Utilization of Mechanically Recycled Carbon Fibers in Vinyl Ester Composites.

As we enter the twenty-first century, the aviation sector is expected to thrive as flying becomes the primary mode of transportation between states or nations. With such a demand, there is a corresponding need to manufacture aircraft components. The study focused on recycling carbon fiber composites received from the STRATA company, which were cut-off/waste material generated during the manufacture of airplane components. The cut-offs were then reduced to powder form using a standard face milling machine in three sizes (90, 150, and 250 µm). After, the powder was utilized to fabricate vinyl ester composites with four weight percentages (10%, 20%, 30%, and 40%). The results demonstrate that the tensile strength of all composites had risen by 30.2%, 21.3%, and 17.6% for 90, 150, and 250 µm respective with the addition of 20 wt% of reinforcement. Furthermore, subsequently decreased with the additional reinforcement for all particle sizes. The compressive strength increased by 30% from 187.5 MPa to 244 MPa with 10 wt% of recycled carbon powder composite of 90µm particle size. However, samples prepared with 150 µm and 250 µm fiber size show approximately 17% and 1% increase in the compression strength with the addition of 10wt% of recycled carbon powder. A similar trend was observed for the flexural strength with an highest increase of 9% for 90 µm particle size with addition of 20 wt% reinforcement. Nonetheless, the SEM images revealed that the fiber-matrix bonding was weak, proved through the clean pullout fibers at the fracture surfaces.

Microplastic Contamination of Chicken Meat and Fish through Plastic Cutting Boards.

Microplastic contamination was found in fish and chicken bought on the market, in food stores and in chain supermarkets in the Middle East with the contamination ranging from 0.03 ± 0.04 to 1.19 ± 0.72 particles per gram of meat in chicken and from 0.014 ± 0.024 to 2.6 ± 2.8 particles per gram in fish. Only one fish was found to be free of microplastic. The source of the microplastic was established to be the polythene-based plastic cutting board the food was cut on. More microplastic contamination was found in food cut from the bone than in cut fillets when the fillets themselves were prepared on surfaces other than plastic. Washing the fish and chicken before food preparation decreased but did not completely remove the microplastic contamination. The fate of the microplastic in grilled fish was studied. The mechanical properties of typical plastic cutting boards commercially used in the markets were investigated in the form of tensile, hardness, and wear tests. Overall, the plastic cutting boards showed similar wear rates.

Influence of Laser Process Parameters, Liquid Medium, and External Field on the Synthesis of Colloidal Metal Nanoparticles Using Pulsed Laser Ablation in Liquid: A Review.

Pulsed laser ablation in liquid, used for nanoparticle synthesis from solid bulk metal targets (a top-down approach), has been a hot topic of research in the past few decades. It is a highly efficient and 'green' fabrication method for producing pure, stable, non-toxic (ligand-free), colloidal nanoparticles, which is often challenging using traditional chemical methods. Due to the short time scale interaction between the laser pulses and the target, it is difficult to achieve complete control on the physical characteristics of metallic nanoparticles. Laser process parameters, liquid environment, and external fields vastly effect the shape and structure of nanoparticles for targeted applications. Past reviews on pulsed laser ablation have focused extensively on synthesising different materials using this technique but little attention has been given to explaining the dependency aspect of the process parameters in fine-tuning the nanoparticle characteristics. In this study, we reviewed the state of the art literature available on this technique, which can help the scientific community develop a comprehensive understanding with special insights into the laser ablation mechanism. We further examined the importance of these process parameters in improving the ablation rate and productivity and analysed the morphology, size distribution, and structure of the obtained nanoparticles. Finally, the challenges faced in nanoparticle research and prospects are presented.

Plastic cutting boards as a source of microplastics in meat.

Plastic cutting boards were found to be the source of polythene microplastic contamination in cut meat commercially available at butchers and a supermarket chain in the Middle East, making them also a direct source of microplastic in wastewater. The mean size of the microplastic in the raw meat was 1279.2 ± 835.0 µm, but decreased when the meat was cooked or fried. The microplastic melted during both cooking and frying processes and recrystallised partially upon cooling. Washing the meat for a short time (10 seconds) before preparing it reduced the microplastic contamination insignificantly, and only extensive washing of the meat over longer periods of time (3 min) helped decrease the microplastic count to 0.07 MP/g meat. The composition of the cutting boards was analysed by FT-IR spectroscopy, differential scanning calorimetry and subjected to wear, tensile and hardness tests. From a 3D photo of a spent cutting board, it was calculatedthat 875 g polythene was lost from the cutting board at the end of its lifetime.

A Comprehensive Review on Optimal Welding Conditions for Friction Stir Welding of Thermoplastic Polymers and Their Composites.

Friction stir welding (FSW) and friction stir spot welding (FSSW) techniques are becoming widely popular joining techniques because of their increasing potential applications in automotive, aerospace, and other structural industries. These techniques have not only successfully joined similar and dissimilar metal and polymer parts but have also successfully developed polymer-metallic hybrid joints. This study classifies the literature available on the FSW and FSSW of thermoplastic polymers and polymer composites on the basis of joining materials (similar or dissimilar), joint configurations, tooling conditions, medium conditions, and study types. It provides a state-of-the-art and detailed review of the experimental studies available on the FSW and FSSW between similar thermoplastics. The mechanical properties of FSW (butt- and lap-joint configurations) and FSSW weld joints depend on various factors. These factors include the welding process parameters (tool rotational speed, tool traverse speed, tool tilt angle, etc.), base material, tool geometry (pin and shoulder size, pin profile, etc.) and tool material, and medium conditions (submerged, non-submerged, heat-assisted tooling, cooling-assisted tooling). Because of the dependence on many factors, it is difficult to optimize the welding conditions to obtain a high-quality weld joint with superior mechanical properties. The general guidelines are established by reviewing the available literature. These guidelines, if followed, will help to achieve high-quality weld joints with least defects and superior mechanical properties. Apart from parametric-based studies, the statistical-based studies (e.g., analysis of variance (ANOVA)-based studies) are covered, which helps with the determination of the influential parameters that affect the FSW and FSSW weld joint strength. Also, the optimal ranges of the most influential process parameters for different thermoplastic materials are established. The current work on the development of general guidelines and determination of influential parameters and their operating ranges from published literature can help with designing smart future experimental studies for obtaining the global optimum welding conditions. The gaps in the available literature and recommendations for future studies are also discussed.

Analysis of microbeads in cosmetic products in the United Arab Emirates.

The microparticle content of 37 common facial and body scrubs commercially available in the United Arab Emirates was analyzed. The chemical composition, ash content, physical characteristics, loading, particle size and shape of the microparticles were determined. Only 11 out of 37 products were found to have microplastic content. Many of the remaining products exhibited microparticles composed of microcrystalline cellulose and crushed walnut shells. Differential scanning calorimetry showed that microplastic products had softening points as low as 84 °C. Plastic microbeads of 2 products were found to fuse at 100 °C. The fusion altered the flotation characteristics of the microbeads of one product. Heat treatment of the product at 100 °C in the presence of silica gel led to entrainment of the silica and partial fragmentation of the beads upon cooling. This may be understood as one mechanism of fragmentation of a microplastic with a low softening point in the presence of hard soil particles under temperature cycling.

Bilirubin detoxification using different phytomaterials: characterization and in vitro studies.

BACKGROUND: Activated carbon (AC) is a common adsorbent that is used in both artificial and bioartificial liver devices. METHODS: Three natural materials - date pits of Phoenix dactylifera (fruit), Simmondsia chinensis (jojoba) seeds, and Scenedesmus spp. (microalgae) - were used in the present investigation as precursors for the synthesis of AC using physical activation. The chemical structures and morphology of AC were analyzed. Then, AC's bilirubin adsorption capacity and its cytotoxicity on normal liver (THLE2) and liver cancer (HepG2) cells were characterized. RESULTS: Compared with the other raw materials examined, date-pit AC was highly selective and showed the most effective capacity of bilirubin adsorption, as judged by isotherm-modeling analysis. MTT in vitro analysis indicated that date-pit AC had the least effect on the viability of both THLE2 and HepG2 cells compared to jojoba seeds and microalgae. All three biomaterials under investigation were used, along with collagen and Matrigel, to grow cells in 3D culture. Fluorescent microscopy confirmed date-pit AC as the best to preserve liver cell integrity. CONCLUSION: The findings of this study introduce date-pit-based AC as a novel alternative biomaterial for the removal of protein-bound toxins in bioartificial liver devices.