ABSTRACT
The effect of gel preparation and heat treatment on the structural and optical properties of SiO2-ZnO materials prepared by the sol-gel method was investigated. Zinc acetate dehydrate, TEOS (tetraethylortosilicate), ethanol, distillated water and HCl were used as a starting material, solvent and catalyst, respectively. Four powders (G1-G4) were prepared in different ways from the starting materials mentioned above. The method of adding Zn precursors during the synthesis differed from one another. For the G1 synthesis, only Zn acetate powder was employed; for the G2 synthesis, Zn acetate was dissolved in distilled water; and for the G3 synthesis, Zn acetate was dissolved in ethanol. When synthesizing G4, TEOS was added last, after Zn acetate had been combined with water and ethanol. The SiO2-ZnO materials were dried at 200 °C and then heat-treated at 700 °C and 900 °C. All samples were investigated by X-ray diffraction and infrared spectroscopy in order to investigate their structure. SEM measurements were performed to investigate the morphology of materials. Optical properties were influenced by gel preparation and heat treatments. A reflectance of over 60% was obtained for G3 and G4 powders, while for G1 and G2, the reflectance was below 30%. In conclusion, synthesis steps and heat treatment can control the structure and properties of the powders.
ABSTRACT
One of the current research objectives is the development of new films for the conservation of glass heritage objects. The value of historical glass objects is given by the technology and raw materials used in production as well as their transparency and color. Their colors are correlated with oxide composition rich in transitional metals, which decrease resistance of corrosive agents from the atmosphere. In this paper, SiO2-ZnO gels have been designed to protect historical glass objects. The sol-gel method used to obtain gels is a powerful tool for functionalizing different materials. An important functionalization is the antibacterial activity. By applying a gel, the coated material is able to decrease the growth of bacteria. After deposition, some gels must be strengthened by heat treatment. The effect of ZnO content (10 mol% and 20 mol%) on the properties of the studied gels was investigated by Differential scanning calorimetry (DSC), Fourier transform infrared (FTIR), X-ray diffraction (XRD), Scanning electron microscopy (SEM), and antibacterial tests. Escherichia coli ATCC 25922, Staphylococcus aureus ATCC 25923, and the halotolerant bacterium, Virgibacillus halodenitrificans, isolated from a salt crystal from Unirea mine, Slanic Prahova, Romania, were used. The gel Gel 2 (SiO2-ZnO (20 mol%)) showed the best properties.
ABSTRACT
In recent years, the rising number of bone diseases which affect millions of people worldwide has led to an increased demand for materials with restoring and augmentation properties that can be used in therapies for bone pathologies. In this work, PMMA- MBG composite scaffolds containing ceria (0, 1, 3 mol%) were obtained by the phase separation method. The obtained composite scaffolds were characterized by X-ray diffraction, infrared spectroscopy, and scanning electron microscopy. UV-Vis measurement and EDX analysis confirmed the presence of cerium ions in the composite scaffolds. Evaluation of the in-vitro biocompatibility using MTT assay showed that composite scaffold containing 1 mol% of ceria presented higher viability than control cells (100%) for concentrations ranging between 5 and 50% after 96 h of incubation.
