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1.
ACS Omega ; 9(15): 17289-17296, 2024 Apr 16.
Article in English | MEDLINE | ID: mdl-38645359

ABSTRACT

Water commonly occurs in coal reservoirs, and it can block the gas flow channels. This has a significant influence on methane transportation within coal. To reveal the gas emission law of water-containing coal across the rank range, three typical coal samples with different coal ranks covering lignite to anthracite were selected in this work. The initial velocity of gas emission (ΔP) under the effect of moisture was measured, and the combination of scanning electron microscopy and mercury injection method was adopted to study the pores and fracture characteristics within coal. Distribution features of oxygen-containing groups in coal were explored by X-ray photoelectron spectroscopy. The microscopic influence mechanism of the water content on ΔP in coal was also comprehensively elucidated. The experimental results show that the moisture content has an obvious inhibitory effect on the ΔP of coal, but the degree of influence on different coal rank samples was different. As the pore space of anthracite (sample XJ) is developed with numerous gas transportation channels, the ΔP has less changes at the lower moisture content (<4.36%). When the moisture content is >4.36%, a large number of water molecules will band together to form water clusters, hindering the gas release, thus greatly reducing the ΔP. However, the change of lignite (sample SL) shows an inverse trend to that of anthracite. Its ΔP is sensitive to the moisture content due to the small number of pores and low porosity. In addition, a great number of oxygen-containing groups in lignite can also provide good surface hydrophilicity for water molecules, and even a small amount of the moisture content (<3.21%) can block most of the pore and facture channels within coal, leading to the remarkable decrease in ΔP. For bituminous coal (sample ML), the distribution of pores and oxygen-containing groups is the most uniform, and the ΔP decreases linearly with the increase in the moisture content.

2.
Environ Sci Pollut Res Int ; 31(19): 28007-28024, 2024 Apr.
Article in English | MEDLINE | ID: mdl-38526715

ABSTRACT

The coal's mechanical properties have a significant influence on mining safety and the mine environment. Preparing a standard sample and conducting repeat mechanical testing are challenging because the coal is primarily soft, fragmented, and rich in developed fractures. This study used nanoindentation technology, combined with X-ray diffraction, small-angle X-ray, a high magnification microscope, and mechanical parameter scale-up analysis, to study the micromechanical of three coals being dominated by heterogeneous components and pores. The results show that load-displacement curves with different maximum loads (50 mN, 100 mN, and 200 mN) all appear the pop-in events, and coal heterogeneity affects the frequency of their occurrence. As the maximum load is increased, pop-in event of DSC appears once each, YW increases from zero to three times and HM decreases from four to two times. The heterogeneity of pore structure has little effect on residual displacement, which is mainly affected by hard minerals, and hard minerals reduce the law that residual displacement increases with the increase in maximum load. The micromechanical parameters of soft coals are mainly affected by large pores, while hard coals are mainly affected by hard minerals. The coal's heterogeneity does not affect the linear relationship between hardness and elastic modulus, but stronger heterogeneity will weaken the linear relationship between fracture toughness and elastic modulus. Compared to the mechanical parameters after scale-up, the values obtained based on nanoindentation are less than 15.588% larger, and the increase in the heterogeneity and hard minerals can make the predicted parameters more accurate. The nanoindentation technique can not only provide an efficient and accurate method for studying the mechanical properties of heterogeneous coal at the nanoscale, an important guide for large-scale coal.


Subject(s)
Coal , Minerals , Minerals/chemistry , X-Ray Diffraction
3.
ACS Omega ; 8(33): 30213-30220, 2023 Aug 22.
Article in English | MEDLINE | ID: mdl-37636939

ABSTRACT

In order to study the pore alteration and permeability of coal affected by acid liquor, samples were collected from the Yuwu coal mine in the Qinshui basin, Shanxi Province, and taken as the study object. Hydrochloric acid (HCl) with a 10% volume concentration was used to treat these coal samples. The pore structure characteristics and gas permeability of this coal with different treatment times were measured by laboratory experiments. The fractal theory was introduced to analyze the complexity of the sample pore and the changing rules of coal permeability. The research results show that acid liquor has a significant influence on the pore structure of YW coal. Under the effect of acid treatment, the micropore volume of the coal sample is reduced, but both the mesopore and macropore volume are increased. The fractal dimension of acidulated coal samples changes in the range of 2.57-2.81, and it is exponentially decreased with the increase of the treatment time. This indicates that the acid treatment can make the YW coal surface become smooth, and the pore structure tends to be smooth. The acidification method is able to effectively enhance the coal permeability with a maximum increment of about 9.43 times. After 30 h of acid treatment, the total pore volume, fractal dimension, and gas permeability of this coal tend to be stable. The acid treatment time should be controlled at around 30 h.

4.
Environ Sci Pollut Res Int ; 30(3): 8269-8279, 2023 Jan.
Article in English | MEDLINE | ID: mdl-36053423

ABSTRACT

Coal spontaneous combustion (CSC) is a major disaster threatening coal mine safety; therefore, the investigation of coal spontaneous combustion and oxidation characteristics has been a hot topic in the long term. In this paper, the experimental temperature programmed system is used to carry out the simulation experiment of coal spontaneous combustion and oxidation of three kinds of coal with different metamorphic degrees under three oxygen concentrations (9%, 15%, 21%). The effects of metamorphic degree and oxygen concentration on coal oxidation characteristics were analyzed, and the variation laws of crossing point temperature, three characteristic point temperature, and apparent activation energy were qualitatively discussed. Finally, coal oxidation reaction stages were evaluated and divided. The results show that the concentrations of CO and C2H4 are negatively correlated with the degree of deterioration but increase with the increase of oxygen concentration. High metamorphic coal corresponds to high crossing point temperature (CPT). The average error between the CPT value calculated from the BM empirical correlation and the experimental data is very small, which is 6.42%. The higher the metamorphic degree of coal, the higher the three characteristic temperature points (critical temperature, xerochasy temperature, and activity temperature). The oxidation process of the three coal samples is divided into four stages: surface oxidation, oxidation self-heating, accelerated oxidation, and deep oxidation. The apparent activation energy of each stage exhibits significant variability, with varying patterns displayed with the degree of metamorphism.


Subject(s)
Coal , Spontaneous Combustion , Hot Temperature , Oxidation-Reduction , Oxygen
5.
Materials (Basel) ; 15(17)2022 Aug 29.
Article in English | MEDLINE | ID: mdl-36079358

ABSTRACT

Banana peel powder (BPP) was used to prepare poly(lactic acid) (PLA) bio-based composites and the flame retardancy was enhanced by introducing silica-gel microencapsulated ammonium polyphosphate (MCAPP). The results showed that the limiting oxygen index (LOI) of PLA containing 15 wt % BPP was 22.1% and just passed the UL-94 V-2 rate. Moreover, with the introduction of 5 wt % MCAPP and 15 wt % BPP, the PLA composite had a higher LOI value of 31.5%, and reached the UL-94 V-0 rating, with self-extinguishing and anti-dripping abilities. The PLA/M5B15 also had a lower peak heat release rate (296.7 kW·m-2), which was 16% lower than that of the PLA/B15 composite. Furthermore, the synergistic effects between MCAPP and BPP impart better thermal stability to PLA composites. According to the investigation of the char residue and pyrolysis gaseous products, MCAPP with BPP addition is beneficial to the formation of a higher quality char layer in the solid phase but also plays the flame retardant effect in the gas phase. This work provides a simple and efficient method to solve the high cost and flammability issues of PLA composites.

6.
ACS Omega ; 7(9): 7777-7790, 2022 Mar 08.
Article in English | MEDLINE | ID: mdl-35284714

ABSTRACT

The liquid nitrogen freeze-thaw (LN2-FT) method has been widely used to improve the coal permeability in the coalbed methane (CBM) production. However, the influence of moisture content on the permeability of coal treated by LN2-FT remains unclear, limiting the broad application of this technique. A novel seepage system was proposed to analyze the permeability evolution of anthracite coal samples treated by LN2-FT. Moreover, variations of the pore structure were analyzed using scanning electron microscopy (SEM), mercury intrusion porosimetry (MIP), and low-field NMR. The results showed that pores and fractures appeared on the coal surface after the LN2-FT treatment. As the moisture content of the coal increased, more pores and fractures tended to be formed during the LN2-FT treatment. The total pore volume, porosity, and average pore diameter of the anthracite coal after the treatment were 1.77, 2.44, and 5.58 times higher, respectively, than that of the raw coal. The change in the specific surface area exhibited three trends as the moisture content of the coal samples increased: a slow descent, a steady increase, and a rapid descent. Moreover, it was found that the LN2-FT treatment increased the connections between pores and fractures, improving gas migration in the coal. Furthermore, the LN2-FT treatment significantly increased the permeability of the anthracite coal samples. The higher the coal moisture, the higher the permeability of the coal samples after the LN2-FT treatment. Hence, the LN2-FT technique can substantially improve the permeability of coal reservoirs, providing essential information for the efficient utilization of CBM.

7.
Environ Sci Pollut Res Int ; 29(13): 18851-18867, 2022 Mar.
Article in English | MEDLINE | ID: mdl-34699010

ABSTRACT

Fully utilizing the energy generated by the explosion of pulverized coal will contribute to realize the clean and efficient exploitation of coal resources. The pulverized coal explosion characteristics will be a far-reaching and important task to explore. In this paper, ten kinds of low-quality coals such as high sulfur, high ash, and low metamorphic degree coals were investigated and the minimum ignition energy (MIE), lower explosion limit (LEL), and explosion intensity (EI) parameters under different particle sizes and coal powder concentration conditions were also analyzed combined with a 1.2-L Hartmann tube and a 20-L explosion sphere experimental system. Finally, the morphological characteristics of the exploded coal powder surface were evaluated by scanning electron microscopy (SEM). The results show that the particle size is positively correlated with MIE. LEL shows an inverted "U"-shaped trend with the increasing degree of coal deterioration. The low-rank coal is more flammable and explosive. The maximum pressure PMax at the LEL concentration and maximum pressure rise rate (dP/dt)Max overall value is small. Here, optimum pulverized coal particle size (75µm) for explosive utilization of low-quality coal was determined. Within 50-225 g/m3 of pulverized coal concentration range, the explosion intensity increases with increasing concentration. The smaller the particle size of pulverized coal, the greater the possibility of agglomeration of pulverized coal particles. The surface of the exploded coal particles produces more developed pores. They are irregularly shaped and have more rounded edges than the original coal.


Subject(s)
Coal , Sulfur , Coal/analysis , Particle Size
8.
ACS Omega ; 6(50): 34395-34405, 2021 Dec 21.
Article in English | MEDLINE | ID: mdl-34963925

ABSTRACT

The technique of high-voltage electrical pulses (HVEP) is a new method to enhance the permeability of coal seams and improve the efficiency of coalbed methane (CBM) exploitation. This paper is aimed at investigating the crack propagation characteristics of samples of different strengths, proposing the improved procedure of HVEP in field application, and proving that the electrohydraulic effect has a wide use in field application of CBM extraction. In this paper, an experimental system utilizing HVEP in water condition is established, coal samples with different strengths are crushed, and the extended processes of cracks are analyzed. According to the research results, the electrohydraulic effect has a good breakage on the coal; the number of main cracks is 2-3 and the length of the main cracks is about 30 cm in the vertical direction of the hard samples; and the formation of cracks is relevant to the discharge voltage, discharge times, and mechanical parameters of the samples. The results of scanning electron microscopy (SEM) demonstrate that the cracks and pore connectivity of the coal samples are improved obviously, and the permeability results show that the permeability of crushed coal samples is 20% greater than that of the raw coal sample. Meanwhile, the generation process of cracks can be divided into four periods: namely, fatigue damage accumulation, slow development, rapid development, and failure; the rapid development stage is the optimal phase in field application. Moreover, the shock wave produced by HVEP via electrohydraulic effect can crush the samples mainly; furthermore, the energy produced by bubble rupture also has a great influence on the formation of cracks. This study can provide a foundation for the HVEP to improve CBM exploitation.

9.
J Nanosci Nanotechnol ; 21(1): 22-42, 2021 01 01.
Article in English | MEDLINE | ID: mdl-33213611

ABSTRACT

Based on gas adsorption theory, high-pressure mercury intrusion (HPMI), low-temperature liquid nitrogen gas adsorption (LT-N2GA), CO2 adsorption, scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FTIR) and small-angle X-ray scattering (SAXS) techniques were used to analyze the pore structures of six coal samples with different metamorphisms in terms of pore volume, specific surface area (SSA), pore size distribution (PSD) and pore shape. Combined with the gas adsorption constant a, the influence and mechanism of the pore structure of different coal ranks on gas adsorption capacity were analyzed. The results show that there are obvious differences in the pore structure of coals with different ranks, which leads to different adsorption capacities. To a large extent, the pore shapes observed by SEM are consistent with the LT-N2GA isotherm analysis. The pore morphology of coal samples with different ranks is very different, indicating the heterogeneity among the coal surfaces. Adsorption analysis revealed that mesopore size distributions are multimodal and that the pore volume is mainly composed of mesopores of 2-15 nm. The adsorption capacity of the coal body micropores depends on the 0.6-0.9 nm and 1.5-2.0 nm aperture sections. The influence of coal rank on gas desorption and diffusion is mainly related to the difference in pore structure. The medium metamorphic coal sample spectra show that the number of peaks in the high-wavenumber segment is small and that it is greater in the high metamorphic coal. The absorption intensity of the C-H stretching vibration peak of naphthenic or aliphatic hydrocarbons varies significantly among the coal samples. Over a small range of angles, as the scattering angle increases, the scattering intensity of each coal sample gradually decreases, and as the degree of metamorphism increases, the scattering intensity gradually increases. That is, the degree of metamorphism of coal samples is directly proportional to the scattering intensity. The influence of coal rank on gas adsorption capacity is mainly related to the difference in pore structure. The gas adsorption capacity shows an asymmetric U-shaped relationship with coal rank. For higher rank coals (Vdaf < 15%), the gas adsorption consistently decreases significantly with increasing Vdaf. In the middle and low rank coal stages (Vdaf > 15%), it increases slowly with the increase of Vdaf. We believe that the results of this study will provide a theoretical basis and practical reference value for effectively evaluating coal-rock gas storage capacity, revealing the law of CBM enrichment and the development and utilization of CBM resources.

10.
J Nanosci Nanotechnol ; 21(1): 405-421, 2021 Jan 01.
Article in English | MEDLINE | ID: mdl-33213640

ABSTRACT

Four coals samples at different ranks were analyzed by Fourier transform infrared (FTIR), X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD), and solid-state 13C nuclear magnetic resonance (NMR). The calculated coal molecular model was constructed according to the experimental data. The mode of evolution of four coal molecules with different metamorphic degrees was explored. The results indicate that the nanostructures of these four coal molecules mainly consist of aromatic structures, aliphatic structures and oxygen-containing functional groups. The coal metamorphic degree is the most important factor affecting the evolution of the coal molecular nanostructure. By increasing the coal rank, the aromatic carbon content and aromatic system increase, while the aliphatic carbon content and aliphatic system decrease, and the species and content of oxygen containing functional groups are also reduced. During the evolution of the molecular microcrystalline structure, the degree of vertical order of the aromatic structural unit, the flatness of the aromatic structural unit (La), the average crystallite stacking height (Lc), and the average number of crystallites in a stack (n) increase, while the interlayer distance between aromatic sheets (d002) decreases; the short-range ordering of the coal structure is mainly caused by changes in the orientational arrangement from intramolecular aromatic layers to intermolecular aromatic layers when low-rank coal molecules evolve to high rank coal molecules. The structural evolution mechanism of coal molecules of different ranks has been revealed through the analysis of the mode of evolution of the molecular structure the coal. This study enables us to better understand the nanostructure evolution mechanism of coal molecules at different ranks.

11.
J Nanosci Nanotechnol ; 21(1): 538-546, 2021 Jan 01.
Article in English | MEDLINE | ID: mdl-33213652

ABSTRACT

The complexity and multiscale structure of coal pores significantly influence the gas diffusion and seepage characteristics of coal. To apply small angle X-ray scattering (SAXS) to study the coal pore structure parameters within the scale of 1-100 nm in the methane adsorption process, the X-ray window was optimized and a gas adsorption chamber was designed to interface with the small angle X-ray scattering platform. The fractal dimension and porosity of Hami coal samples under different methane pressures were studied using the small angle X-ray scattering platform and adsorption chamber. The surface and nanopore fractal information of the nanopores in coal were distinguished. The variation trends of the pores and surface fractal dimension with time under the same methane pressure were compared. The results indicate that the surface dimension changes from 2.56 to 2.75, and the extremum point may indicate that the primary nanopore structure is crushed by the adsorbed gas after approximately 15 minutes. This work clarifies that the fractal dimension can characterize the changes in nanopores in the process of gas adsorption by using SAXS. According to the fractal characteristics, the adsorption of gas in coal nanopores is summarized as four steps: expansion from adsorbance, deformation, crushing and recombination. The minimum porosity is 0.95% and the extreme value point is 1.47%. This work also shows that decrease in surface energy affect the porosity changes in nano-size pores. This work is of some significance to coalbed methane permeability improvement and gas extraction.

12.
ACS Omega ; 5(49): 31716-31723, 2020 Dec 15.
Article in English | MEDLINE | ID: mdl-33344824

ABSTRACT

The bright spot phenomenon during the gas explosion was because of the soot particles of high heat radiation characteristics generated during the explosion process. The formation mechanism of soot and precursor polycyclic aromatic hydrocarbons (PAHs) of the methane explosion was numerically simulated using CHEMKIN-PRO. The methane explosion soot of the CH4-air premixed gas explosion experiments with volume concentrations of 8% was collected, and the pore size distribution and surface structure of the soot were analyzed by low-pressure nitrogen gas adsorption (LP-N2GA), scanning electron microscopy (SEM), and transmission electron microscopy (TEM). The results show that C2 and C3 play an important role in the formation of PAHs in the early stage of the explosion reaction. The LP-N2GA isotherms demonstrate that the pore type of the soot particles is mostly wedge-shaped, which was verified with SEM observations. The SEM analysis showed that the methane explosion soot is composed of a large number of spherical soot aggregates with diameters between 4 and 50 µm and the pores at the particle surface are well developed, some of the particles exhibit a melt sintering feature. Soot aggregates collide with each other with a chain-branched structure, and the diameters of the majority of the particles are of 100 nm according to TEM images. In addition, graphite-like lattice stripes can be clearly seen inside the particles when magnified to 8 nm. This work will provide the basis for further analysis of soot formation in the gas explosion process.

13.
ACS Omega ; 5(38): 24639-24653, 2020 Sep 29.
Article in English | MEDLINE | ID: mdl-33015481

ABSTRACT

Methane gas is mainly present in coal in two forms: free and adsorbed. There are a large number of closed pores inside the coal, which makes it difficult to measure the gas content of the coal. Therefore, studying the nanoscale closed pores of coal is of great importance for gas control. To study the pore structure characteristics of coal with different deformation degrees and to analyze the volume fraction of closed pores in coal, various coal samples were analyzed by the low-temperature liquid nitrogen adsorption method (LT-N2GA), the carbon dioxide adsorption method, and small-angle X-ray scattering (SAXS). The variation of parameters such as the pore size, pore volume, specific surface area, and degree of metamorphism was compared by using different methods to obtain the proportion of the closed pore volume of different coal samples. The results show that with the increase of the degree of coal metamorphism, the total pore volume and specific surface area of coal samples show a decreasing trend first and then an increasing trend, while the average pore diameter of coal samples gradually increases first and then decreases sharply. When the degree of deterioration of coal is low (volatile content > 20%), the closed pores of coal account for more than 48% of the open pores. When the degree of deterioration of coal samples is relatively high (volatile content <20%), the proportion of large pores in coal bodies decreased from 59.47 to 29.07%, and the proportion of pores in mesopores decreased from 12.15 to 11.09% and finally increased to 11.65%, and the proportion of micropore diameter increased from 28.38 to 59.28%. The volume fraction of the coal sample measured by the SAXS experiment shows that when the coal quality is high, the volume of the mesopores is large, which is consistent with the results of the low-temperature liquid nitrogen and CO2 adsorption experiments. Judging from the number of holes, the number of closed holes is 1 to 3 orders of magnitude greater than the number of open holes, and the number of closed holes of coal samples accounts for more than 94% of the total number of holes. It shows that the number of closed holes in the coal is far greater than the number of open holes, so the gas in the coal is mainly concentrated in the closed holes, and the formation of closed pores is partly because of the collapse of the internal structure and partly because of the volatilization of unstable substances. The research combined with LT-N2GA, the carbon dioxide adsorption method, and SAXS test methods can better analyze the number of closed pores of coal and characterize the nanopore fracture structure of coal. The novelties of this article are that this is a quantitative analysis performed using a scientific method of SAXS. The findings of this study can lead to a better understanding of the coal and gas outburst mechanism and the existence of gas to adopt better prevention measures.

14.
Sci Rep ; 9(1): 15005, 2019 Oct 18.
Article in English | MEDLINE | ID: mdl-31628364

ABSTRACT

Outburst simulation experiments facilitate understanding coal and gas outburst in underground mining. With the help of the mid-scale simulation system, a model based on similitude principle, coal seam sandwiched by roof and floor, was constructed to conduct an outburst experiment. It had a three-dimensional size of 1500 mm × 600 mm × 1000 mm with 0.5 MPa gas pressure. The experimental procedures include specimen preparation, moulding, sealing, gas charging and adsorption, and completion. The outburst process was investigated by analyzing the gas pressure variation, temperature variation, outburst propagation velocity, particle size of outburst coal and energy transformation. During the experiment, each gas charging was accompanied with gas pressure or temperature fluctuation because of coal behavior of gas adsorption-desorption. The outburst propagation velocity was 17.2 m/s, obtained by a mass-weighted calculation of velocities of outburst coal. The small-size coal particles have a higher desorption rate and tend to participate in outburst process. According to energy conservation law, the energy forms of the outburst included elastic strain energy (Ee), gas expansion energy (Ep), internal energy of coal (ΔU), breakage work (W1), throwing out work (W2) and gas-flow loss energy (ΔE), and each was calculated respectively. Gas potential energy, including gas expansion energy and internal energy of coal, registered a larger percent and was far greater than the strain energy. And it can be the main factor influencing the occurrence of low-threshold outburst. The experimental system provides a feasible way to study the initiation and evolution of coal and gas outbursts.

15.
Int J Occup Saf Ergon ; 24(2): 268-277, 2018 Jun.
Article in English | MEDLINE | ID: mdl-28092228

ABSTRACT

In order to enhance Chinese workers' occupational safety awareness, it is essential to learn from developed countries' experiences. This article investigates thoroughly occupational safety and health (OSH) in China and the UK; moreover, the article performs a comparison of Chinese and British OSH training-related laws, regulations and education system. The following conclusions are drawn: China's work safety continues to improve, but there is still a large gap compared with the UK. In China a relatively complete vocational education and training (VET) system has been established. However, there exist some defects in OSH. In the UK, the employer will not only pay attention to employees' physiological health, but also to their mental health. The UK's VET is characterized by classification and grading management, which helps integrate OSH into the whole education system. China can learn from the UK in the development of policies, VET and OSH training.


Subject(s)
Occupational Health/education , Occupational Health/legislation & jurisprudence , Vocational Education/organization & administration , Accidents, Occupational/mortality , Accidents, Occupational/prevention & control , Accidents, Occupational/statistics & numerical data , China , Humans , Mental Health/standards , Occupational Health/statistics & numerical data , Policy , United Kingdom , Vocational Education/methods
16.
Environ Sci Technol ; 51(21): 12072-12080, 2017 Nov 07.
Article in English | MEDLINE | ID: mdl-28956434

ABSTRACT

China, the largest coal producer in the world, is responsible for over 50% of the total global methane (CH4) emissions from coal mining. However, the current emission inventory of CH4 from coal mining has large uncertainties because of the lack of localized emission factors (EFs). In this study, province-level CH4 EFs from coal mining in China were developed based on the data analysis of coal production and corresponding discharged CH4 emissions from 787 coal mines distributed in 25 provinces with different geological and operation conditions. Results show that the spatial distribution of CH4 EFs is highly variable with values as high as 36 m3/t and as low as 0.74 m3/t. Based on newly developed CH4 EFs and activity data, an inventory of the province-level CH4 emissions was built for 2005-2010. Results reveal that the total CH4 emissions in China increased from 11.5 Tg in 2005 to 16.0 Tg in 2010. By constructing a gray forecasting model for CH4 EFs and a regression model for activity, the province-level CH4 emissions from coal mining in China are forecasted for the years of 2011-2020. The estimates are compared with other published inventories. Our results have a reasonable agreement with USEPA's inventory and are lower by a factor of 1-2 than those estimated using the IPCC default EFs. This study could help guide CH4 mitigation policies and practices in China.


Subject(s)
Coal Mining , Methane , Air Pollutants , China , Coal
17.
Appl Ergon ; 65: 1-11, 2017 Nov.
Article in English | MEDLINE | ID: mdl-28802427

ABSTRACT

Fatigue can lead to decreased work performance and poorer safety and health condition. Fatigue is ubiquitous in production and in life, while the research on it is mainly concentrated in the automotive driving, aircraft piloting and other fields, and it is insufficient to study on the fatigue of fixed-position staff. This paper puts forward a non-contact visual image method, which can monitor the extent of fatigue of fixed-position staff. Fatigue threshold used in judgment is obtained by processing the recorded data of visual images of the experimental subjects when fatiguing and by analyzing eye closure time, percentage of eyelid closure (PERCLOS) value, frequency and number of blinks. The results show that there is significant difference among the four indicators before and after experiment subjects undergo fatigue. The fatigue of experimental subjects is obvious when eye closure time is 3.5 s/min, PERCLOS value 6%, and blink frequency 0.4 times/s. This provides a reference for a wider range of detection of fatigue and a method for avoiding mistakes and accidents.


Subject(s)
Blinking , Eyelids/physiopathology , Fatigue/diagnosis , Fatigue/physiopathology , Adult , Algorithms , Female , Humans , Image Processing, Computer-Assisted , Male , Pattern Recognition, Automated , Time Factors , Video Recording , Young Adult
18.
J Hazard Mater ; 192(2): 741-7, 2011 Aug 30.
Article in English | MEDLINE | ID: mdl-21704454

ABSTRACT

In order to substantially suppress the shock waves resulting from gas explosions in coal mines as well as to reveal the mechanism of explosion flame quenching by foam ceramics, a rectangular explosion test pipe was designed, which has a 200mm × 200mm cross-section and is similar in shape to the roadways in coal mines. Explosion flame propagation characteristics in empty pipe and in the presence of Al(2)O(3) and SiC foam ceramics were experimentally investigated. To obtain direct observations, the flame propagation was photographed by a high-speed camera. Furthermore, the mechanism of foam ceramics affecting gas explosion propagation was analyzed. The results demonstrate that the foam ceramics attenuate drastically the maximal explosion overpressure by up to fifty percent; the interconnected micro-network structure of the foam ceramics contribute to quenching gas explosion flame and suppressing shock wave overpressure. These important findings hint that, if properly designed and deployed, this material is expected to be developed into a new suppression and isolation technique against multiple and continuous gas explosions that are presently a grave threat to production safety of coal mines across China and the rest of the world.


Subject(s)
Ceramics , Fires , Gases
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