1.
Org Lett
; 14(16): 4186-9, 2012 Aug 17.
Article
in English
| MEDLINE
| ID: mdl-22873133
ABSTRACT
In 1-deoxy-xylofuranose derivatives possessing a good leaving group at 2-C, participation of allyloxy and propargyloxy substituents at 5-C results in loss of the 2-C substituent and attack of various nucleophiles at 5-C of the oxonium intermediate. Such participation of a benzyloxy or crotyloxy group leads to dioxabicyclo[2.2.1]heptane rings.