A knowledge-aware deep learning model for landslide susceptibility assessment in Hong Kong.

Despite the success of the growing data-driven landslide susceptibility prediction, the model training heavily relies on the quality of the data (involving topography, geology, hydrology, land cover, climate, and human activity), the structure of the model, and the fine-tuning of the model parameters. Few data-driven methods have considered incorporating 'landslide priors', as in this article the prior knowledge or statistics related to landslide occurrence, to enhance the model's perception in landslide mechanism. The main objective and contribution of this study is the coupling of landslide priors and a deep learning model to improve the model's transferability and stability. This is accomplished by selecting non-landslide sample grounded on landslide statistics, disentangling input landslide features using a variational autoencoder, and crafting a loss function with physical constraints. This study utilizes the SHAP method to interpret the deep learning model, aiding in the acquisition of feature permutation results to identify underlying landslide causes. The interpretation result indicates that 'slope' is the most influential factor. Considering the extreme rainfall impact on landslide occurrences in Hong Kong, we combine this prior into the deep learning model and find feature ranking for 'rainfall' improved, in comparison to the ranking result interpreted from a pure MLP. Further, the potency of MT-InSAR is utilized to augment the landslide susceptibility map and promote efficient cross-validation. A comparison of InSAR results with historical images reveals that detectable movement before their occurrence is evident in only a minority of landslides. Most landslides occur spontaneously, exhibiting no precursor motion. Comparing with other data-driven methods, the proposed methods outperform in accuracy (by 2 %-5 %), precision (by 2 %-7 %), recall (by 1 %-3 %), F1-score (by 8 %-10 %), and AuROC (by 2 %-4 %). Especially, the Cohen Kappa performance surpasses nearly 20 %, indicating that the knowledge-aware methodology enhances model generalization and mitigates training bias induced by unbalanced positive and negative samples.

A comparative life cycle assessment of recycling waste concrete powder into CO2-Capture products.

Waste concrete powder (WCP), a byproduct of construction and demolition (C&D), currently has a low degree of recycling despite its potential for environmentally friendly applications. WCP can serve as a valuable substitute for cement, offering advantages for resource conservation and carbon sequestration. However, there are very few studies that quantitatively assess the environmental impact of incorporating WCP into the circular economy as a secondary material instead of disposing of it. The energy-intensive processing of WCP raises questions about the optimal carbonation time using available equipment. This study aims to fill this knowledge gap by employing carbon footprint and life cycle assessments (LCA) to optimize WCP recycling. Three recycling WCP scenarios are analyzed. The first scenario involved the conversion of WCP into compacts that absorb CO2 during the carbonation process. The results of the first scenario revealed that the optimal carbonation time for WCP compacts was 8 h, during which 42.7 kg CO2-e per tonne of WCP compacts was sequestered. The total global warming potential (GWP) was -4.22 kgCO2-e, indicating a carbon-negative recycling process. In the second and third scenarios, LCA was conducted to compare the use of carbonated and uncarbonated WCP as a partial replacement for cement in concrete. In these scenarios, it was found that uncarbonated WCP is a more effective solution for reducing the carbon footprint of traditional concrete mixes, achieving a significant 16% reduction of GWP when 20% of cement is replaced. Conversely, using carbonated WCP as a partial cement replacement in concrete mixtures shows limited potential for CO2 uptake. The sensitivity analysis reveals that the carbon footprint of the WCP compacts production process is strongly influenced by the electricity supplier used.

Life cycle analysis of common landfill final cover systems focusing on carbon neutrality.

Carbon emissions from landfill construction and management have become a global concern. Life cycle analysis (LCA) has been widely used to assess the environmental impacts of engineered infrastructures over their lifetimes. LCA has also been applied to landfill leachate and gas management, but rarely to landfill final cover systems. This paper reports the results of an LCA of the following landfill final cover systems: compacted clay cover, geomembrane cover, cover with capillary effects (CCBE), dual capillary barrier cover, three-layer landfill cover system using natural soils, three-layer cover using recycled concrete aggregate (RCA) and biochar-amended three-layer landfill cover system using RCA. The LCA assessment of landfill cover considers the cost, carbon emissions and carbon sequestration during the production, construction and operation phases. The effects of landfill cover on global warming, freshwater eutrophication, terrestrial ecotoxicity, freshwater ecotoxicity, marine ecotoxicity and fossil resource scarcity are also evaluated. In addition, the sensitivities of cost and carbon emission to the use of electric-powered machines and transportation distance are analysed. It is revealed that the three-layer cover system using RCA and biochar has the lowest unit cost and carbon emission of all of the covers, up to 88 % and 66 % lower, respectively, than those of the other six covers. In addition, this cover system has the highest carbon sequestration rate, with a value of 47.9 kg CO2/(y·m2), four times higher than that of the compacted clay cover. Finally, this sustainable cover mitigates global warming and reduces adverse environmental impacts by up to 82 %. Therefore, the biochar amended three-layer cover system using RCA without geomembrane offers the greatest economic benefits, performs effectively in terms of the pursuit of carbon neutrality and promotes sustainable development.

Dynamics of carbon dioxide emission during cracking in peanut shell biochar-amended soil.

As a primary source of greenhouse gas emissions and a carbon sink, soil plays a key role in climate regulation. The development of cracks in soil strongly influences CO2 emissions, and soil amendment with biochar has been shown to reduce cracking. However, the impact of biochar on CO2 emissions during soil cracking is not well understood. This study investigates the release of CO2 flux during the cracking of peanut shell biochar-amended soil. The biochar-amended soil was incubated at a constant temperature of 35 °C for 160 h with periodic photography and analysis of CO2 concentration and soil moisture. To achieve continuous monitoring of incubation soil, a new coupled sensor was specially designed to measure CO2 concentration and soil moisture, based on the Arduino microcontroller. Measured results reveal that peanut shell biochar reduced the evaporation rate by 29 % compared to unamended soil, resulting in slower soil cracking caused by water loss. The biochar also decreased the shrinkage crack length by 20 % compared to unamended soil. In addition, the crack volume fraction was reduced by 16 % after the peanut shell biochar amendment. Due to the reduction of the soil crack channel openings during drying shrinkage when biochar was applied to the soil, cumulative CO2 fluxes were also reduced by 5 % compared to unamended soil. The presence of biochar induced more stable and larger compounds with the soil particles, which blocked the crack propagation path and inhibited further development of the crack.

Coupled effects of elevated CO2 and biochar on microbial communities of vegetated soil.

Soil microbial communities are important for plant growth and establishing healthy ecosystems. Although biochar is widely adopted as a sustainable fertilizer, its influence on soil ecological functions is still unclear, especially under climate change such as elevated carbon dioxide concentration (eCO2). This study explores the coupled effects between eCO2 and biochar on microbial communities in soil planted with tree seedlings of Schefflera heptaphylla. Root characteristics and soil microbial communities were examined and interpreted with statistical analysis. Results show that biochar application at ambient carbon dioxide concentration (aCO2) always improves plant growth, which is further promoted under eCO2. Similarly, ß-glucosidase, urease and phosphatase activities are enhanced by biochar at aCO2 (p < 0.05). In contrast, only urease activity increases with biochar added at eCO2 (p < 0.05). The beneficial effects of biochar on soil enzyme activities become less significant at eCO2. Depending on biochar type, biochar can increase bacterial diversity and fungal richness at aCO2. However, at eCO2, biochar does not significantly affect microbial richness (p > 0.05) while microbial diversity is reduced by peanut shell biochar (p < 0.05). Owing to better plant growth under biochar application and eCO2, plants are likely to become more dominant in specializing the microbial communities that are favourable to them. In such community, the abundance of Proteobacteria is the greatest and increases after biochar addition at eCO2. The most abundant fungus also shifts from Rozellomycota to Ascomycota and Basidiomycota. These microbes can improve soil fertility. Even though the microbial diversity is reduced, using biochar at eCO2 can further promote plant growth, which in turn enhances carbon sequestration. Thus, biochar application can be an effective strategy to facilitate ecological restoration under climate change and relieve the problem of eCO2.

Intercropping of Pinellia ternata (herbal plant) with Sedum alfredii (Cd-hyperaccumulator) to reduce soil cadmium (Cd) absorption and improve yield.

Soil contamination by cadmium (Cd) is of global concern, threatening not only crop production, but also supply of herbal medicine. Research studies usually grow crops with Sedum alfredii (a Cd-hyperaccumulator). However, intercropping herbal plants with S. alfredii and their interactions with hydro-chemical properties of soil are rarely considered. This study examines the growth of a herbal plant, Pinellia ternata, intercropped with S. alfredii in Cd-contaminated soil. Plant characteristics were assessed, especially biomass and Cd content of bulbil (yield and quality of P. ternata). Soil hydro-chemical properties including water retention, Cd content and organic matter were determined with statistical analyses. At low soil-Cd contamination (0.6 µg/g), bulbil biomass of intercropped P. ternata (PSL) was almost double compared with monoculture of P. ternata (PL), which is barely significant (p ≈ 0.05). The corm biomass of PSL was also significantly greater than that of PL (p < 0.05). Although soil-Cd contamination became more severe by increasing to 3 µg/g, the bulbil biomass in the intercrop was not significantly different from PL (p > 0.05). That said, it is evidenced that the yield of intercropped P. ternata was improved in Cd-contaminated soil. Such improvement was mainly attributed to reduced soil-Cd content and enhanced soil-water retention which was governed by plant roots and soil organic matters. The soil-water retention was first identified as a critical parameter in promoting plant growth under intercropping. More importantly, the bulbil-Cd content of P. ternata in PSL was significantly reduced (p < 0.05). This study demonstrates that the newly proposed intercrop is feasible to improve yield of herbal plants, and at the same time reduce heavy metal absorption and accumulation in medicinal organs, especially for P. ternata. This is anticipated to reduce the human health risk imposed by ingestion of Chinese herbal plants.

Effects of Bacillus subtilis and Pseudomonas fluorescens as the soil amendment.

The application of soil beneficial bacteria (SBB) in agriculture is steadily increasing as it provides a promising way to replace chemical fertilisers and other supplements. Although the role of SBB as a biofertiliser is well understood, little is known about the response of soil physiochemical properties via the change in soil enzymatic activities with SBB growth. In this study, sterilised bulk soil was inoculated with Bacillus subtilis (BS) and Pseudomonas fluorescens (PF), which exhibit excellent characteristics in vitro for potentially improving soil quality. It is found that the contents of bioavailable nitrogen and ammonium in soil inoculated with SBB increased significantly, up to 34% and 57% relative to a control. This resulted from the enhancement of soil urease activity with BS and PF treatments by approximately 90% and 70%, respectively. The increased soil urease activity can be explained by the increased microorganism activity evident from the larger population size of BS (0.78-0.97 CFU mL-1/CFU mL-1) than PF (0.55-0.79 CFU mL-1/CFU mL-1) (p < 0.05). Results of principal component analysis also reinforce the interaction apparent in the significant relationship between soil urease activity and microbial biomass carbon (p < 0.05). Therefore, it can be concluded that the enhancement of soil enzymatic activities induced bulk soil fertility upregulation because of bacterial growth. These results demonstrate the application of SBB to be a promising strategy for bulk soil amendment, particularly nutrient restoration.

Effects of biochar on shear strength of completely decomposed granite.

Biochar has a great potential to sustainably improve the performance of bio-engineered slope due to its ability to retain water and to supply nutrients. Existing studies mainly focus on hydrological properties of biochar-amended soil. However, the effects of biochar on shear strength of soil are not well studied. This study aims to assess the shearing behaviour of biochar-amended completely decomposed granite (CDG). Soil specimens were prepared by mixing CDG with two types of biochar at a mass ratio of 5% and compacted at 95% of the maximum dry density. Although the peak shear strength of biochar-amended CDG is reduced by up to 20% because of lower initial dry density of the soil and crushing of biochar particles during shearing, both types of biochar have negligible effects on the ultimate shear strength, which is governed by friction between soil particles. This highlights that the ultimate friction angle can be adopted for designing bio-engineered slopes using biochar-amended soils.

Effects of phosphorus-modified biochar as a soil amendment on the growth and quality of Pseudostellaria heterophylla.

Phosphorus (P) deficiency in agricultural soil is a worldwide concern. P modification of biochar, a common soil conditioner produced by pyrolysis of wastes and residues, can increase P availability and improve soil quality. This study aims to investigate the effects of P-modified biochar as a soil amendment on the growth and quality of a medicinal plant (Pseudostellaria heterophylla). P. heterophylla were grown for 4 months in lateritic soil amended with P-modified and unmodified biochar (peanut shell) at dosages of 0, 3% and 5% (by mass). Compared with unmodified biochar, P-modified biochar reduced available heavy metal Cd in soil by up to 73.0% and osmotic suction in the root zone by up to 49.3%. P-modified biochar application at 3% and 5% promoted the tuber yield of P. heterophylla significantly by 68.6% and 136.0% respectively. This was different from that in unmodified biochar treatment, where tuber yield was stimulated at 3% dosage but inhibited at 5% dosage. The concentrations of active ingredients (i.e., polysaccharides, saponins) in tuber were increased by 2.9-78.8% under P-modified biochar amendment compared with control, indicating the better tuber quality. This study recommended the application of 5% P-modified biochar for promoting the yield and quality of P. heterophylla.

Quality and yield of Pseudostellaria heterophylla treated with GGBS as pH adjuster against the toxicity of Cd and Cu.

The contamination of Cd and Cu in soil is a great threat to medicinal plant. Ground granulated blast furnace slag (GGBS) is a potential soil pH adjuster to reduce metal toxicity. However, how GGBS affects the quality and yield of herbal plants under the stress of Cd and Cu is not clear. This study aims to investigate the quality and yield of a medicinal plant (Pseudostellaria heterophylla) responding to GGBS treatment in Cd and Cu contaminated soil. GGBS with three mass percentages (0%, 3%, 5%) was added into contaminated lateritic soils for planting. Each condition had 21 replicated seedlings. The concentrations of Cd and Cu in plant, amounts of active ingredients (polysaccarides and saponins) in medicinal organ, and tuber properties were measured after harvest. The results showed that under 3% and 5% GGBS treatments, Cd and Cu accumulations in all plant organs (leaf, stem, root and tuber) were reduced by 69.4-86.0% and 10.3-30.1%, respectively. They were below the permissible limits (World Health Organization, WHO). Even though the concentrations of active ingredients in P. heterophylla tuber decreased by up to 35.8%, they still met Hong Kong Chinese Materia Medica standard. Besides, the biomass of root tuber increased by 9.8% and 46%, due to 3% and 5% GGBS treatments, respectively. The recommended 5% GGBS treatment in practice can balance the reduction of active ingredients and the increase of plant yield when minimizing Cd and Cu accumulation in tuber.

Effect of competitive adsorption on the transport of multiple pollutants through a compacted clay liner.

Leachate transport through municipal solid waste (MSW) landfill liners can be slowed considerably by adsorption. MSW landfill leachate contains a large variety of pollutants at very different concentrations, and there will be competitive adsorption as these pollutants are transported through the landfill's compacted clay liner (CCL). In this study, we used batch adsorption tests and geotechnical centrifuge modelling to examine how the adsorption of pollutants commonly found in leachate changed under competitive adsorption conditions and how competitive adsorption affected the CCL breakthrough of multiple pollutants. The results showed that the adsorption of the target pollutant on clay decreased by approximately 30% when competing pollutants were added. The speed at which the pollutants were transported through a 2-m-thick CCL increased, and the breakthrough times reduced by up to 24.8%, when the competing pollutants were mixed. Competitive adsorption significantly promoted the CCL breakthrough of pollutants at low concentrations, but it had limited effect on pollutants at high concentrations.

Soil desiccation cracking and its characterization in vegetated soil: A perspective review.

The formation and propagation of surface desiccation cracks in vegetated infrastructures involve coupled factors including unsaturated soil mechanics, atmospheric conditions and vegetation parameters. Vegetation induces a "Love-hate" relationship in the development of desiccation cracks due to plant induced suction as well as root reinforcement. The objective of the paper is to provide a state-of-the-art that comprehensively reviews the desiccation process in context of the soil-water-plant interaction together. At first, basic theories of crack initiation and propagation in literature are discussed in the context of unsaturated soil mechanics. Thereafter, influence of vegetation on soil cracking is discussed systematically based on transpiration induced suction, root reinforcement, plantation strategy, root exudate and basic plant traits. Intrusive and non-intrusive measurement approaches of desiccation cracks including lab and field studies are put forward. Various schools of desiccation models have been briefly touched upon. More than 150 studies on desiccation cracks have been tabulated in this review, considering soil types, vegetation cover, drying-wetting cycles, approaches of characterizing cracks, sample size, crack pattern, hydraulic conductivity and water retention. Future scopes involving measurement considerations, usage of geotechnical centrifuge modelling, bio-amendments and plant effects on desiccation cracking have been put forward.

Modelling root growth and soil suction due to plant competition.

Previous experimental results show that planting spacing has significant effects on root distribution and soil suction (negative pore water pressure) due to inter-plant competition. However, there is a lack of theoretical study on this aspect. This study proposes a new physically based mathematical model to capture planting spacing effects on root growth and soil suction considering three key factors, namely hydrotropism, soil mechanical impedance and inter-plant competition. The model is mainly composed of four parts: (i) extension of root zone front; (ii) increase in root density; (iii) root water uptake and (iv) water flow in soil matrix. Root growth and root water uptake are fully coupled. In order to validate the model, laboratory and field tests were conducted on one tree (Schefflera heptaphylla) and one shrub species (Schefflera arboricola), respectively, with different planting spacings. Even though the investigated tree and shrub species had different values of leaf area index and root length density, consistent conclusions on planting spacing effects can be drawn. When planting spacing became smaller, the size of root system decreased while root density increased, hence causing higher soil suction. The model can capture the root distributions as well as induced soil suction during both evapotranspiration and rainfall events quite well for both tree and shrub species.

Effects of biochar on bacterial communities in a newly established landfill cover topsoil.

Recent studies revealed the benefits of applying biochar in landfill final cover soil, such as adsorbing odorous compounds and promoting microbial methane oxidation. Most of these processes are related to the soil bacterial communities. However, the effects of biochar application on the overall bacterial community in newly established landfill cover soil are not yet understood, especially in field condition. The objective of the present field study is to investigate the effects of biochar on the diversity of soil bacterial community 3 months after incubation (short-term). Landfill final cover topsoil (0.6 m) was amended with 0 (control), 5, and 10% (w/w) of biochar derived from peanut-shell and wheat straw. Soil bacterial communities were analysed using the 16S rRNA-based T-RFLP approach. Biochar application significantly (p < 0.05) increased the diversity of soil bacterial communities. The Shannon diversity index of bacterial communities in soil amended with 5 and 10% of biochar was increased from 3.34 to 3.85 and 3.92, respectively. There were four bacterial phyla recorded found at both control and amended soils, namely Actinobacteria, Bacteroidetes, Firmicutes, and Proteobacteria. In addition, Gemmatimonadetes was found only in soil amended with 10% biochar. The interactions between soil bacterial communities and measured soil parameters including moisture content, electrical conductivity, total organic matter, total nitrogen and total phosphorus were found to be statistically non-significant (p > 0.05), according to the canonical correspondence analysis (CCA). This may be due to the highly heterogeneous nature of landfill soil. Results from this study revealed that short-term biochar application already altered the soil physicochemical properties and increased the diversity of soil bacterial communities.

Long-term effects of grass roots on gas permeability in unsaturated simulated landfill covers.

Landfill cover is a barrier that can reduce landfill gas emission. Vegetation could affect soil hydraulic properties of landfill cover, while its effects on gas permeability is not well understood. This paper investigated the effects of plant roots on the evolution of gas permeability (kg) in unsaturated landfill cover over a two-year period. One grass species (Cynodon dactylon) was selected for testing in the laboratory and there were six replications. Bare soil was used as a reference. kg was determined after 6, 15 and 24 months of grass growth. The test results show that with the increase of suction, kg increased linearly in log scale for both bare and grass-covered soils. kg of grass-covered can be lower or higher than that of bare soil, depending on the plant age. After 6 months, kg of grass-covered soil was smaller than that of bare soil by 85%, due to the root occupancy of soil pore space. However, after 15 and 24 months, kg of grass-covered soil increased by 2-3 orders of magnitude within the root zone over the suction range considered (2-86 kPa). After 2 years, kg of grass-covered soil was up to one order of magnitude higher than that in bare soil. It implies that mature vegetation is not beneficial for reducing gas emission in final landfill covers.

Arbuscular mycorrhizal fungal community in the topsoil of a subtropical landfill restored after 18 years.

Restoration of disturbed habitats (e.g., landfills and mine tailings) is important to recover ecosystem services. Arbuscular mycorrhizal (AM) fungal community is an important indicator of ecological performance of ecosystems. Rhizospheric soils were collected in two sites (A1 and A2) within the restored area of a landfill (18 yrs after restoration), and two sites (B and C, serving as control) in the adjacent natural area. Soil properties were analysed. AM fungal communities in soils were analysed by sequencing 18S small subunit rRNA gene. Results showed that genera Glomus (the most abundant, relative abundance: 10-24%), Paraglomus and Rhizophagus were commonly found at all sites. Acaulospora and Redeckera were found exclusively at natural sites, while Scutellospora only at the restored site. On average, AM fungal species richness was lower (87 operational taxonomy units, OTUs), while diversity was higher (Shannon index 3.2) in restored site, compared with control (107 OTUs, Shannon index 2.8). The structure of the AM fungal communities was influenced by soil nitrogen and cation exchange capacity. The restored sites possessed a more phylogenetically heterogeneous fungal community than that in natural sites. AM fungal community at restored sites clearly deviated from that at natural sites, indicating that current restoration practice is certainly inadequate. The trend of ecological succession could be significantly influenced by rehabilitation methods, such as adjustment of initial soil properties and selection of plant species. This study highlights the necessity of assessing AM fungal community during ecological restoration for sustainable ecosystem, in addition to plant and bacteria.

Leachate breakthrough mechanism and key pollutant indicator of municipal solid waste landfill barrier systems: Centrifuge and numerical modeling approach.

Groundwater pollution by leachate leakage is one of the most common environmental hazards associated with municipal solid waste (MSW) landfill sites. However, landfill leachate contains a large variety of pollutants with widely different concentrations and biotoxicity. Thus, selecting leachate pollutant indicators and levels for identifying breakthrough of barrier systems are key factors in assessing their breakthrough times. This study investigated the transport behavior of leachate pollutants through landfill barrier systems using centrifuge tests and numerical modeling. The overall objective of this study is to investigate breakthrough mechanism to facilitate the establishment of a consistent pollutant threshold concentration for use as a groundwater pollution alert. The specific objective of the study is to identify which pollutant and breakthrough threshold concentration should be used as an indicator in the transport of multiple pollutants through a landfill barrier system. The threshold concentration from the Chinese groundwater quality standards was used in the analysis of the properties of leachates from many landfill sites in China. The time for the chemical oxygen demand (COD) to reach the breakthrough threshold concentration at the bottom of a 2m compacted clay liner was 1.51years according to centrifuge tests, and 1.81years according to numerical modeling. The COD breakthrough times for single and double composite liners were within the range of 16 and 36.58years. Of all the pollutants, COD was found to consistently reach the breakthrough threshold first. Therefore, COD can be selected as the key indicator for pollution alerts and used to assess the environmental risk posed by MSW landfill sites.

Effects of biochar on hydraulic conductivity of compacted kaolin clay.

Compacted clay is widely used as capillary barriers in landfill final cover system. Recently, biochar amended clay (BAC) has been proposed as a sustainable alternative cover material. However, the effects of biochar on saturated hydraulic conductivity (ksat) of clay with high degree of compaction is not yet understood. The present study aims to investigate the effects of biochar on ksat of compacted kaolin clay. Soil specimens were prepared by amending kaolin clay with biochar derived from peanut-shell at 0, 5 and 20% (w/w). The ksat of soil specimens was measured using a flexible water permeameter. The effects of biochar on the microstructure of the compacted clay was also investigated using MIP. Adding 5% and 20% of biochar increased the ksat of compacted kaolin clay from 1.2 × 10-9 to 2.1 × 10-9 and 1.3 × 10-8 ms-1, respectively. The increase in ksat of clay was due to the shift in pore size distribution of compacted biochar-amended clay (BAC). MIP results revealed that adding 20% of biochar shifted the dominant pore diameter of clay from 0.01-0.1 µm (meso- and macropores) to 0.1-4 µm (macropores). Results reported in this communication revealed that biochar application increased the ksat of compacted clay, and the increment was positively correlated to the biochar percentage.

Effects of biochar on the ecological performance of a subtropical landfill.

Landfills commonly occupy large areas of land that may be ecologically important. Ecological restoration of landfill cover is a necessary approach to rebuild sustainable habitats. However, unfavourable soil conditions and invasion by exotic plants in certain regions hinder the restoration. In this study, the effects of biochar as a soil amendment on the restoration of a landfill cover were investigated under field condition. Topsoils of a landfill cover in the subtropical region (Shenzhen, China) were mixed with 0, 5 and 10% (v/v) of biochar. Soil pH, electronic conductivity, organic matter, total organic carbon, water content, total N and total P were enhanced by biochar amendment. After nine months of self-succession, plant productivity, species richness and diversity were enhanced by biochar. The structures of soil bacterial and arbuscular mycorrhizal (AM) fungal communities were changed, and species richness and diversity were moderately promoted. Enhanced plant growth and diversity were probably attributed to a number of enhanced bacterial functions related to nutrient cycling including aerobic ammonia oxidation, aerobic nitrite oxidation, nitrification, sulphur respiration, nitrate respiration, nitrogen respiration, ureolysis, chemoheterotrophy and fermentation. The higher abundances of bacteria Streptomyces sp. and Pseudomonas sp. in biochar treatments potentially enhanced the AM fungal diversity. The bacterial diversity was more related to the soil properties, especially pH, than AM fungi. Continuous monitoring is necessary to track the changes of species composition and ecological functions over time. This is the first comprehensive study on the effects of biochar on the ecological performance of a man-made ecosystem. In addition to agricultural application, biochar can be used for restoring degraded lands.

Mechanisms of hydrogen sulfide removal by ground granulated blast furnace slag amended soil.

Ground granulated blast furnace slag (GGBS) amended soil has been found able to remove gaseous hydrogen sulfide (H2S). However, how H2S is removed by GGBS amended soil and why GGBS amended soil can be regenerated to remove H2S are not fully understood. In this study, laboratory column tests together with chemical analysis were conducted to investigate and reveal the mechanisms of H2S removal process in GGBS amended soil. Sulfur products formed on the surface of soil particle and in pore water were quantified. The test results reveal that the reaction between H2S and GGBS amended soil was a combined process of oxidation and acid-base reaction. The principal mechanism to remove H2S in GGBS amended soil was through the formation of acid volatile sulfide (AVS), elemental sulfur and thiosulfate. Soil pH value decreased gradually during regeneration and reuse cycles. It is found that the AVS plays a significant role in H2S removal during regeneration and reuse cycles. Adding GGBS increased the production of AVS and at the same time suppressed the formation of elemental sulfur. This mechanism is found to be more prominent when the soil water content is higher, leading to increased removal capacity.