Progress and Perspective in harnessing MXene-carbon-based composites (0-3D): Synthesis, performance, and applications.

MXene is recognized as a promising catalyst for versatile applications due to its abundant metal sites, physicochemical properties, and structural formation. This comprehensive review offers an in-depth analysis of the incorporation of carbon into MXene, resulting in the formation of MXene-carbon-based composites (MCCs). Pristine MXene exhibits numerous outstanding characteristics, such as its atomically thin 2D structure, hydrophilic surface nature, metallic electrical conductivity, and substantial specific surface area. The introduction of carbon guides the assembly of MCCs through electrostatic self-assembly, pairing positively charged carbon with negatively charged MXene. These interactions result in increased interlayer spacing, reduced ion/electron transport distances, and enhanced surface hydrophilicity. Subsequent sections delve into the synthesis methods for MCCs, focusing on MXene integrated with various carbon structures, including 0D, 1D, 2D, and 3D carbon. Comprehensive discussions explore the distinctive properties of MCCs and the unique advantages they offer in each application domain, emphasizing the contributions and advancements they bring to specific fields. Furthermore, this comprehensive review addresses the challenges encountered by MCCs across different applications. Through these analyses, the review promotes a deeper understanding of exceptional characteristics and potential applications of MCCs. Insights derived from this review can serve as guidance for future research and development efforts, promoting the widespread utilization of MCCs across a broad spectrum of disciplines and spurring future innovations.

Binary metal oxide (NiO/SnO2) composite with electrochemical bifunction: Detection of neuro transmitting drug and catalysis for hydrogen evolution reaction.

The synergetic effect between dual oxides in binary metal oxides (BMO) makes them promising electrode materials for the detection of toxic chemicals, and biological compounds. In addition, the interaction between the cations and anions of diverse metals in BMO tends to create more oxygen vacancies which are beneficial for energy storage devices. However, specifically targeted synthesis of BMO is still arduous. In this work, we prepared a nickel oxide/tin oxide composite (NiO/SnO2) through a simple solvothermal technique. The crystallinity, specific surface area, and morphology were fully characterized. The synthesized BMO is used as a bifunctional electrocatalyst for the electrochemical detection of dopamine (DPA) and for the hydrogen evolution reaction (HER). As expected, the active metals in the NiO/SnO2 composite afforded a higher redox current at a reduced redox potential with a nanomolar level detection limit (4 nm) and excellent selectivity. Moreover, a better recovery rate is achieved in the real-time detection of DPA in human urine and DPA injection solution. Compared to other metal oxides, NiO/SnO2 composite afforded lower overpotential (157 mV @10 mA cm-2), Tafel slope (155 mV dec-1), and long-term durability, with a minimum retention rate. These studies conclude that NiO/SnO2 composite can act as a suitable electrode modifier for electrochemical sensing and the HER.

Sense and Shoot: Unveiling the Electro-/Photocatalytic Potential of 2D White Graphene-Supported Perovskite Strontium Cobaltite from Detection to Remediation of Oxidative Stress Herbicide (Mesotrione).

In this research, we employed a strategy akin to "Feeding Two Birds with One Stone" aiming for the dual objectives of highly selective electrochemical detection and photocatalytic degradation of the environmentally hazardous herbicide mesotrione (MTN). We achieved this by utilizing hexagonal boron nitride (BN)-supported strontium cobaltite perovskite nanocomposites (SrCoO3/BN). The fabrication of the innovative bifunctional SrCoO3/BN nanocomposites involved a straightforward process of precipitation, followed by an annealing treatment and ultrasonication. The successful formation of these nanocomposites was corroborated through the application of diverse spectroscopic tools. Notably, as-prepared SrCoO3/BN nanocomposites exhibited a remarkable sensing platform for MTN, characterized by a notably low detection limit (11 nm), considerable sensitivity (3.782 µA µM-1 cm-2), and outstanding selectivity, alongside remarkable stability. Concurrently, these SrCoO3/BN nanocomposites demonstrated exceptional visible-light-driven photocatalytic efficacy for MTN degradation (99%) and complete mineralization. Our investigation systematically delved into the influence of operational parameters, including catalyst loading and the involvement of reactive oxidative species, in both the electrocatalytic and photocatalytic reactions. Drawing from these comprehensive studies, we have proposed plausible mechanisms for detecting and degrading MTN. Our findings pave the way for catalyst development, offering a unified solution for detecting and eliminating toxic organic compounds from the environment.

Electrocatalytic detection of noxious antioxidant diphenylamine in fruit samples with support of Cu@nanoporous carbon modified sensor.

Herein, the facile synthesis of copper(II) and benzene-1,3,5-tricarboxylate (Cu-BTC) and copper nanoporous carbon (Cu@NPC) for the electrochemical detection of diphenylamine (DPA) was systematically investigated. The Cu-BTC and Cu@NPC materials structural, morphological, and thermal stability were evaluated and confirmed using FE-SEM, HR-TEM, XRD, FT-IR, and TGA. The electrocatalytic behavior of sensor materials was examined by cyclic voltammetry (CV) and differential pulse voltammetry (DPV). It is presumed that the structural stability and synergic effect exhibited in Cu@NPC are favorable for enhanced sensitivity and selectivity towards the detection of DPA. The Cu@NPC exhibited a wide linear range (0.09-396.82 µM) and the lowest limit of detection (5 nM). Furthermore, the real sample analysis of the sensor for the detection of DPA in apples and pears confirms its potential capability in practical application.

Bismuth molybdate incorporated functionalized carbon nanofiber as an electrocatalytic tool for the pinpoint detection of organic pollutant in life samples.

Herein, we fabricated a feasible and accurate sensing platform for the quantification of toxic organic pollutant 2-nitroaniline (2-NA) in water samples through electrocatalyst made up of bismuth molybdate (Bi2MoO6, BMO) functionalized carbon nanofiber (f-CNF) modified electrode. The preparation of BMO/f-CNF composite is of two methods, such as co-precipitation (C-BMO/f-CNF) and ultrasonication method (U-BMO/f-CNF). The physicochemical properties of the composites were characterized by XRD, FTIR, Raman, BET, FE-SEM, and HR-TEM techniques. At U-BMO/f-CNF, the charge transfer resistance was low (Rct = 12.47 Ω) compared to C-BMO/f-CNF because nanosized U-BMO particles correctly aim at the defective sites of the f-CNF surface wall. Further, the electrocatalytic activity of C&U-BMO/f-CNF composites was examined by cyclic voltammetry (CV) and differential pulse voltammetry techniques (DPV) for the electrochemical detection of 2-nitroaniline (2-NA). The U-BMO/f-CNF/GCE shows a higher cathodic current, wide dynamic linear range of 0.01-168.01 µM, and superior electrocatalytic activity with a low detection limit (0.0437 µM) and good sensitivity (0.6857 µA µM-1 cm-2). The excellent selectivity nature of U-BMO/f-CNF/GCE was observed in the presence of various organic pollutants and a few toxic metal cations. The practical applicability such as stability, repeatability towards 2-NA outcomes with accepted results. Besides, the practical viability of as proposed U-BMO/f-CNF sensor was investigated in soil and lake water samples delivers good recovery results. Hence from these analyses, we conclude that U-BMO/f-CNF/GCE potential for the determination of hazardous environmental pollutant 2-NA.

Low potential detection of antiprotozoal drug metronidazole with aid of novel dysprosium vanadate incorporated oxidized carbon nanofiber modified disposable screen-printed electrode.

In this work, we designed tetragonal nanogravel structured dysprosium vanadate Dy(VO4) nanoparticles unified with oxidized carbon nanofiber (f-CNF) denoted as Dy(VO4)/f-CNF nanocomposite for the low potential determination of antiprotozoal drug metronidazole (MEZ). The physicochemical properties of novel Dy(VO4)/f-CNF nanocomposite were analyzed through microscopic and spectroscopic techniques and obtained results express nanocomposite formed with desired surface morphology, crystalline phase, atomic vibrational modes, and preferred elemental compositions. The electrocatalytic activity of Dy(VO4)/f-CNF nanocomposite was examined with a disposable screen-printed electrode (SPCE) via cyclic voltammetry (CV) and linear sweep voltammetry technique (LSV) with a conventional three-electrode system. Dy(VO4)/f-CNF/SPCE delivers a higher active surface area recommends superior electrocatalytic activity which is favorable for the MEZ sensor. Electrocatalytic reduction of MEZ occurred with lower reduction potential (-0.55 V) with dynamic linear range (1.5-1036.9 µM), lower detection limit (6 nm), LOQ (0.022 µM), and higher sensitivity (1.12 µA µM-1 cm2). The anti-interference studies retain its actual current without any shift in cathodic potential. Besides, the practical feasibility outcomes with higher cathodic current with the higher recovery rate and RSD in human blood sample, urine sample, and lake water as a real samples. Thus, Dy(VO4)/f-CNF nanocomposite modified SPCE considers being a potential candidate for the MEZ sensor.

Nanomolar level detection of non-steroidal antiandrogen drug flutamide based on ZnMn2O4 nanoparticles decorated porous reduced graphene oxide nanocomposite electrode.

Flutamide is a non-steroidal antiandrogen drug and widely used in the treatment of prostatic carcinoma. Nevertheless, the excessive intake and improper disposal could affect the living organisms. In this work, we have synthesized a new nanocomposite based on ZnMn2O4 nanoparticles and porous reduced graphene oxide nanosheets (ZnMn2O4-PGO) for the electrocatalytic detection of flutamide (FLU) drug. The crystallinity and morphological properties of ZnMn2O4-PGO composite examined by different characterization techniques such as X-ray diffraction, Raman spectroscopy and so on. The fabricated ZnMn2O4-PGO nanocomposite modified electrode exhibited superior electrocatalytic performance to FLU drug in an optimized pH electrolyte. Fascinatingly, the electrode received a wide linear range (0.05-3.5 µM) with limit of detection of 8 nM. Besides, the developed ZnMn2O4-PGO nanocomposite electrode showed good sensitivity 1.05 µAµM-1 cm-2 and excellent selectivity for FLU detection in presence of various interfering species. A developed disposable electrode was scrutinized to determine FLU level in human urine samples by spiking method and the results achieved good recoveries in real sample analysis.

Ultrasonication-aided synthesis of nanoplates-like iron molybdate: Fabricated over glassy carbon electrode as an modified electrode for the selective determination of first generation antihistamine drug promethazine hydrochloride.

The innovation of novel and proficient nanostructured materials for the precise level determination of pharmaceuticals in biological fluids is quite crucial to the researchers. With this in mind, we synthesized iron molybdate nanoplates (Fe2(MoO4)3; FeMo NPs) via simple ultrasonic-assisted technique (70 kHz with a power of 100 W). The FeMo NPs were used as the efficient electrocatalyst for electrochemical oxidation of first-generation antihistamine drug- Promethazine hydrochloride (PMH). The as-synthesized FeMo NPs were characterized and confirmed by various characterization techniques such as XRD, Raman, FT-IR, FE-SEM, EDX and Elemental mapping analysis and electron impedance spectroscopy (EIS). In addition, the electrochemical characteristic features of FeMo NPs were scrutinized by electrochemical techniques like cyclic voltammetry (CV) and differential pulse voltammetry technique (DPV). Interestingly, the developed FeMo NPs modified glassy carbon electrode (FeMo NPs/GCE) discloses higher peak current with lesser anodic potential on comparing to bare GCE including wider linear range (0.01-68.65 µM), lower detection limit (0.01 µM) and greater sensitivity (0.97 µAµM-1cm-2). Moreover, the as-synthesized FeMo NPs applied for selectivity, reproducibility, repeatability and storage ability to investigate the practical viability. In the presence of interfering species like cationic, anionic and biological samples, the oxidation peak current response doesn't cause any variation results disclose good selectivity towards the detection of PMH. Additionally, the practical feasibility of the FeMo NPs/GCE was tested by real samples like, commercial tablet (Phenergan 25 mg Tablets) and lake water samples which give satisfactory recovery results. All the above consequences made clear that the proposed sensor FeMo NPs/GCE exhibits excellent electrochemical behavior for electrochemical determination towards oxidation of antihistamine drug PMH.