ABSTRACT
Polyethylene (PE), a highly prevalent non-biodegradable polymer in the field of plastics, presents a waste management issue. To alleviate this issue, bio-based PE (bio-PE), derived from renewable resources like corn and sugarcane, offers an environmentally friendly alternative. This review discusses various production methods of bio-PE, including fermentation, gasification, and catalytic conversion of biomass. Interestingly, the bio-PE production volumes and market are expanding due to the growing environmental concerns and regulatory pressures. Additionally, the production of PE and bio-PE biocomposites using agricultural waste as filler materials, highlights the growing demand for sustainable alternatives to conventional plastics. According to previous studies, addition of ≈50% defibrillated corn and abaca fibers into bio-PE matrix and a compatibilizer, results in the highest Young's modulus of 4.61 and 5.81 GPa, respectively. These biocomposites have potential applications in automotive, building construction, and furniture industries. Moreover, the advancement made in abiotic and biotic degradation of PE and PE biocomposites is elucidated to address their environmental impacts. Finally, the paper concludes with insights into the opportunities, challenges, and future perspectives in the sustainable production and utilization of PE and bio-PE biocomposites. In summary, production of PE and bio-PE biocomposites can contribute to a cleaner and sustainable future.
ABSTRACT
Polypropylene (PP) is among the most widely used commodity plastics in our everyday life due to its low cost, lightweight, easy processability, and exceptional chemical, thermo-mechanical characteristics. The growing awareness on energy and environmental crisis has driven global efforts for creating a circular economy via developing sustainable and eco-friendly alternatives to traditional plastics produced from fossil fuels for a variety of end-use applications. This review paper presents a brief outline of the emerging bio-based PP derived from renewable natural resources, covering its production routes, market analysis and potential utilizations. This contribution also provides a comprehensive review of the PP-based biocomposites produced with diverse green fillers generated from agro-industrial wastes, with particular emphasis on the structural modification, processing techniques, mechanical properties, and practical applications. Furthermore, given that the majority of PP products are currently destined for landfills, research progress on enhancing the degradation of PP and its biocomposites is also presented in light of the environmental concerns. Finally, a brief conclusion with discussions on challenges and future perspectives are provided.
