ABSTRACT
The waste generated by the global fishing industry, such as fish scales, is mostly considered useless and discarded in a disorderly and/or unplanned way in inappropriate places, posing serious risks to both the environment and human health. This study proposes the use of fish scales in combustion processes as an alternative for such residues and to avoid their exposure in urban areas. Combustion experiments were conducted in a drop tube furnace (DTF), and the factors temperature, residence time, and sample particle size were investigated. The main atmospheric pollutants (CO, NO, CO2, and SO2) and the residues generated from the combustion processes were characterized by FTIR, EDS and ICP-OES analyses, and SEM images. The samples showed better performance at 1100 °C and 500 -ms residence time, when the burnout reached 96%, and particle size greater than 300-µm and 300-ms residence time led to the worst combustion performance (24.45% burnout), with the highest CO and NO peaks, indicating incomplete combustion of the fish scales. The analysis of the residues revealed total decomposition of the organic matter at temperatures above 700 °C and formation of hydroxyapatite. According to the DTF results, the use of fish scales in firing processes is a viable treatment of the residues, generating energy and avoiding environmental problems caused by inadequate disposal.
