Biobased, biodegradable and compostable plastics: chemical nature, biodegradation pathways and environmental strategy.

Increasing pollution of plastic waste is one of the major global environmental threats, deteriorating our land, water and air. The shift towards biobased, biodegradable and compostable plastics is considered a green alternative to petroleum-based plastic due to its renewable source or biodegradability. However, there is a misconception about biodegradable plastics and their degradability and behaviour after service life. Biobased, biodegradable and compostable plastics offer various benefits such as less carbon footprint, energy efficiency, independence and eco-safety. On the other hand, there are some disadvantages such as higher cost, limited recycling, misuse of terms and lack of legislation. Also, there is an urgent need for comparable international standard methods to define these materials as biodegradable material, or biocompostable material. There are some standards currently available, however, an in-depth detail and explanation of these standards is still missing. This review outlines the basic definition and chemical structure of biobased, biodegradable and compostable plastics; describes the degradation pathways of biodegradable and compostable plastics; and summarises current key applications of these materials together with possible future applications in different industries. Finally, strategies are developed for minimising the environmental impacts and the need for future research is proposed.

CRISPR/Cas-mediated editing of cis-regulatory elements for crop improvement.

To improve future agricultural production, major technological advances are required to increase crop production and yield. Targeting the coding region of genes via the Clustered Regularly Interspaced Short Palindromic Repeats/CRISPR-associated Protein (CRISPR/Cas) system has been well established and has enabled the rapid generation of transgene-free plants, which can lead to crop improvement. The emergence of the CRISPR/Cas system has also enabled scientists to achieve cis-regulatory element (CRE) editing and, consequently, engineering endogenous critical CREs to modulate the expression of target genes. Recent genome-wide association studies have identified the domestication of natural CRE variants to regulate complex agronomic quantitative traits and have allowed for their engineering via the CRISPR/Cas system. Although engineering plant CREs can be advantageous to drive gene expression, there are still many limitations to its practical application. Here, we review the current progress in CRE editing and propose future strategies to effectively target CREs for transcriptional regulation for crop improvement.

Forecasting of energy consumption by G20 countries using an adjacent accumulation grey model.

This paper studies an adjacent accumulation discrete grey model to improve the prediction of the grey model and enhance the utilization of new data. The impact of COVID-19 on the global economy is also discussed. Two cases are discussed to prove the stability of the adjacent accumulation discrete grey model, which helped the studied model attain higher forecasting accuracy. Using the adjacent accumulation discrete grey model, non-renewable energy consumption in G20 countries from 2022 to 2026 is predicted based on their consumption data from 2011 to 2021. It is proven that the adjacent accumulation exhibits sufficient accuracy and precision. Forecasting results obtained in this paper show that energy consumption of all the non-renewable sources other than coal has an increasing trend during the forecasting period, with the USA, Russia, and China being the biggest consumers. Natural gas is the most consumed non-renewable energy source between 2022 and 2026, whereas hydroelectricity is the least consumed. The USA is the biggest consumer of Nuclear energy among the G20 countries, whereas Argentina consumed only 0.1 Exajoules of nuclear energy, placing it at the end of nuclear energy consumers.

Performance of waste plastic bio-oil as a rejuvenator for asphalt binder.

Pavement recycling is actively applied on asphalt roads due to ageing problems associated with bituminous binders when exposed to weathering and trafficking during their service life. Recycling of asphalt occurs through rejuvenator agents. This study utilised bio-oil produced from hydrothermal liquefaction of waste plastic films (linear low-density polyethylene - LLDPE) to rejuvenate laboratory-aged bitumen. Initially, the neat bitumen was aged through thermal ageing (Pressure Ageing Vessel - PAV) and then the aged binder was mixed with bio-oil from waste plastics at 5% and 8% bio-oil (BO) by weight of aged binder. All four binders including neat bitumen, aged bitumen, aged bitumen/BO-5% and aged bitumen/BO-8% were analysed for thermogravimetric analysis, Fourier Transform Infra-Red analysis, rheology in the linear viscoelastic region, multiple stress creep and recovery analysis, and linear amplitude sweep analysis. The ageing of neat binder resulted in hardening of the binder; however, the bio-oil rejuvenator softened the aged binder significantly. The thermo-chemical and rheological performance of aged binder was significantly improved after the addition of bio-oil. The outcomes suggest how bio-oil produced from hydrothermal liquefaction of waste plastics (possibly non-recyclable) may serve as potential rejuvenator for aged asphalt binders in an effort to recycle more using non-recyclable material.

Integrated treatment of food waste with wastewater and sewage sludge: Energy and carbon footprint analysis with economic implications.

Food waste (FW) is a primary constituent of solid waste and its adequate management is a global challenge. Instead of disposal in landfills, integrated treatment of FW with wastewater (WW) can diminish both environmental and economic burdens. Utilizing steady-state modelling and life cycle assessment techniques, this study investigated the prospects of FW integration with biological WW treatment in terms of WW treatment performance, net energy and carbon footprint and economics of the process. The explored scenarios include co-disposal and treatment with WW by using FW disposers and anaerobic co-digestion with sewage sludge in Hong Kong. Compared to the existing WW and FW treatment, the integrated scenarios significantly improved the energy balance (~83-126%), net greenhouse gas emissions (~90%), and economics of operation, with permissible impact on WW treatment performance. Therefore, utilizing the surplus capacity of the existing WW treatment facilities, these integrated scenarios are a promising solution for sustainable development.

The effect of KOH activation and Ag nanoparticle incorporation on rice husk-based porous materials for wastewater treatment.

Major agricultural solid waste, rice husk (RH)-based mesoporous materials were prepared by potassium hydroxide (KOH) treatment of RH and RH hydrochar (RHH) produced at 180 °C with 20 min reaction time. In this study, RH was treated with three different methods: RH activation by KOH (KOH-RH), RH activation by KOH-aqueous silver (Ag)-shell nanoparticle (AgNP) incorporation followed calcination at 550 °C for 2 h (AgNP-KOH-RH) and hydrothermally carbonized RH activation by KOH (KOH-RHH). The main objective of this study was to determine the effect of KOH activation with different synthesis approaches and compare the characterization results of RH based porous material to identify the potential adsorbent application for wastewater treatment. Therefore, after activation in different methods, all interactive properties such as elemental, chemical, structural, morphological, and thermal analyses were investigated comprehensively for all samples. The crystallinity peak intensity around 22°λ at the angle of diffraction of 2θ confirmed the presence of silica, higher stability of the material, and removal of organic components during the KOH activation. AgNP-KOH-RH and KOH-RHH presented high porosity on the outer surface. The presence of negligible volatile matter in KOH-RHH by TGA demonstrated the decomposition of organic compound. Very high ratio of aromatic carbon and lignin content by FTIR and XPS analysis in both AgNP-KOH-RH and KOH-RHH showed these two samples have improved stability. Very high negative surface charge (zeta potential) in AgNP-KOH-RH (-43.9 mV) and KOH-RHH (-43.1 mV) indicated the enhanced water holding capacity. Surface area for all experimented porous materials has been enhanced after KOH activation, where KOH-RHH demonstrated the maximum surface area value, 27.87 m2/g. However, AgNP-KOH-RH presented maximum pore diameter, 18.16 nm, and pore volume, 0.12 cm3/g. Hence, it can be concluded that both KOH-RHH and AgNP-KOH-RH have the potential to be implemented as wastewater adsorbents.

Sustainable Polymers from Recycled Waste Plastics and Their Virgin Counterparts as Bitumen Modifiers: A Comprehensive Review.

The failure of bituminous pavements takes place due to heavy traffic loads and weather-related conditions, such as moisture, temperature, and UV radiation. To overcome or minimize such failures, a great effort has been put in recent years to enhance the material properties of bitumen, ultimately improving field performance and increasing the pavement service life. Polymer modification is considered one of the most suitable and by far the most popular approach. Elastomers, chemically functionalised thermoplastics and plastomers * (* Note: notwithstanding the fact that in Polymer Science the word 'plastomer' indicates a polymer with the simultaneous behaviour of an elastomer and plastics (thermoplastics), this paper uses the term 'plastomer' to indicate a thermoplastic polymer as it is more commonly found in Civil and Pavement Engineering.) are the most commonly used polymers for bitumen modification. Plastomers provide several advantages and are commonly acknowledged to improve high-temperature stiffness, although some of them are more prone to phase separation and consequent storage instability. Nowadays, due to the recent push for recycling, many road authorities are looking at the use of recycled plastics in roads. Hence, some of the available plastomers-in pellet, flakes, or powder form-are coming from materials recycling facilities rather than chemical companies. This review article describes the details of using plastomers as bitumen modifiers-with a specific focus on recycled plastics-and how these can potentially be used to enhance bitumen performance and the road durability. Chemical modifiers for improving the compatibility between plastomers and bitumen are also addressed in this review. Plastomers, either individual or in combination of two or three polymers, are found to offer great stiffness at high temperature. Different polymers including HDPE, LDPE, LLDPE, MDPE, PP, PS, PET, EMA, and EVA have been successfully employed for bitumen modification. However, each of them has its own merit and demerit as thoroughly discussed in the paper. The recent push in using recycled materials in roads has brought new light to the use of virgin and recycled plastomers for bitumen modification as a low-cost and somehow environmental beneficial solution for roads and pavements.

Carbon and polymer-based magnetic nanocomposites for oil-spill remediation-a comprehensive review.

Oil spills are a major contributor to water contamination, which sets off a significant impact on the environment, biodiversity, and economy. Efficient removal of oil spills is needed for the protection of marine species as well as the environment. Conventional approaches are not efficient enough for oil-water separation; therefore, effective strategies and efficient removal techniques (and materials) must be developed to restore the contaminated marine to its normal ecology. Several research studies have shown that nanotechnology provides efficient features to clean up these oil spills from the water using magnetic nanomaterials, particularly carbon/polymer-based magnetic nanocomposites. Surface modification of these nanomaterials via different techniques render them with salient innovative features. The present review discusses the advantages and limitations of conventional and advanced techniques for the oil spills removal from wastewater. Furthermore, the synthesis of magnetic nanocomposites, their utilization in oil-water separation, and adsorption mechanisms are discussed. Finally, the advancement and future perspectives of magnetic nanocomposites (particularly of carbon and polymer-based magnetic nanocomposites) in environmental remediation are presented.

A comprehensive review on magnetic carbon nanotubes and carbon nanotube-based buckypaper for removal of heavy metals and dyes.

Industrial effluents contain several organic and inorganic contaminants. Among others, dyes and heavy metals introduce a serious threat to drinking waterbodies. These pollutants can be noxious or carcinogenic in nature, and harmful to humans and different aquatic species. Therefore, it is of high importance to remove heavy metals and dyes to reduce their environmental toxicity. This has led to an extensive research for the development of novel materials and techniques for the removal of heavy metals and dyes. One route to the removal of these pollutants is the utilization of magnetic carbon nanotubes (CNT) as adsorbents. Magnetic carbon nanotubes hold remarkable properties such as surface-volume ratio, higher surface area, convenient separation methods, etc. The suitable characteristics of magnetic carbon nanotubes have led them to an extensive search for their utilization in water purification. Along with magnetic carbon nanotubes, the buckypaper (BP) membranes are also favorable due to their unique strength, high porosity, and adsorption capability. However, BP membranes are mostly used for salt removal from the aqueous phase and limited literature shows their applications for removal of heavy metals and dyes. This study focuses on the existence of heavy metal ions and dyes in the aquatic environment, and methods for their removal. Various fabrication approaches for the development of magnetic-CNTs and CNT-based BP membranes are also discussed. With the remarkable separation performance and ultra-high-water flux, magnetic-CNTs, and CNT-based BP membranes have a great potential to be the leading technologies for water treatment in future.

Recycling of low-value packaging films in bitumen blends: A grey-based multi criteria decision making approach considering a set of laboratory performance and environmental impact indicators.

Many road construction and maintenance projects are increasingly using recycled material as pavement material. Most of the times, generic sustainability evaluations are ascribed to recycled products without fully considering their performance. The potential environmental benefits of various alternatives can be analytically evaluated with Life Cycle Assessment while many performance indicators can be found through laboratory and field tests. However, it is highly uncommon for these two approaches to be combined in the same assessment methodology and most of the analyses rely on one or the other. Trading off between environmental advantages and performance and durability in the field is considered of utmost importance when evaluating construction alternatives, especially on large projects. This study utilizes recycled plastic packaging films for bitumen modification. The recycled polyolefin blend is a combination of linear low-density polyethylene and low-density polyethylene (LLDPE/LDPE). LLDPE/LDPE was added in bitumen at various dosages (i.e., from 3% to 12% by weight of the bitumen) to assess the effect of recycled LLDPE/LDPE on the binder physio-chemical, rheological and thermal performance. In addition to the various laboratory performance tests, the environmental sustainability of the alternatives was evaluated through an LCA study. Finally, the outcomes from the two approaches (laboratory performance and environmental impact assessment) were combined via grey relational analysis to identify the best overall alternative. It was found that the storage stability of LLDPE/LDPE modified blends varied from 6 °C to 57 °C whereas the storage stability value of A35P was 2 °C. Softening point of bitumen was 44.1 °C which improved to 55.7-104.1 °C at different content of LLDPE/LDPE. The melting temperature of LLDPE/LDPE modified blends was 100.22, 101.44, 101.87 and 102.49 for LLDPE/LDPE-3%, LLDPE/LDPE-6%, LLDPE/LDPE-9% and LLDPE/LDPE-12%. The methodology highlighted in the paper can be easily adapted to other scenarios, hence facilitating multi-attribute decision-making processes when incorporating recycled materials in roads and leading to better informed decisions.

Magnetic nanocomposites for sustainable water purification-a comprehensive review.

Numerous contaminants in huge amounts are discharged to the environment from various anthropogenic activities. Waterbodies are one of the major receivers of these contaminants. The contaminated water can pose serious threats to humans and animals, by distrubing the ecosystem. In treating the contaminated water, adsorption processes have attained significant maturity due to lower cost, easy operation and environmental friendliness. The adsorption process uses various adsorbent materials and some of emerging adsorbent materials include carbon- and polymer-based magnetic nanocomposites. These hybrid magnetic nanocomposites have attained extensive applications in water treatment technologies due to their magnetic properties as well as combination of unique characteristics of organic and inorganic elements. Carbon- and polymer-related magnetic nanocomposites are more adapted materials for the removal of various kinds of contaminants from waterbodies. These nanocomposites can be produced via different approaches such as filling, pulse-laser irradiation, ball milling, and electro-spinning. This comprehensive review is compiled by reviewing published work of last the latest recent 3 years. The review article extensively focuses on different approaches for producing various carbon- and polymer-based magnetic nanocomposites, their merits and demerits and applications for sustainable water purification. More specifically, use of carbon- and polymer-based magnetic nanocomposites for removal of heavy metal ions and dyes is discussed in detail, critically analyzed and compared with other technologies. In addition, commercial viability in terms of regeneration of adsorbents is also reviewed. Furthermore, the future challenges and prospects in employing magnetic nanocomposites for contaminant removal from various water sources are presented.

Synthesis and characterization of rice husk biochar via hydrothermal carbonization for wastewater treatment and biofuel production.

The recent implication of circular economy in Australia spurred the demand for waste material utilization for value-added product generations on a commercial scale. Therefore, this experimental study emphasized on agricultural waste biomass, rice husk (RH) as potential feedstock to produce valuable products. Rice husk biochar (RB) was obtained at temperature: 180 °C, pressure: 70 bar, reaction time: 20 min with water via hydrothermal carbonization (HTC), and the obtained biochar yield was 57.9%. Enhancement of zeta potential value from - 30.1 to - 10.6 mV in RB presented the higher suspension stability, and improvement of surface area and porosity in RB demonstrated the wastewater adsorption capacity. Along with that, an increase of crystallinity in RB, 60.5%, also indicates the enhancement of the catalytic performance of the material significantly more favorable to improve the adsorption efficiency of transitional compounds. In contrast, an increase of the atomic O/C ratio in RB, 0.51 delineated high breakdown of the cellulosic component, which is favorable for biofuel purpose. 13.98% SiO2 reduction in RB confirmed ash content minimization and better quality of fuel properties. Therefore, the rice husk biochar through HTC can be considered a suitable material for further application to treat wastewater and generate bioenergy.

Magnetic nanoparticles incorporation into different substrates for dyes and heavy metals removal-A Review.

Substantial discharge of hazardous substances, especially dyes and heavy metal ions to the environment, has become a global concern due to many industries neglecting the environmental protocols in waste management. A massive discharge of contaminantsfrom different anthropogenic activities, can pose alarming threats to living species and adverse effect to the ecosystem stability. In the process of treating the polluted water, various methods and materials are used. Hybrid nanocomposites have attained numerous interest due to the combination of remarkable features of the organic and inorganic elements in a single material. In this regards, carbon and polymer based nanocomposites have gained particular interest because of their tremendous magnetic properties and stability. These nanocomposites can be fabricated using several approaches that include filling, template, hydrothermal, pulsed-laser irradiation, electro-spinning, detonation induced reaction, pyrolysis, ball milling, melt-blending, and many more. Moreover, carbon-based and polymer-based magnetic nanocomposites have been utilized for an extensive number of applications such as removal of heavy metal and dye adsorbents, magnetic resonance imaging, and drug delivery. This review emphasized mainly on the production of magnetic carbon and polymer nanocomposites employing various approaches and their applications in water and wastewater treatment. Furthermore, the future opportunities and challenges in applying magnetic nanocomposites for heavy metal ion and dye removal from water and wastewater treatment plant.

Study of diesel engine characteristics by adding nanosized zinc oxide and diethyl ether additives in Mahua biodiesel-diesel fuel blend.

This study deals with an experimental investigation to assess the characteristics of a modified common rail direct injection (CRDI) engine utilizing diesel, Mahua biodiesel, and their blends with synthesized zinc oxide (ZnO) nano additives. The physicochemical properties of diesel, diesel + 30 ppm ZnO nanoparticles (D10030), 20% Mahua biodiesel (MOME20), and Mahua biodiesel (20%) + 30 ppm ZnO nanoparticles (MOME2030) were measured in accordance to the American Society for Testing and Materials standards. The effects of modification of fuel injectors (FI) holes (7-hole FI) and toroidal reentrant combustion chamber (TRCC) piston bowl design on the performance of CRDI using different fuel blends were assessed. For injection timings (IT) and injection opening pressure (IOP) average increase in brake thermal efficiency for fuel blend D10030 and MOME2030 was 9.65% and 16.4%, and 8.83% and 5.06%, respectively. Also, for IT and IOP, the average reductions in brake specific fuel consumption, smoke, carbon monoxide, hydrocarbon and nitrogen oxide emissions for D10030 and MOME2030 were 10.9% and 7.7%, 18.2% and 8.6%, 12.6% and 11.5%, 8.74% and 13.1%, and 5.75% and 7.79%, respectively and 15.5% and 5.06%, 20.33% and 6.20%, 11.12% and 24.8%, 18.32% and 6.29%, and 1.79% and 6.89%, respectively for 7-hole fuel injector and TRCC. The cylinder pressure and heat release rate for D10030 and MOME2030 were enhanced by 6.8% and 17.1%, and 7.35% and 12.28%. The 7-hole fuel injector with the nano fuel blends at an injection timing and pressure of 10° btdc and 900 bar demonstrated the overall improvement of the engine characteristics due to the better air quality for fuel mixing. Similarly, the TRCC cylinder bowl geometry illustrated advanced ignition due to an improved swirl and turbulence. Also, the engine test results demonstrated that 30 ppm of ZnO nanoparticles in Mahua biodiesel (MOME2030) and diesel (D10030) with diethyl ether resulted overall enhancement of CRDI engine characteristics.

Photocatalytic degradation of methyl orange from wastewater using a newly developed Fe-Cu-Zn-ZSM-5 catalyst.

Photo-Fenton oxidation is one of the most promising processes to remove recalcitrant contaminants from industrial wastewater. In this study, we developed a novel heterogeneous catalyst to enhance photo-Fenton oxidation. Multi-composition (Fe-Cu-Zn) on aluminosilicate zeolite (ZSM-5) was prepared using a chemical process. Subsequently, the synthesized catalyst was characterized by using X-ray diffraction (XRD), field emission scanning electron microscope (FESEM), high-resolution transmission electron microscopy (HRTEM), energy dispersive X-ray (spectroscopy) (EDX), and Brunauer-Emmett-Teller (BET). Activity of the synthesized catalyst is analysed to degrade an azo dye, methyl orange. Taguchi method is used to optimize color removal and total carbon content (TOC) removal. The dye completely degraded, and 76% of TOC removal was obtained at optimized process conditions. The amount of catalyst required for the desired degradation of dye significantly reduced up to 92% and 30% compared to conventional homogenous and heterogeneous Fenton oxidation processes, respectively.

Magnetic nanoadsorbents' potential route for heavy metals removal-a review.

Due to the rapid growth in the heavy metal-based industries, their effluent and local dumping have created significant environmental issues. In the past, typically, removal of heavy metals was handled by reverse osmosis and ion exchange techniques, but these methods have many disadvantages. Therefore, extensive work into the development of improved techniques has increased, especially for heavy metal removal. Many countries are currently researching new materials and techniques based on nanotechnology for various applications that involve extracting heavy metals from different water sources such as wastewater, groundwater, drinking water and surface water. Nanotechnology provides the possibility of enhancing existing techniques to tackle problems more efficiently. The development in nanotechnology has led to the discovery of many new materials such as magnetic nanoparticles. These nanoparticles demonstrate excellent properties such as surface-volume ratio, higher surface area, low toxicity and easy separation. Besides, magnetic nanoparticles can be easily and efficiently recovered after adsorption compared with other typical adsorbents. This review mainly emphasises on the efficiency of heavy metal removal using magnetic nanoadsorbent from aqueous solution. In addition, an in-depth analysis of the synthesis, characterisation and modification approaches of magnetic nanoparticles is systematically presented. Furthermore, future opportunities and challenges of using magnetic particles as an adsorbent for the removal of heavy metals are also discussed.

Promoting sustainability of use of biomass as energy resource: Pakistan's perspective.

Biomass is primary source of energy for household in rural communities. Developing countries are focusing on increasing utilization of indigenous energy resources for energy security and to achieve sustainable development goal. Combustion of solid biomass is the primary approach for utilizing biomass to generate electricity and heat. Sixty-eight percent of population of Pakistan is living in rural areas while 30% population is still without electricity. The traditional household appliances used for cooking and heating are less efficient, more hazardous to users, and more damaging to the environment. Low carbon energy system prerequisites access to modern energy services. This paper presents an assessment of biomass resources potential in Pakistan as renewable energy resources and reviews potentials to adopt efficient use of biomass for cooking, heating, and small decentralized electricity generation. Objective of this study is to increase the sustainability of the use of biomass as source of energy in developing countries like Pakistan by an integrating energy-efficient and modern appliances and technologies that fit into a sustainable development path. Promotion of cleaner technologies and efficient use of biomass energy constitute appropriate strategies to mitigate global climate, health risks, and help in attending the targets set by sustainable development goal (SDG) to confirm worldwide access to reliable, affordable, and modern energy services by 2030.

Synthesis and characterization of polylactide/rice husk hydrochar composite.

Polymer composites are fabricated by incorporating fillers into a polymer matrix. The intent for addition of fillers is to improve the physical, mechanical, chemical and rheological properties of the composite. This study reports on a unique polymer composite using hydrochar, synthesised by microwave-assisted hydrothermal carbonization of rice husk, as filler in polylactide matrix. The polylactide/hydrochar composites were fabricated by incorporating hydrochar in polylactide at 5%, 10%, 15% and 20 wt% by melt processing in a Haake rheomix at 170 °C. Both the neat polylactide and polylactide/hydrochar composite were characterized for mechanical, structural, thermal and rheological properties. The tensile modulus of polylactide/hydrochar composites was improved from 2.63 GPa (neat polylactide) to 3.16 GPa, 3.33 GPa, 3.54 GPa, and 4.24 GPa after blending with hydrochar at 5%, 10%, 15%, and 20%, respectively. Further, the incorporation of hydrochar had little effect on storage modulus (G') and loss modulus (G″). The findings of this study reported that addition of hydrochar improves some characteristics of polylactide composites suggesting the potential of hydrochar as filler for polymer/hydrochar composites.

Microwave Hydrothermal Carbonization of Rice Straw: Optimization of Process Parameters and Upgrading of Chemical, Fuel, Structural and Thermal Properties.

The process parameters of microwave-induced hydrothermal carbonization (MIHTC) play an important role on the hydrothermal chars (hydrochar) yield. The effect of reaction temperature, reaction time, particle size and biomass to water ratio was optimized for hydrochar yield by modeling using the central composite design (CCD). Further, the rice straw and hydrochar at optimum conditions have been characterized for energy, chemical, structural and thermal properties. The optimum condition for hydrochar synthesis was found to be at a 180 °C reaction temperature, a 20 min reaction time, a 1:15 weight per volume (w/v) biomass to water ratio and a 3 mm particle size, yielding 57.9% of hydrochar. The higher heating value (HHV), carbon content and fixed carbon values increased from 12.3 MJ/kg, 37.19% and 14.37% for rice straw to 17.6 MJ/kg, 48.8% and 35.4% for hydrochar. The porosity, crystallinity and thermal stability of the hydrochar were improved remarkably compared to rice straw after MIHTC. Two characteristic peaks from XRD were observed at 2θ of 15° and 26°, whereas DTG peaks were observed at 50⁻150 °C and 300⁻350 °C for both the materials. Based on the results, it can be suggested that the hydrochar could be potentially used for adsorption, carbon sequestration, energy and agriculture applications.

Upgradation of chemical, fuel, thermal, and structural properties of rice husk through microwave-assisted hydrothermal carbonization.

The process parameters of microwave hydrothermal carbonization (MHTC) have significant effect on yield of hydrochar. This study discusses the effect of process parameters on hydrochar yield produced from MHTC of rice husk. Results revealed that, over the ranges tested, a lower temperature, lower reaction time, lower biomass to water ratio, and higher particle size produce more hydrochar. Maximum hydrochar yield of 62.8% was obtained at 1000 W, 220 °C, and 5 min. The higher heating value (HHV) was improved significantly from 6.80 MJ/kg of rice husk to 16.10 MJ/kg of hydrochar. Elemental analysis results showed that the carbon content increased and oxygen content decreased in hydrochar from 25.9 to 47.2% and 68.5 to 47.0%, respectively, improving the energy and combustion properties. SEM analysis exhibited modification in structure of rice husk and improvement in porosity after MHTC, which was further confirmed from BET surface analysis. The BET surface area increased from 25.0656 m2/g (rice husk) to 92.6832 m2/g (hydrochar). Thermal stability of hydrochar was improved from 340 °C for rice husk to 370 °C for hydrochar.