Evaluation of hydrogeochemical processes and saltwater intrusion in the coastal aquifers in the southern part of Puri District, Odisha, India.

Groundwater is widely regarded as being among the freshwater natural resources with the lowest levels of contamination. Nevertheless, the saltwater intrusion has resulted in the contamination of groundwater in coastal regions with lower elevation. The rationale of the present work is to investigate the chemistry of groundwater, to identify the various facies of groundwater, to identify the processes that influence groundwater chemistry and saltwater intrusion, and to evaluate the groundwater's aptness for use in drinking and farming. In order to gain an understanding of the groundwater quality as well as the salinization process that occurs in coastal aquifers as a result of hydrogeochemical processes, a total of 108 groundwater samples (54 each in pre- and post-monsoon) were taken and analyzed for several physiochemical parameters in the southern part of the Puri district in the Indian state of Odisha. The data has undergone analysis and examination to identify the factors (such as hydrological facies, potential solute source in water, and salinization process) that contribute to groundwater salinity. The result showed the chemistry controlling processes of rock-water interaction as per Gibbs diagram. The majority of shallow aquifers exhibit the Na-Cl type of facies as per the Piper plot. A total of 37% pre-monsoon and 33% post-monsoon samples having Na+/Cl- ratio below the threshold of 0.86 indicating the influence of saltwater intrusion. In both seasons, it was observed that 74% of the samples exhibited a Na+ concentration that exceeded the permissible limit set by the World Health Organization (WHO) for drinking purposes. The findings indicate that most groundwater failed to pass safe drinking water and irrigation standards due to saltwater intrusion. Consequently, the monitoring of coastal aquifer quality has become imperative in order to ensure the sustainability of aquifers and the development of groundwater resources. This is because coastal aquifers are highly vulnerable to saltwater intrusion, primarily as a result of the extensive extraction of groundwater for diverse purposes.

Environmental health risk assessment and source apportion of heavy metals using chemometrics and pollution indices in the upper Yamuna river basin, India.

River Yamuna is the largest tributary of the Ganges with great economic importance, and provides water for about 57 million people and accounts for more than 70% of Delhi's water supply. Various pollution indices and chemometric methods were used to investigate heavy metal pollution, associated risks, and probable sources in the upper Yamuna river water. A total of 56 river water samples, 28 each in pre and post-monsoon season were collected and analysed for 15 heavy metals. The findings reveal that Al (38.66 ± 21.14 µg/L), As (16.52 ± 15.81 µg/L), and Mn (41.06 ± 89.25 µg/L) in pre-monsoon and Al (45.77 ± 29.46 µg/L), As (10.30 ± 12.15 µg/L), Fe (48.03 ± 81.11 µg/L), and Mn (31.02 ± 70.13 µg/L) in post-monsoon exceeded the Bureau of Indian Standards (BIS) acceptable limits. The pollution indices (HPI, NPI, HEI, and Cd) indicate that most locations are low to moderately polluted, except for the lower catchment. Health indices, i.e., hazard Index (HI) and incremental lifetime cancer risk (ILCR), suggest that the prolonged consumption of river water may cause potential human health hazards. In contrast, the water is suitable for domestic and other uses as the dermal risk is less prominent. The ecological risk index (ERI) of pre (0.22-58.75) and post-monsoon (0.12-44.21) were in the low-risk category (<110), indicating no ecological risk associated with heavy metals. In pre and post-monsoon, four principal components (PCs) described 73.97% and 76.18% of the total variance respectively, suggesting the mixed impact of numerous geogenic and anthropogenic sources in the region's water chemistry. Cluster analysis demonstrates that the lower catchment samples (National Capital Region, Delhi) significantly vary from each other due to wastewater discharge, industrialisation, and rapid urbanization, while the upper and mid-catchment samples are less distinct. Hence, more than 90% of the Yamuna water is extracted from the upper region; present findings may aid in developing an effective catchment scale management strategy.

Impacts of climate change and coastal salinization on the environmental risk of heavy metal contamination along the odisha coast, India.

Climate change-mediated rise in sea level and storm surges, along with indiscriminate exploitation of groundwater along populous coastal regions have led to seawater intrusion. Studies on groundwater salinization and heavy metal contamination trends are limited. Present study investigated the heavy metal contamination, associated risks and provided initial information on the impacts of groundwater salinization on heavy metals along the coastal plains of Odisha, India. Total 50 groundwater samples (25 each in post- and pre-monsoon) were collected and analysed. Concentrations of Fe (44%), Mn (44%), As (4%) and Al (4%) in post-monsoon and Fe (32%), Mn (32%), As (4%), B (8%) and Ni (16%) in pre-monsoon exceeded Bureau of Indian Standards (BIS) drinking water limits. High concentrations of heavy metals (Fe, Sr, Mn, B, Ba, Li, Ni and Co) and high EC (>3000 µS/cm) indicated that the groundwater-seawater mixing process has enhanced the leaching and ion exchange of metallic ions in central part of the study area. Multivariate statistical analysis suggested leaching process, seawater intrusion and agricultural practices as the main heavy metal sources in the groundwater. 4% of samples in post- and 16% in pre-monsoon represented high heavy metal pollution index (HPI). Pollution indices indicated the central and south-central regions are highly polluted due to saline water intrusion and high agricultural activities. Ecological risks in the groundwater systems found low (ERI <110) in both seasons. Children population found more susceptible to health risks than adults. Hazard index (HI > 1) has shown significant non-carcinogenic risks where Fe, Mn, As, B, Li and Co are the potential contributors. Incremental lifetime cancer risk (ILCR >1.0E-03) has suggested high carcinogenic risks, where As and Ni are the major contributors. The study concluded that groundwater salinization could increase the heavy metal content and associated risks. This would help policymakers to take appropriate measures for sustainable coastal groundwater management.

Preliminary investigation of saline water intrusion (SWI) and submarine groundwater discharge (SGD) along the south-eastern coast of Andhra Pradesh, India, using groundwater dynamics, sea surface temperature and field water quality anomalies.

Intensive anthropogenic activities along the coastal plains of Andhra Pradesh (such as urbanisation, agriculture and aquaculture) rely extensively on coastal fresh groundwater resources that are pumped at unsustainable rates causing groundwater decline and water quality problems due to saline water intrusion. Hydrogeological studies are imperative to implement groundwater conservation strategies in coastal Andhra Pradesh, which is experiencing a severe freshwater shortage due to overexploitation and saline water intrusion as well as clean water loss through the aquifer system close to the coastal plains. An attempt is made in this study to demarcate the submarine groundwater discharge (SGD) and saline water intrusion (SWI) zones adopting a three-tier validation system, i.e. groundwater dynamic, LANDSAT resultant sea surface temperature (SST) variance and site-specific water characteristics along the southeast coast of Andhra Pradesh, India. A total of 234 water samples (139 porewater, 31 groundwater and 64 seawater samples) were evaluated along ~ 450 km southeast coastline of Andhra Pradesh. In situ porewater physio-chemical parameters, i.e. EC, TDS, pH, DO, temperature, and salinity, at every 1 km except non-accessible areas and groundwater for every 5 km were analysed and used for identification of SGD zones in the study area. The hydraulic gradient values vary from - 11 to 250 m in post-monsoon and - 14 to 250 m in pre-monsoon. And sea surface temperature anomaly for 2017, 2018 and 2019 varies between 21-39 °C, 15-34 °C and 20-39 °C. Three districts out of the four districts studied (Krishna, Guntur and Nellore) were shown to be prone to SWI, whereas Prakasam district was susceptible for SGD. For the first time, this kind of preliminary study was carried out in the coastal Andhra Pradesh region, and it will serve as a basis for the meticulous analysis of the fresh and saline water mixing zones/process as well as to develop and manage the groundwater resources along the water-stressed coastal plains of Andhra Pradesh, India.