A Review of Rechargeable Zinc-Air Batteries: Recent Progress and Future Perspectives.

Zinc-air batteries (ZABs) are gaining attention as an ideal option for various applications requiring high-capacity batteries, such as portable electronics, electric vehicles, and renewable energy storage. ZABs offer advantages such as low environmental impact, enhanced safety compared to Li-ion batteries, and cost-effectiveness due to the abundance of zinc. However, early research faced challenges due to parasitic reactions at the zinc anode and slow oxygen redox kinetics. Recent advancements in restructuring the anode, utilizing alternative electrolytes, and developing bifunctional oxygen catalysts have significantly improved ZABs. Scientists have achieved battery reversibility over thousands of cycles, introduced new electrolytes, and achieved energy efficiency records surpassing 70%. Despite these achievements, there are challenges related to lower power density, shorter lifespan, and air electrode corrosion leading to performance degradation. This review paper discusses different battery configurations, and reaction mechanisms for electrically and mechanically rechargeable ZABs, and proposes remedies to enhance overall battery performance. The paper also explores recent advancements, applications, and the future prospects of electrically/mechanically rechargeable ZABs.

A State-of-Art Review of the Metal Oxide-Based Nanomaterials Effect on Photocatalytic Degradation of Malachite Green Dyes and a Bibliometric Analysis.

A wide range of hard contaminants in wastewater is generated from different industries as byproducts of the organic compound. In this review, various metal oxide-based nanomaterials are employed for the photocatalytic removal of malachite green (MG) dye from wastewater. Some cost-effective and appropriate testing conditions are used for degrading these hard dyes to get higher removal efficiency. The effects of specific parameters are considered such as how the catalyst is made, how much dye is in the solution at first, how much nanocatalyst is needed to break down the dye, the initial pH of the dye solution, the type of light source used, the year of publications, and how long the dye has to be exposed to light to be removed. This study suggests that Scopus-based core collected data employ bibliometric methods to provide an objective analysis of global MG dye from 2011 to 2022 (12 years). The Scopus database collects all the information (articles, authors, keywords, and publications). For bibliometric analysis, 658 publications are retrieved corresponding to MG dye photodegradation, and the number of publications increases annually. A bibliometric study reveals a state-of-art review of metal oxide-based nanomaterials' effects on photocatalytic degradation of MG dyes (12 years).

Cu@Fe-Redox Capacitive-Based Metal-Organic Framework Film for a High-Performance Supercapacitor Electrode.

A metal-organic framework (MOF) is a highly porous material with abundant redox capacitive sites for intercalation/de-intercalation of charges and, hence, is considered promising for electrode materials in supercapacitors. In addition, dopants can introduce defects and alter the electronic structure of the MOF, which can affect its surface reactivity and electrochemical properties. Herein, we report a copper-doped iron-based MOF (Cu@Fe-MOF/NF) thin film obtained via a simple drop-cast route on a 3D-nickel foam (NF) substrate for the supercapacitor application. The as-deposited Cu@Fe-MOF/NF electrodes exhibit a unique micro-sized bipyramidal structure composited with nanoparticles, revealing a high specific capacitance of 420.54 F g-1 at 3 A g-1 which is twice compared to the nano-cuboidal Fe-MOF/NF (210 F g-1). Furthermore, the asymmetric solid-state (ASSSC) supercapacitor device, derived from the assembly of Cu@Fe-MOF/NFǁrGO/NF electrodes, demonstrates superior performance in terms of energy density (44.20 Wh.kg-1) and electrochemical charge-discharge cycling durability with 88% capacitance retention after 5000 cycles. This work, thus, demonstrates a high potentiality of the Cu@Fe-MOF/NF film electrodes in electrochemical energy-storing devices.

Tuning of electron transport layers using MXene/metal-oxide nanocomposites for perovskite solar cells and X-ray detectors.

This work elaborates on the decoration of metal oxides (ZnO and Fe3O4) between MXene sheets for use as the supporting geometry of PCBM electron transport layers (ETLs) in perovskite solar cells and X-ray detectors. The metal oxide supports for carrying the plentiful charge carriers and the hydrophobic nature of MXenes provide an easy charge transfer path through their flakes and a smooth surface for the ETL. The developed interface engineering based on the MXene/ZnO and MXene/Fe3O4 hybrid ETL results in improved power conversion efficiencies (PCEs) of 13.31% and 13.79%, respectively. The observed PCE is improved to 25.80% and 30.34% by blending the MXene/ZnO and MXene/Fe3O4 nanoparticles with the PCBM layer, respectively. Various factors, such as surface modification, swift interfacial interaction, roughness decrement, and charge transport improvement, are strongly influenced to improve the device performance. Moreover, X-ray detectors with the MXene/Fe3O4-modulated PCBM ETL achieve a CCD-DCD, sensitivity, mobility, and trap density of 15.46 µA cm-2, 4.63 mA per Gy per cm2, 5.21 × 10-4 cm2 V-1 s-1, and 1.47 × 1015 cm2 V-1 s-1, respectively. Metal oxide-decorated MXene sheets incorporating the PCBM ETL are a significant route for improving the photoactive species generation, long-term stability, and high mobility of perovskite-based devices.

Chitosan and carbon nitride doped barium hydroxide nanoparticles served as dye degrader and bactericidal potential: A molecular docking study.

Chitosan (CS) and different concentration of graphitic carbon nitride (g-C3N4) (0.02 wt% and 0.04 wt%) doped barium hydroxide (Ba(OH)2) nanoparticles (NPs) were harvested through co-precipitation route. Degradation of the potentially harmful methylene blue (MB) dye and evaluation of the antibacterial potential of the produced CS/g-C3N4-doped Ba(OH)2 NPs were the primary objectives of this study. In addition, the produced NPs were analyzed through structural, optical and morphological techniques to evaluate optical features, phase formation, elemental composition, functional groups presence, surface morphology, crystallinity, and interlayer spacing. The photocatalytic activity was assessed against the degradation of MB by varying pH, whereas Escherichia coli (E. coli) and Staphylococcus aureus (S. aureus) pathogens were utilized to determine bactericidal potential in terms of inhibition zone (mm) measured through Vernier caliper. Highly (4 %) CS/g-C3N4-doped Ba(OH)2 NPs explored effective degradation and antibacterial results as 89.39 % in neutral medium and 7.85 mm against E. coli pathogens, respectively. In silico, molecular docking studies against DNA gyrase and ß-lactamase enzyme from both E. coli and S. aureus were performed to rationale mechanism governing the anti-bacterial potential of these synthesized NPs.

Peroxymonosulfate activated by composite ceramic membrane for the removal of pharmaceuticals and personal care products (PPCPs) mixture: Insights of catalytic and noncatalytic oxidation.

A composite manganese-based catalytic ceramic membrane (Mn-CCM) was developed by a solid-state sintering method, and its effectiveness toward activation of peroxymonosulfate (PMS) for the degradation of 11 pharmaceutical and personal care products (PPCPs) mixture was tested. The optimized Mn-CCMs/PMS system showed remarkable degradation efficiencies for PPCPs mixture with total removal >90% in ultrapure water, river water and natural organic matter (NOM) solution. The Mn-CCMs/PMS system showed the contribution of different phenomena in PPCPs removal in the order of catalytic oxidation (54.7%, Mn-CCMs/PMS) > noncatalytic oxidation (42.3%, PMS oxidation) > adsorption (3.0%, by Mn-CCMs). The singlet oxygen (1O2) was the dominant reactive oxygen specie for the degradation of PPCPs in all water matrices proved by the quenching experiments and electro-paramagnetic resonance (EPR) spectroscopy. The extraordinary stability of Mn-CCMs for the activation of PMS has been noted in terms of repeatability experiments for PPCPs degradation with fewer leaching of Mn (1.9 to 3.6 µg/L). Mineralization was achieved in the range of 28-65% for different water matrices. The toxicity of the PPCPs mixture was reduced by 85.9%. The Mn-CCMs/PMS system showed a reduction (25-100%) in precursors of different carbon- and nitrogen-based disinfection by-products. This study found the Mn-CCMs/PMS system as a feasible purification unit for removing trace concentrations of PPCPs (ng/L) in real drinking water matrices.

Graphitic-C3N4/chitosan-doped NiO nanostructure to treat the polluted water and their bactericidal with in silico molecular docking analysis.

Different concentrations (2 and 4 wt%) of graphite carbon nitride (g-C3N4) was doped into fixed amount of chitosan (CS) and nickel oxide (NiO) nanoparticles (NPs) via a co-precipitation route. The aim of study is to remove the pollutants from wastewater through catalytic activity (CA) and determine the bactericidal activities of synthesized products. X-ray diffraction pattern confirmed the cubic structure of NiO NPs and peak shifted to higher angle upon g-C3N4 doping. Fourier transform infrared spectroscopy revealed the existence of bending and stretching vibration mode. The absorption decreased gradually accompanied blue-shift and assessed bandgap energy increased upon doping. The high resolution transmission electron microscopy micrographs confirmed the formation of cubic-shaped NPs and elongated nanorods were seen for NiO and co-doped NiO. The catalytic efficiency of samples was examined using methylene blue (MB) in the presence of reducing agent. A remarkable dye de-colorization was confirmed with a g-C3N4 and CS doping; moreover, the bactericidal efficacy compared to Escherichia coli (E. coli) and Staphylococcus aureus (S. aureus) was observed as 3.15 and 13.8 mm, respectively. In silico, molecular docking investigations targeting against b-lactamaseS. aureus and FabHE. coli enzymes assisted to elaborate the mechanism underlying microbicidal action of the NPs.

Innovations in the synthesis of graphene nanostructures for bio and gas sensors.

Sensors play a significant role in modern technologies and devices used in industries, hospitals, healthcare, nanotechnology, astronomy, and meteorology. Sensors based upon nanostructured materials have gained special attention due to their high sensitivity, precision accuracy, and feasibility. This review discusses the fabrication of graphene-based biosensors and gas sensors, which have highly efficient performance. Significant developments in the synthesis routes to fabricate graphene-based materials with improved structural and surface properties have boosted their utilization in sensing applications. The higher surface area, better conductivity, tunable structure, and atom-thick morphology of these hybrid materials have made them highly desirable for the fabrication of flexible and stable sensors. Many publications have reported various modification approaches to improve the selectivity of these materials. In the current work, a compact and informative review focusing on the most recent developments in graphene-based biosensors and gas sensors has been designed and delivered. The research community has provided a complete critical analysis of the most robust case studies from the latest fabrication routes to the most complex challenges. Some significant ideas and solutions have been proposed to overcome the limitations regarding the field of biosensors and hazardous gas sensors.

Bias-Modified Schottky Barrier Height-Dependent Graphene/ReSe2 van der Waals Heterostructures for Excellent Photodetector and NO2 Gas Sensing Applications.

Herein, we reported a unique photo device consisting of monolayer graphene and a few-layer rhenium diselenide (ReSe2) heterojunction. The prepared Gr/ReSe2-HS demonstrated an excellent mobility of 380 cm2/Vs, current on/off ratio ~ 104, photoresponsivity (R ~ 74 AW-1 @ 82 mW cm-2), detectivity (D* ~ 1.25 × 1011 Jones), external quantum efficiency (EQE ~ 173%) and rapid photoresponse (rise/fall time ~ 75/3 µs) significantly higher to an individual ReSe2 device (mobility = 36 cm2 V-1s-1, Ion/Ioff ratio = 1.4 × 105-1.8 × 105, R = 11.2 AW-1, D* = 1.02 × 1010, EQE ~ 26.1%, rise/fall time = 2.37/5.03 s). Additionally, gate-bias dependent Schottky barrier height (SBH) estimation for individual ReSe2 (45 meV at Vbg = 40 V) and Gr/ReSe2-HS (9.02 meV at Vbg = 40 V) revealed a low value for the heterostructure, confirming dry transfer technique to be successful in fabricating an interfacial defects-free junction. In addition, HS is fully capable to demonstrate an excellent gas sensing response with rapid response/recovery time (39/126 s for NO2 at 200 ppb) and is operational at room temperature (26.85 °C). The proposed Gr/ReSe2-HS is capable of demonstrating excellent electro-optical, as well as gas sensing, performance simultaneously and, therefore, can be used as a building block to fabricate next-generation photodetectors and gas sensors.

Stabilization of Perovskite Solar Cells: Recent Developments and Future Perspectives.

Exceptional power conversion efficiency (PCE) of 25.7% in perovskite solar cells (PSCs) has been achieved, which is comparable with their traditional rivals (Si-based solar cells). However, commercialization-worthy efficiency and long-term stability remain a challenge. In this regard, there are increasing studies focusing on the interface engineering in PSC devices to overcome their poor technical readiness. Herein, the roles of electrode materials and interfaces in PSCs are discussed in terms of their PCEs and perovskite stability. All the current knowledge on the factors responsible for the rapid intrinsic and external degradation of PSCs is presented. Then, the roles of carbonaceous materials as substitutes for noble metals are focused on, along with the recent research progress in carbon-based PSCs. Furthermore, a sub-category of PSCs, that is, flexible PSCs, is considered as a type of exceptional power source due to their high power-to-weight ratios and figures of merit for next-generation wearable electronics. Last, the future perspectives and directions for research in PSCs are discussed, with an emphasis on their commercialization.

Facile synthesis of starch and tellurium doped SrO nanocomposite for catalytic and antibacterial potential: In silico molecular docking studies.

A chemical co-precipitation route was used to synthesize novel strontium oxide (SrO), SrO-starch composite and various tellurium (Te) concentrations were incorporated in SrO-starch composite. This study aims to enhance the catalytic activities and bactericidal behavior of SrO, SrO-starch composite with different percentage concentrations of Te doping and a fixed amount of starch nanoparticles. XRD affirmed that the dopant contribution was investigated to improve crystallinity. Surface morphological characteristics and elemental composition evaluation were determined using an FE-SEM and EDS exhibit a doping concentration of an element in the synthesized products. The configuration of Sr-O-Sr bonds and molecular vibrations has been indicated by FTIR spectra. In addition, dye degradation of prepared samples was investigated through catalytic activity (CA) in the existence of NaBH4 act as a reduction representative. The Te-doped SrO-starch composite indicates superior catalytic activity and shows a degradation of Methylene blue dye (91.4 %) in an acidic medium. The synthesis nanocatalyst demonstrated impressive antibacterial activity against Staphylococcus aureus (S. aureus) at high and low concentrations exhibiting zones of inhibition 9.30 mm as compared to ciprofloxacin. Furthermore, molecular docking studies of synthesized nanocomposites were performed against selected enzyme targets, i.e., ß-lactamaseE.coli and DNA GyraseE.coli.

Evaluation of bactericidal potential and catalytic dye degradation of multiple morphology based chitosan/polyvinylpyrrolidone-doped bismuth oxide nanostructures.

In this study, 0.02 and 0.04 wt% of chitosan (CS) were successfully incorporated in a fixed amount of polyvinylpyrrolidone (PVP)-doped Bi2O3 nanostructures (NSs) via a co-precipitation approach. The purpose of this research was to degrade hazardous methylene blue dye and assess antimicrobial potential of the prepared CS/PVP-doped Bi2O3 nanostructures. In addition, optical characteristics, charge recombination rate, elemental composition, phase formation, surface morphology, functional groups, d-spacing, and crystallinity of the obtained nanostructures were investigated. CS/PVP-doped Bi2O3 nanostructures exhibited efficient catalytic activity (measured as 99%) in a neutral medium for dopant-free nanostructures while the inhibition zone was measured using a Vernier caliper against pathogens Escherichia coli (E. coli) and Staphylococcus aureus (S. aureus) at low and high doses to check antimicrobial activity. Strong bactericidal action was recorded against S. aureus bacteria such that a significant inhibition zone was measured at 3.09 mm.

Development of Binder-Free Three-Dimensional Honeycomb-like Porous Ternary Layered Double Hydroxide-Embedded MXene Sheets for Bi-Functional Overall Water Splitting Reactions.

In this study, a honeycomb-like porous-structured nickel-iron-cobalt layered double hydroxide/Ti3C2Tx (NiFeCo-LDH@MXene) composite was successfully fabricated on a three-dimensional nickel foam using a simple hydrothermal approach. Owing to their distinguishable characteristics, the fabricated honeycomb porous-structured NiFeCo-LDH@MXene composites exhibited outstanding bifunctional electrocatalytic activity for pair hydrogen and oxygen evolution reactions in alkaline medium. The developed NiFeCo-LDH@MXene electrocatalyst required low overpotentials of 130 and 34 mV to attain a current density of 10 mA cm-2 for OER and HER, respectively. Furthermore, an assembled NiFeCo-LDH@MXene‖NiFeCo-LDH@MXene device exhibited a cell voltage of 1.41 V for overall water splitting with a robust firmness for over 24 h to reach 10 mA cm-2 current density, signifying outstanding performance for water splitting reactions. These results demonstrated the promising potential of the designed 3D porous NiFeCo-LDH@MXene sheets as outstanding candidates to replace future green energy conversion devices.

Valorization of orange peel waste to tunable heteroatom-doped hydrochar-derived microporous carbons for selective CO2 adsorption and separation.

Constrained by the extortionately expensive carbon sources, low carbon yields, inadequate adsorption capacities, and corrosive chemical activating agents, the commercialization of carbonaceous CO2 adsorbents remains a challenging task. Herein, potassium oxalate (K2C2O4), an activating agent with less corrosive properties, was used for the synthesis of activated carbons from inexhaustibly available "orange peel biowaste." For the first time, a comprehensive report is presented on the effect of hydrothermal treatment, hydrochar/K2C2O4 ratio, activation temperature, and melamine modification in tailoring the porosity and surface functionalization of activated carbons. The optimized sample, OPMK-900, exhibited large specific surface area ~2130 m2/g; micropore volume ~1.1166 cm3/g, and a high pyrrolic nitrogen content (~ 46.1 %). Notably, melamine played the dual role as a promoter to K2C2O4 porosity generation and a nitrogen dopant, which synergistically led to an efficient CO2 uptake of ~6.67 mmol/g at 273 K/ 1 bar via micropore-filling mechanism and Lewis acid-base interactions. Moreover, remarkably high IAST CO2/N2 selectivity (105 at 273 K and 96 at 298 K) surpasses most of the biomass-derived carbons. Furthermore, the moderately high isosteric heat of adsorption (∆Hads ~ 38.9 kJ/mol) revealed the physisorption mechanism of adsorption with a limited energy requirement for the regeneration of the spent adsorbents.

Bimetallic Cu/Fe MOF-Based Nanosheet Film via Binder-Free Drop-Casting Route: A Highly Efficient Urea-Electrolysis Catalyst.

Developing efficient electrocatalysts for urea oxidation reaction (UOR) can be a promising alternative strategy to substitute the sluggish oxygen evolution reaction (OER), thereby producing hydrogen at a lower cell-voltage. Herein, we synthesized a binder-free thin film of ultrathin sheets of bimetallic Cu-Fe-based metal-organic frameworks (Cu/Fe-MOFs) on a nickel foam via a drop-casting route. In addition to the scalable route, the drop-casted film-electrode demonstrates the lower UOR potentials of 1.59, 1.58, 1.54, 1.51, 1.43 and 1.37 V vs. RHE to achieve the current densities of 2500, 2000, 1000, 500, 100 and 10 mA cm-2, respectively. These UOR potentials are relatively lower than that acquired by the pristine Fe-MOF-based film-electrode synthesized via a similar route. For example, at 1.59 V vs. RHE, the Cu/Fe-MOF electrode exhibits a remarkably ultra-high anodic current density of 2500 mA cm-2, while the pristine Fe-MOF electrode exhibits only 949.10 mA cm-2. It is worth noting that the Cu/Fe-MOF electrode at this potential exhibits an OER current density of only 725 mA cm-2, which is far inconsequential as compared to the UOR current densities, implying the profound impact of the bimetallic cores of the MOFs on catalyzing UOR. In addition, the Cu/Fe-MOF electrode also exhibits a long-term electrochemical robustness during UOR.

Ultrafast and Highly Stable Photodetectors Based on p-GeSe/n-ReSe2 Heterostructures.

Two-dimensional transition-metal dichalcogenide (2D-TMD) semiconductors and their van der Waals heterostructures (vdWHs) have attracted great attention because of their tailorable band-engineering properties and provide a propitious platform for next-generation extraordinary performance energy-harvesting devices. Herein, we reported unique and unreported germanium selenide/rhenium diselenide (p-GeSe/n-ReSe2) 2D-TMD vdWH photodetectors for extremely sensitive and high-performance photodetection in the broadband spectral range (visible and near-infrared range). A high and gate-tunable rectification ratio (RR) of 7.34 × 105 is achieved, stemming from the low Schottky barrier contacts and sharp interfaces of the p-GeSe/n-ReSe2 2D-TMD vdWHs. In addition, a noticeably high responsivity (R = 2.89 × 105 A/W) and specific detectivity (D* = 4.91 × 1013 Jones), with good external quantum efficiency (EQE = 6.1 × 105) are obtained because of intralayer and interlayer transition of excitations, enabling the broadband photoresponse (λ = 532-1550 nm) at room temperature. Furthermore, fast response times of 16-20 µs are estimated under the irradiated laser of λ = 1550 nm because of interlayer exciton transition. Such a TMD-based compact system offers an opportunity for the realization of high-performance broadband infrared photodetectors.

Valorization of shrimp shell biowaste for environmental remediation: Efficient contender for CO2 adsorption and separation.

Over the years, single heteroatom-doped biowaste-derived activated carbons were studied for effective CO2 adsorption. However, binary or ternary heteroatoms-doping is equally important and could significantly affect the CO2 adsorption and flue gas (i.e., CO2/N2) separation. Herein, for the first time, shrimp shell-derived chitosan was used to design a series of ternary (N, S, O)-doped hierarchically porous carbons. The resultant carbons exhibit a large specific surface area (up to 2095 m2/g), micropore volume (up to 1.2647 cm3/g), and high heteroatoms content i.e., N up to 4.1 at. %, S up to 4.6 at. %, and O up to 13.4 at. %. Consequently, high CO2 uptake of 236.80 mg/g at 273 K/1 bar and an excellent CO2/N2 gas selectivity (84.3) was observed, attributed to the synergistic role of narrow micropores (<1 nm) and optimum heteroatom content. Furthermore, the stable CO2 adsorption-desorption cyclic behavior under flue gas conditions i.e., 15% CO2/85% N2 reveals the physisorption mechanism of CO2 adsorption and appears to be an energy-efficient regeneration process. Concluding, our work demonstrates a facile route of valorization of biowaste for environmental remediation to combat biowaste accumulation and mitigating atmospheric CO2 levels, simultaneously.

Energy-Efficient Tunneling Field-Effect Transistors for Low-Power Device Applications: Challenges and Opportunities.

Conventional field-effect transistors (FETs) have long been considered a fundamental electronic component for a diverse range of devices. However, nanoelectronic circuits based on FETs are not energy efficient because they require a large supply voltage for switching applications. To reduce the supply voltage in standard FETs, which is hampered by the 60 mV/decade limit established by the subthreshold swing (SS), a new class of FETs have been designed, tunnel FETs (TFETs). A TFET utilizes charge-carrier transportation in device channels using quantum mechanical based band-to-band tunneling despite of conventional thermal injection. The TFETs fabricated with thin semiconducting film or nanowires can attain a 100-fold power drop compared to complementary metal-oxide-semiconductor (CMOS) transistors. As a result, the use of TFETs and CMOS technology together could ameliorate integrated circuits for low-power devices. The discovery of two-dimensional (2D) materials with a diverse range of electronic properties has also opened new gateways for condensed matter physics, nanotechnology, and material science, thus potentially improving TFET-based devices in terms of device design and performance. In this review, state-of-art TFET devices exhibiting different semiconducting channels and geometries are comprehensively reviewed followed by a brief discussion of the challenges that remain for the development of high-performance devices. Lastly, future prospects are presented for the improvement of device design and the working efficiency of TFETs.

WS2/GeSe/WS2 Bipolar Transistor-Based Chemical Sensor with Fast Response and Recovery Times.

Vertical heterostructures of transition-metal dichalcogenide semiconductors have attracted considerable attention and offer new opportunities in electronics and optoelectronics for the development of innovative and multifunctional devices. Here, we designed a novel and compact vertically stacked two-dimensional (2D) n-WS2/p-GeSe/n-WS2 van der Waals (vdW) heterojunction bipolar transistor (2D-HBT)-based chemical sensor. The performance of the 2D-HBT vdW heterostructure with different base thicknesses is investigated by two configurations, namely, common-emitter and common-base configurations. The 2D-HBT vdW heterostructure exhibited intriguing electrical characteristics of current amplification with large gains of α ≈ 1.11 and ß ≈ 20.7. In addition, 2D-HBT-based devices have been investigated as chemical sensors for the detection of NH3 and O2 gases at room temperature. The effects of different environments, such as air, vacuum, O2, and NH3, were also analyzed in dark conditions, and with a light of 633 nm wavelength, ultrahigh sensitivity and fast response and recovery times (6.55 and 16.2 ms, respectively) were observed. These unprecedented outcomes have huge potential in modern technology in the development of low-power amplifiers and gas sensors.