ABSTRACT
In the title compound, C(13)H(16)N(2)O(2), the planes of the benzimidazole ring system and the acetate O-C=O fragment make a dihedral angle of 84.5â (3)°. In the crystal, mol-ecules are connected through C-Hâ¯N hydrogen bonds to form infinite chains in the [-110] direction.
ABSTRACT
The title butterfly-shaped mol-ecule, C(11)H(6)N(2)O(2), is folded slightly along the O=Câ¯C=O line, the dihedral angle between the two parts being 6.42â (3)°. In the crystal, adjacent mol-ecules are linked through C-Hâ¯O hydrogen bonds into infinite layers parallel to the ac plane. The layers are further connected into a three-dimensional netweork via π-π inter-actions formed between pairs of anti-parallel arranged mol-ecules, with a centroid-centroid distance between the central six-membered ring and the benzene ring of 3.4349â (9)â Å.
ABSTRACT
In the title compound, C(13)H(23)N(2)O(2) (+)·Br(-), the octyl chain has an all-trans conformation. In the crystal, the cations are linked by C-Hâ¯O bonds into a zigzag chain along the b axis. The bromide anions further link the chains via C-Hâ¯Br inter-actions into a two-dimensional array parallel to the ab plane. An O-Hâ¯Br interaction is also observed.
ABSTRACT
In the title compound, C(29)H(24)N(4)O(4)S(3), the two N-tosyl-benzimidazolyl unit are connected through a -S-CH(2)- fragment, the dihedral angle between the benzimidazole rings being 76.09â (5)°. The methyl-thio group is disordered with respect to exchange of the S and C atoms in a 0.547â (4):0.453â (4) ratio. In the crystal, C-Hâ¯O and C-Hâ¯π inter-actions connect adjacent mol-ecules into infinite layers parallel to the ab plane. The crystal packing is further stabilized by a π-π inter-action [centroid-centroid separation = 3.5187â (4)â Å].