ABSTRACT
Harnessing visible-light in organic synthesis is one of the most effective methods that aligns with green and sustainable chemistry principles and hence skyrocketed in the last two decades. Similarly, three-component 1,2-dicarbofunctionalization of alkenes and alkynes has recently been a great choice to construct complex molecular systems in an easy and rapid manner. Therefore, light-induced reactions can be an excellent alternative to carry out 1,2-dicarbofunctionalization reactions, and very recently, organic chemists across the globe have fascinated us with their interesting articles. In this present review, we have summarized the recent advancements in the area of visible light induced three-component 1,2-dicarbofunctionalization of alkenes and alkynes till March 2023. We have categorized the discussion based on the catalysts used to carry out the transformations for better understanding and different important aspects of these transformations have also been covered.
ABSTRACT
Air pollution by various volatile organic compounds (VOC) is a matter of concern for us. So in this regard, designing real-time VOC responsive materials is gaining attention across the scientific community. In this present work, we have developed an inexpensive VOC sensor based on a Meisenheimer complex derived from picric acid and N,N'-dicyclohexylcarbodiimide. The sensor coated TLC plate was used as a sensor of potentially harmful VOCs. The sensor coated TLC plate looks deep red colored and does not show any fluorescence emission under 366 nm UV light. But in the presence of harmful volatile organic compounds like benzene, toluene, xylene, etc the sensor coated TLC plate becomes orange colored and it also shows strong yellow emission under 366 nm UV light. This property was utilized to detect the VOCs by fluorescence spectroscopy. The detection limit for various VOCs was found to be in the range of 0.7-9 ppm. To make the sensor user friendly, we have demonstrated a method where VOCs can be detected using a smartphone in real-time and also the setup is portable.