Removal of hydrocarbons and heavy metals from petroleum water by modern green nanotechnology methods.

Considered heavy metals, such as As(III), Bi(II), Cd(II), Cr(VI), Mn(II), Mo(II), Ni(II), Pb(II), Sb(III), Se(-II), Zn(II), and contaminating chemical compounds (monocyclic aromatic hydrocarbons such as phenolic or polycyclic derivatives) in wastewater (petrochemical industries: oil and gas production plants) are currently a major concern in environmental toxicology due to their toxic effects on aquatic and terrestrial life. In order to maintain biodiversity, hydrosphere ecosystems, and people, it is crucial to remove these heavy metals and polluting chemical compounds from the watery environment. In this study, different Nanoparticles (α-Fe2O3, CuO, and ZnO) were synthesized by green synthesis method using Portulaca oleracea leaf extract and characterized by UV-Vis spectrophotometers, FTIR spectroscopy, X-Ray Diffraction (XRD), Scanning Electron Microscopy (SEM), Energy Dispersive Spectroscopy (EDS) techniques in order to investigate morphology, composition, and crystalline structure of NPs, these were then used as adsorbent for the removal of As(III), Bi(II), Cd(II), Cr(VI), Mn(II), Mo(II), Ni(II), Pb(II), Sb(III), Se(-II), and Zn(II) from wastewater, and removal efficiencies of were obtained 100% under optimal conditions.

A novel biosynthesis of MgO/PEG nanocomposite for organic pollutant removal from aqueous solutions under sunlight irradiation.

The novel synthesis of MgO from Laurus nobilis L. leaves was prepared using the green synthesis method. It is using direct blending process to decorate MgO/PEG nanocomposite to enhance the photodegradation properties and examine its physical properties using diverse characterization techniques, including XRD, FTIR, SEM, EDX, and UV-Vis. X-ray diffraction reveals a cubic phase of MgO with a 37-nm grain size. SEM images confirm spherical nanoparticles with a diameter size of 22.9 nm. The optical energy gap of MgO NPs was 4.4 eV, and the MgO/PEG nanocomposite was 4.1 eV, which made it an efficient catalyst under sunlight. The photocatalytic activity of Rose Bengal (RB) and Toluidine Blue (TB) dyes at 5 × 10-5 mol/l dye concentration indicates excellent degradation efficiencies of 98% and 95% in 120 min, respectively, under sunlight irradiation. MgO/PEG is an excellent candidate nanocomposite for applications of photodegradation and could be used for its potential capability to develop conventionally used techniques.