiles are highlighted. This challenge is a component of the exploratory nature of nanoarchitectonics, that also extends farther than the realm of nanotechnology. This nanoarchitectonics has been successful at the laboratory scale as antimicrobial metal nanoparticles are mainly used as additives in preparing tiles. A detailed description of various materials for developing unique antimicrobial tiles is reported here. Pure metal (Ag, Zn) nanoparticles and a mixture of nanoparticles with other inorganic materials (SiO2,, TiO2, anatase, nepheline) have been predominantly used to combat microbes. The developed antimicrobial tiles have shown excellent activity against a wide range of Gram-positive and Gram-negative bacteria. The last section discussed a hypothetical overview of utilizing the antimicrobial tiles against SARS-CoV-2. Overall, this review gives descriptive knowledge about the importance of antimicrobial tiles to create a clean and sustainable environment.

A review on efficient electromagnetic interference shielding materials by recycling waste-a trio of land to lab to land concept.

The materials used in electrical and electronic applications have great importance and broader applications, but they have severe electromagnetic interference (EMI). These materials have extensive applications in broadcasting, medical industries, research, defence sectors, communication and similar fields. The EMI can be addressed by using effective EMI shielding materials. This review presents a detailed, comprehensive description for making electromagnetic interference shielding material by recycling various wastes. It starts with highlighting the overview of electromagnetic interference shielding (EMI) and its theoretical aspects. It provides a comprehensive and detailed understanding of recent trends in the novel approaches towards fabricating EMI shielding from industrial waste, agricultural waste and other miscellaneous wastes. This paper critically reviews the works related to the recycling of wastes like red mud (waste from the aluminium refining industry), ground tyre rubber, tea waste (biowaste) from tea industries, bagasse (waste from sugar cane industry), peanut and hazelnut shells (agricultural waste), waste tissue paper and polyethylene and other miscellaneous wastes like hydrocarbon carbon black and ash for the fabrication of highly effective electromagnetic (EM) interference shielding materials. Highly effective results have been reported using red mud showing maximum efficiency of 51.4 dB in X-band range, various agricultural waste displaying reflection loss of up to - 87.117 dB (in the range 0.01 to 20 GHz) and miscellaneous waste giving EMI SE of 80 dB in X-band frequency. A separate section is dedicated to emphasizing future work and recommendations.

Designing of Poly(l-lactide)-Nicotine Conjugates: Mechanistic and Kinetic Studies and Thermal Release Behavior of Nicotine.

The current work focuses on the ring-opening polymerization (ROP) of l-lactide (LLA) using N-heterocyclic functionalized molecules as an initiator for the synthesis of metal-free poly(l-lactide) (PLLA) conjugates. With this motivation, we have used a drug molecule, nicotine, having N-heterocyclic functionality as the initiator for the synthesis of PLLA conjugates. Structural characterizations carried out using matrix-assisted laser desorption ionization time-of-flight mass spectrometry, Fourier transform infrared, and NMR establish the reacting species during polymerization in the absence of any side reactions. However, side reactions occurred because of the absence of steric hindrance when polymerization is initiated using nicotine in the presence of benzyl alcohol. Accordingly, we report here a detailed investigation on the mechanism of nicotine as an initiator and propose an anionic-based mechanism for the ROP of LLA. Studies on the kinetics parameters have been performed for the nicotine-initiated ROP of LLA and have found that polymerization proceeds with a first-order dependence on both the monomer and initiator concentrations with a low activation energy of 4.9 kcal·mol-1. Further, thermal release studies performed by hyphenated thermogravimetric-Fourier transform infrared analysis found that nicotine is released along with reduced toxins from these synthesized PLLA-nicotine conjugates. Thus, these PLLA-nicotine conjugates can in turn open up a new era in tobacco industries for the preparation of synthetic cigarettes and also in biomedical applications for drug delivery purposes. Herein, a few preliminary experiments using another drug molecule, nicorandil, having similar N-heterocyclic functionality were also conducted to support the role of nicotine as an initiator for the synthesis of PLLA conjugates.